3M MALAYSIA SDN BHD ======================================================================== CHEMICAL SAFETY DATA SHEET ======================================================================== Document id : 08-7352-1 Issue date : 30/05/2006 Version : 2.00 Supersedes date : 09/11/2004 Document status : Issued This CSDS has been prepared by Toxicology Department 3M Malaysia Sdn. Bhd. ------------------------------------------------------------------------ SECTION 1: CHEMICAL PRODUCT AND COMPANY IDENTIFICATION ------------------------------------------------------------------------ Tradename SCOTCH-WELD (TM) EPOXY ADHESIVE DP-420 BLACK (PART A) 3M Product ID: 62-2878-8530-5, 62-2878-9530-4 Intended Use of Product COMPANY IDENTIFICATION ---------------------- Manufacturer's name and address 3M 3M Center St. Paul, Minnesota 55144-1000 USA Importer's name and address 3M Malaysia Sdn. Bhd. Bangunan 3M No. 6, Persiaran Tropicana 47410 Petaling Jaya Selangor Telephone number 03-7806-2888 Emergency telephone number 1-651-7376501 ( 24 hours ) CONTACT POINT ------------- Designation Toxicology Coordinator Telephone number 03-7806-2888 ------------------------------------------------------------------------ SECTION 2: COMPOSITION/INFORMATION ON INGREDIENT ------------------------------------------------------------------------ Ingredient name CAS number Percentage ------------------------------------- ------------------ ------------- 4,7,10-TRIOXATRIDECANE-1,13-DIAMINE 4246-51-9 50.0 - 60.0 MODIFIED DIGLYCIDYL ETHER OF Trade Secret 20.0 - 30.0 BISPHENOL A - N.J. TRADE SECRET (T.S. ) REGISTRY #04499600-5023P EPOXY RESIN 25068-38-6 5.0 - 10.0 AMORPHOUS SILICA 7631-86-9 3.0 - 7.0 2,4,6-TRIS((DIMETHYLAMINO)METHYL)) 90-72-2 3.0 - 7.0 PHENOL SULFONIC ACID SALT - N.J. TRADE Trade Secret 1.0 - 5.0 SECRET (T.S.) REGISTRY #04499600- 5022P ------------------------------------------------------------------------ SECTION 3: PHYSICAL AND CHEMICAL PROPERTIES ------------------------------------------------------------------------ Physical form,Color,Odor viscous liquid amber, very mild pungent odor. Water Solubility <<< Boiling point/boiling range N/A Melting point/melting range NOT DETERMINED Vapour pressure N/A Percent Volatile No data available. Evaporation rate N/A Vapour density = 3.72 Air=1 Specific gravity = 1.120 Water=1 Flash point > 90.0 C TCC Autoflammability NOT DETERMINED Flammable Limits - LEL N/A Flammable Limits - UEL N/A Viscosity = 8000.0 centipoise ------------------------------------------------------------------------ SECTION 4: HAZARD IDENTIFICATION ------------------------------------------------------------------------ Risk Phrases None ------------------------------------------------------------------------ SECTION 5: FIRST AID MEASURES ------------------------------------------------------------------------ Instructions for Ingestion Do not induce vomiting. Drink two glasses of water. Call a physician. Instructions for Eye Contact Immediately flush eyes with large amounts of water for at least 15 minutes. Get immediate medical attention. Instructions for Skin Contact Immediately flush skin with large amounts of water for at least 15 minutes in a chemical safety shower while removing contaminated clothing and shoes. Get immediate medical attention. Wash contaminated clothing before reuse. Instructions for Inhalation If signs/symptoms occur, remove person to fresh air. If signs/symptoms continue, call a physician. ------------------------------------------------------------------------ SECTION 6: FIRE FIGHTING MEASURES ------------------------------------------------------------------------ Suitable Extinguishing Media Water Carbon dioxide Dry chemical Foam Fire Fighting Procedures Wear full protective clothing, including helmet, self-contained, positive pressure or pressure demand breathing apparatus, bunker coat and pants, bands around arms, waist and legs, face mask, and protective covering for exposed areas of the head. Special Instructions for Fire Fighting None known. ------------------------------------------------------------------------ SECTION 7: ACCIDENTAL RELEASE MEASURE ------------------------------------------------------------------------ Spill Response Cover with absorbent material. Collect as much of the spilled material as possible. Place in a U.S. DOT-approved container. Methods for Disposal Cure (harden, set, or react) the product according to product instructions. As a disposal alternative, incinerate uncured product in an industrial or commercial incinerator. Dispose of completely cured (or polymerized) wastes in a sanitary landfill. ------------------------------------------------------------------------ SECTION 8: HANDLING AND STORAGE ------------------------------------------------------------------------ Incompatible Materials Store away from heat. Use Instructions Keep container tightly closed. ------------------------------------------------------------------------ SECTION 9: EXP0SURE CONTROL AND PERSONAL PROTECTION ------------------------------------------------------------------------ AMORPHOUS SILICA (7631-86-9) Exposure Limits 3 mg/m3 CMRG: TWA - specific form; as respirable dust; DUPONT MSDS DATED 11/16 /99 FOR 11-0001-3049-9. 