3M MALAYSIA SDN BHD ======================================================================== CHEMICAL SAFETY DATA SHEET ======================================================================== Document id : 08-9514-4 Issue date : 26/04/2007 Version : 1.00 Supersedes date : --- Document status : Issued This CSDS has been prepared by Toxicology Department 3M Malaysia Sdn. Bhd. ------------------------------------------------------------------------ SECTION 1: CHEMICAL PRODUCT AND COMPANY IDENTIFICATION ------------------------------------------------------------------------ Tradename 7423/7423M 3M(TM) ESPE(TM) SCOTCHBOND(TM) ETCHANT GEL 3M Product ID: 70-2010-1314-4, 70-2010-1578-4, 70-2010-1553-7, 70-2010-1603-0, 70-2010-1686-5, 70-2010-2660-9, 70-2010-2661-7 Intended Use of Product COMPANY IDENTIFICATION ---------------------- Manufacturer's name and address 3M 3M Center St. Paul, Minnesota 55144-1000 USA Importer's name and address 3M Malaysia Sdn. Bhd. Bangunan 3M No. 6, Persiaran Tropicana 47410 Petaling Jaya Selangor Telephone number 03-7806-2888 Emergency telephone number 1-651-7376501 ( 24 hours ) CONTACT POINT ------------- Designation Toxicology Coordinator Telephone number 03-7806-2888 ------------------------------------------------------------------------ SECTION 2: COMPOSITION/INFORMATION ON INGREDIENT ------------------------------------------------------------------------ Ingredient name CAS number Percentage ------------------------------------- ------------------ ------------- WATER 7732-18-5 50 - 60 PHOSPHORIC ACID 7664-38-2 30 - 40 POLY(VINYL ALCOHOL) 9002-89-5 5 - 15 ------------------------------------------------------------------------ SECTION 3: PHYSICAL AND CHEMICAL PROPERTIES ------------------------------------------------------------------------ Physical form,Color,Odor DETAILS: Liquid. Liquid Blue, odorless. Water Solubility N/A COMPLETE Boiling point/boiling range N/A Melting point/melting range N/A Vapour pressure <= 16 psi Percent Volatile NOT DETERMINED Evaporation rate NOT DETERMINED Vapour density NOT DETERMINED Specific gravity CA. 1.2 Flash point N/A Autoflammability NOT DETERMINED Flammable Limits - LEL NOT DETERMINED Flammable Limits - UEL NOT DETERMINED Viscosity 300 - 800 centipoise ------------------------------------------------------------------------ SECTION 4: HAZARD IDENTIFICATION ------------------------------------------------------------------------ Risk Phrases None ------------------------------------------------------------------------ SECTION 5: FIRST AID MEASURES ------------------------------------------------------------------------ Instructions for Ingestion Do not induce vomiting. Get immediate medical attention. Give victim two glasses of water. Never give anything by mouth to an unconscious person. Instructions for Eye Contact Get immediate medical attention. Immediately flush eyes with large amounts of water for at least 15 minutes. Instructions for Skin Contact Immediately flush skin with large amounts of water for at least 15 minutes. Get immediate medical attention. Remove contaminated clothing and shoes. Wash contaminated clothing and clean shoes before reuse. Instructions for Inhalation Remove person to fresh air. If signs/symptoms develop, get medical attention. ------------------------------------------------------------------------ SECTION 6: FIRE FIGHTING MEASURES ------------------------------------------------------------------------ Suitable Extinguishing Media Use fire extinguishers with class B extinguishing agents (e.g., dry chemical, carbon dioxide). Fire Fighting Procedures Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatus (SCBA). Exposure Hazards during Fire Non-flammable: ordinary combustible material. ------------------------------------------------------------------------ SECTION 7: ACCIDENTAL RELEASE MEASURE ------------------------------------------------------------------------ Spill Response Place in a metal container approved for use in transportation by appropriate authorities. The container must be lined with polyethylene plastic or contain a plastic drum liner made of polyethylene. Ventilate the area with fresh air. Contain spill. Cover with absorbent material. Remember, adding an absorbent material does not remove a toxic, corrosivity or flammability hazard. Collect as much of the spilled material as possible. Clean up residue. Cover, but do not seal for 