3M MALAYSIA SDN BHD ======================================================================== CHEMICAL SAFETY DATA SHEET ======================================================================== Document id : 08-2286-6 Issue date : 29/12/2006 Version : 1.00 Supersedes date : --- Document status : Issued This CSDS has been prepared by Toxicology Department 3M Malaysia Sdn. Bhd. ------------------------------------------------------------------------ SECTION 1: CHEMICAL PRODUCT AND COMPANY IDENTIFICATION ------------------------------------------------------------------------ Tradename 3M FILTEK Z250 UNIVERSAL RESTORATIVE PASTE 3M Product ID: 41-5300-6441-3, 70-2010-2227-7, 70-2010-2229-3, 70-2010-2234-3, 70-2010-2235-0, 70-2010-2241-8, 70-2010-2242-6, 70-2010-2246-7, 70-2010-2251-7, 70-2010-2252-5, 70-2010-2253-3, 70-2010-2260-8, 70-2010-2564-3, 70-2010-2567-6, 70-2010-2568-4, 70-2010-2569-2, 70-2010-2570-0, 70-2010-2576-7, 70-2010-2585-8, 70-2010-2587-4, 70-2010-2588-2, 70-2010-2592-4, 70-2010-2593-2, 70-2010-2595-7, 70-2010-2599-9, 70-2010-2626-0, 70-2010-2628-6, 70-2010-2631-0, 70-2010-2709-4, 70-2010-2710-2, 70-2010-2715-1, 70-2010-2718-5, 70-2010-2724-3, 70-2010-2726-8, 70-2010-3135-1, 70-2010-3197-1, 70-2010-3200-3, 70-2010-3201-1, 70-2010-5200-1, 70-2010-5202-7, 70-2010-5206-8, 70-2010-5208-4, 70-2010-5211-8, 70-2010-5214-2, 70-2010-2225-1, 70-2010-2226-9, 70-2010-2228-5, 70-2010-2231-9, 70-2010-2233-5, 70-2010-2237-6, 70-2010-2238-4, 70-2010-2247-5, 70-2010-2577-5, 70-2010-2594-0, 70-2010-2598-1, 70-2010-2621-1, 70-2010-2625-2, 70-2010-2629-4, 70-2010-2630-2, 70-2010-2633-6, 70-2010-2634-4, 70-2010-2703-7, 70-2010-2704-5, 70-2010-2711-0, 70-2010-2712-8, 70-2010-2714-4, 70-2010-2716-9, 70-2010-2717-7, 70-2010-2720-1, 70-2010-2723-5, 70-2010-2725-0, 70-2010-3118-7, 70-2010-3177-3, 70-2010-3196-3, 70-2010-3198-9, 70-2010-3788-7, 70-2010-5203-5, 70-2010-5209-2, 70-2010-5210-0, 70-2010-5213-4, 70-2010-5217-5, 70-2010-2230-1, 70-2010-2232-7, 70-2010-2243-4, 70-2010-2244-2, 70-2010-2248-3, 70-2010-2249-1, 70-2010-2250-9, 70-2010-2254-1, 70-2010-2259-0, 70-2010-2565-0, 70-2010-2566-8, 70-2010-2571-8, 70-2010-2573-4, 70-2010-2575-9, 70-2010-2236-8, 70-2010-2245-9, 70-2010-2572-6, 70-2010-2574-2, 70-2010-2578-3, 70-2010-2586-6, 70-2010-2589-0, 70-2010-2590-8, 70-2010-2591-6, 70-2010-2596-5, 70-2010-2597-3, 70-2010-2620-3, 70-2010-2622-9, 70-2010-2623-7, 70-2010-2624-5, 70-2010-2627-8, 70-2010-2632-8, 70-2010-2700-3, 70-2010-2702-9, 70-2010-2707-8, 70-2010-2708-6, 70-2010-2713-6, 70-2010-3178-1, 70-2010-3195-5, 70-2010-3202-9, 70-2010-3203-7, 70-2010-3232-6, 70-2010-3278-9, 70-2010-3279-7, 70-2010-5064-1, 70-2010-5201-9, 70-2010-5204-3, 70-2010-5205-0, 70-2010-5207-6, 70-2010-5212-6, 70-2010-5215-9, 70-2010-5216-7, 70-2010-5218-3, 70-2010-5219-1 Intended Use of Product Limitations on Use of Product For use only by dental professionals. COMPANY IDENTIFICATION ---------------------- Manufacturer's name and address 3M 3M Center St. Paul, Minnesota 55144-1000 USA Importer's name and address 3M Malaysia Sdn. Bhd. Bangunan 3M No. 6, Persiaran Tropicana 47410 Petaling Jaya Selangor Telephone number 03-7806-2888 Emergency telephone number 1-651-7376501 ( 24 hours ) CONTACT POINT ------------- Designation Toxicology Coordinator Telephone number 03-7806-2888 ------------------------------------------------------------------------ SECTION 2: COMPOSITION/INFORMATION ON INGREDIENT ------------------------------------------------------------------------ Ingredient name CAS number Percentage ------------------------------------- ------------------ ------------- SILANE TREATED CERAMIC 444758-98-9 75 - 85 BISPHENOL A POLYETHYLENE GLYCOL 41637-38-1 5 - 10 DIETHER DIMETHACRYLATE DIURETHANE DIMETHACRYLATE 72869-86-4 5 - 10 BISPHENOL A DIGLYCIDYL ETHER 1565-94-2 1 - 10 DIMETHACRYLATE (BISGMA) TRIETHYLENE GLYCOL DIMETHACRYLATE 109-16-0 < 5 (TEGDMA) WATER 7732-18-5 < 2 ------------------------------------------------------------------------ SECTION 3: PHYSICAL AND CHEMICAL PROPERTIES ------------------------------------------------------------------------ Physical form,Color,Odor Solid Paste Slight acrylate odor, various shades. Water Solubility NIL Boiling point/boiling range N/A Melting point/melting range NOT DETERMINED Vapour pressure N/A Percent Volatile NOT DETERMINED Evaporation rate NIL Vapour density N/A Specific gravity = 2.1 Flash point N/A Autoflammability NOT DETERMINED Flammable Limits - LEL N/A Flammable Limits - UEL N/A Viscosity CA. 300000 centipoise ------------------------------------------------------------------------ SECTION 4: HAZARD IDENTIFICATION ------------------------------------------------------------------------ Risk Phrases None ------------------------------------------------------------------------ SECTION 5: FIRST AID MEASURES ------------------------------------------------------------------------ Instructions for Ingestion Do not induce vomiting unless instructed to do so by medical personnel. Give victim two glasses of water. Never give anything by mouth to an unconscious person. Get medical attention. Instructions for Eye Contact Flush eyes with large amounts of water. If signs/symptoms persist, get medical attention. Instructions for Skin Contact Remove contaminated clothing and shoes. Immediately flush skin with large amounts of water. Get medical attention. Wash contaminated clothing and clean shoes before reuse. Instructions for Inhalation Remove person to fresh air. If signs/symptoms develop, get medical