48 hours. Dispose of collected material as soon as possible. Methods for Disposal Not applicable. ------------------------------------------------------------------------ SECTION 8: HANDLING AND STORAGE ------------------------------------------------------------------------ Ventilation Keep container in well-ventilated area. ------------------------------------------------------------------------ SECTION 9: EXP0SURE CONTROL AND PERSONAL PROTECTION ------------------------------------------------------------------------ PHOSPHORIC ACID (7664-38-2) Exposure Limits 3 mg/m3 1 mg/m3 ACGIH: STEL ACGIH: TWA POLY(VINYL ALCOHOL) (9002-89-5) Exposure Limits 5 mg/m3 10 mg/m3 CMRG TWA RESPIRABLE 1991. CMRG TWA AS TOTAL DUST 1991. Recommended Ventilation Not applicable. Eye Protection Avoid eye contact. The following should be worn alone or in combination, as appropriate, to prevent eye contact: Safety glasses with side shields Hand Protection Not applicable. Skin Protection Avoid skin contact. Respiratory Protection Under normal use conditions, airborne exposures are not expected to be significant enough to require respiratory protection. Ingestion Do not ingest. ------------------------------------------------------------------------ SECTION 10: STABILITY AND REACTIVITY ------------------------------------------------------------------------ Materials to Avoid Strong Bases Hazardous Decomposition Carbon monoxide During Combustion Carbon dioxide During Combustion Stability and Reactivity Hazardous polymerization will not occur. Stable ------------------------------------------------------------------------ SECTION 11: TOXICOLOGICAL INFORMATION ------------------------------------------------------------------------ Effects from Eye Contact Corrosive (Eye Burns): Signs/symptoms may include cloudy appearance of the cornea, chemical burns, severe pain, tearing, ulcerations, significantly impaired vision or complete loss of vision. Effects from Skin Contact Corrosive (Skin Burns): Signs/symptoms may include localized redness, swelling, itching, intense pain, blistering, ulceration, and tissue destruction. Effects from Inhalation Upper Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Effects from Ingestion Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, nausea, diarrhea and vomiting. ------------------------------------------------------------------------ SECTION 12: ECOLOGICAL INFORMATION ------------------------------------------------------------------------ Environmental Data No data available. Ecotoxicity Data Not determined. Ecofate Data Not determined. Special statements for 2001/58/EC A conservative assessment indicates this product presents a low environmental risk. Components released to the environment through use and disposal are expected to have minimal environmental impact. ------------------------------------------------------------------------ SECTION 13: DISPOSAL INFORMATION ------------------------------------------------------------------------ Product as Sold Incinerate in a permitted hazardous waste incinerator in the presence of a combustible material. As a disposal alternative, dispose of waste product in a permitted hazardous waste facility. ------------------------------------------------------------------------ SECTION 14: TRANSPORT INFORMATION ------------------------------------------------------------------------ UN Number UN 1805. IMO Class FORBIDDEN 3M DIVISION POLICY. ICAO Class DANGEROUS GOODS IN EXCEPTED QUANTITIES OF CLASS 8. ------------------------------------------------------------------------ SECTION 15: REGULATORY INFORMATION ------------------------------------------------------------------------ Symbols None Risk Phrases None Safety Phrases None Special Regulatory Information Contact 3M for more information. ------------------------------------------------------------------------ SECTION 16: OTHER INFORMATION ------------------------------------------------------------------------ Reason for Reissue Added/Deleted stock numbers. New or changed physical property data. The information on this data sheet represents our current data and best opinion as to the proper use in handling of this product under normal conditions. Any use of the product which is not in conformance with this data sheet or which involves using the product in combination with any other product or any other process is the responsibility of the user.