attention. ------------------------------------------------------------------------ SECTION 6: FIRE FIGHTING MEASURES ------------------------------------------------------------------------ Suitable Extinguishing Media Use fire extinguishers with class B extinguishing agents (e.g., dry chemical, carbon dioxide). Fire Fighting Procedures Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatus (SCBA). Exposure Hazards during Fire Non-flammable: ordinary combustible material. ------------------------------------------------------------------------ SECTION 7: ACCIDENTAL RELEASE MEASURE ------------------------------------------------------------------------ Spill Response Ventilate the area with fresh air. Collect as much of the spilled material as possible. Clean up residue. Collect the resulting residue containing solution. Place in a closed container approved for transportation by appropriate authorities. Dispose of collected material as soon as possible. Methods for Disposal Not applicable. ------------------------------------------------------------------------ SECTION 8: HANDLING AND STORAGE ------------------------------------------------------------------------ Storage Requirements Store in a cool place. ------------------------------------------------------------------------ SECTION 9: EXP0SURE CONTROL AND PERSONAL PROTECTION ------------------------------------------------------------------------ Recommended Ventilation Not applicable. Eye Protection Avoid eye contact. The following should be worn alone or in combination, as appropriate, to prevent eye contact: Safety glasses with side shields Hand Protection A no-touch technique is recommended. If skin contact occurs, wash skin with soap and water. Acrylates may penetrate commonly-used gloves. If product contacts glove, remove and discard glove, wash hands immediately with soap and water and then re-glove. A no-touch technique is recommended. If skin contact occurs, wash skin with soap and water. Acrylates may penetrate commonly-used gloves. If product contacts glove, remove and discard glove, wash hands immediately with soap and water and then re-glove. Skin Protection Avoid skin contact. Avoid skin contact. Respiratory Protection Under normal use conditions, airborne exposures are not expected to be significant enough to require respiratory protection. Ingestion Do not ingest. Special Information, Exposure/Protection See Sect. 7.1 for more information about skin protection. ------------------------------------------------------------------------ SECTION 10: STABILITY AND REACTIVITY ------------------------------------------------------------------------ Materials to Avoid None known. Hazardous Decomposition Carbon monoxide During Combustion Carbon dioxide During Combustion Stability and Reactivity Hazardous polymerization will not occur. Stable ------------------------------------------------------------------------ SECTION 11: TOXICOLOGICAL INFORMATION ------------------------------------------------------------------------ Effects from Eye Contact Moderate Eye Irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision. Effects from Skin Contact Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, and itching. Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering and itching. Effects from Inhalation Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Effects from Ingestion Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. ------------------------------------------------------------------------ SECTION 12: ECOLOGICAL INFORMATION ------------------------------------------------------------------------ Environmental Data No data available. Ecotoxicity Data Not determined. Ecofate Data Not determined. Special statements for 2001/58/EC A conservative assessment indicates this product presents a low environmental risk because use and disposal are unlikely to result in the significant release of components to the environment. ------------------------------------------------------------------------ SECTION 13: DISPOSAL INFORMATION ------------------------------------------------------------------------ Product as Sold Incinerate in an industrial or commercial facility in the presence of a combustible material. As a disposal alternative, dispose of waste product in a facility permitted to accept chemical waste. ------------------------------------------------------------------------ SECTION 14: TRANSPORT INFORMATION ------------------------------------------------------------------------ UN Number IMO Class ICAO Class Special Instructions ** NOT HAZARDOUS FOR TRANSPORT FOR DOT, IMO OR IATA. ------------------------------------------------------------------------ SECTION 15: REGULATORY INFORMATION ------------------------------------------------------------------------ Symbols None Risk Phrases None Safety Phrases None Special Regulatory Information Contact 3M for more information. ------------------------------------------------------------------------ SECTION 16: OTHER INFORMATION ------------------------------------------------------------------------ Reason for Reissue Added/Deleted stock numbers. Change in MSDS ingredient disclosure. The information on this data sheet represents our current data and best opinion as to the proper use in handling of this product under normal conditions. Any use of the product which is not in conformance with this data sheet or which involves using the product in combination with any other product or any other process is the responsibility of the user.