2,4,6-TRIS((DIMETHYLAMINO)METHYL))PHENOL (90-72-2) Exposure Limits 5 ppm CMRG: TWA; CMRG AUTHORITY: ALSO ROHM & HAAS Recommended Ventilation Provide appropriate local exhaust for cutting, grinding, sanding or machining. Curing enclosures must be exhausted to outdoors or to a suitable emission control device. Use in a well-ventilated area. If exhaust ventilation is not adequate, use appropriate respiratory protection. Eye Protection Avoid eye contact. Indirect Vented Goggles Safety glasses with side shields Hand Protection Wear appropriate gloves when handling this material. The following glove material(s) are recommended: polyethylene/ethylene vinyl alcohol Skin Protection Avoid skin contact. Respiratory Protection Avoid breathing of vapors. Avoid breathing of dust created by cutting, sanding, grinding or machining. Select one of the following approved respirators based on airborne concentration of contaminants and in accordance with regulations: half-mask dust respirator Ingestion Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Do not ingest. Keep out of the reach of children. ------------------------------------------------------------------------ SECTION 10: STABILITY AND REACTIVITY ------------------------------------------------------------------------ Materials to Avoid Heat is generated during cure. Do not cure a mass larger than 50 grams in a confined space to prevent a premature reaction (exotherm) with production of intense heat and smoke. Hazardous Decomposition Carbon Monoxide and Carbon Dioxide Oxides of Nitrogen Amine Compounds Toxic Vapors, Gases or Particulates Stability and Reactivity Stable Hazardous polymerization will not occur. ------------------------------------------------------------------------ SECTION 11: TOXICOLOGICAL INFORMATION ------------------------------------------------------------------------ Effects from Eye Contact Corrosive (Eye Burns): Signs/symptoms may include cloudy appearance of the cornea, chemical burns, severe pain, tearing, ulcerations, significantly impaired vision or complete loss of vision. Vapors from heated material may cause eye irritation. Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision. Dust created by cutting, grinding, sanding, or machining may cause eye irritation. Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision. Effects from Skin Contact Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching. Corrosive (Skin Burns): Signs/symptoms may include localized redness, swelling, itching, intense pain, blistering, ulceration, and tissue destruction. May be absorbed through the skin and produce effects similiar to those caused by inhalation and/or ingestion. Effects from Inhalation Upper Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Vapors from heated material may cause irritation of the respiratory system. Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Dust from cutting, grinding, sanding or machining may cause irritation of the respiratory system. Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Effects from Ingestion Ingestion may cause: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, nausea, diarrhea and vomiting. Other Toxicological Information Exposure to this material in normal storage and handling has not been reported to cause significant adverse health effects. However, under normal processing conditions, e.g. grinding or heating, this product may release fumes and vapors of variable composition based on specific process conditions. These process releases may produce irritation or any of the health effects listed above when the emissions are present at elevated concentrations. Use with appropriate local exhaust ventilation. ------------------------------------------------------------------------ SECTION 12: ECOLOGICAL INFORMATION ------------------------------------------------------------------------ Environmental Data No data available. Other Ecotoxicity Information Not determined. Since regulations vary, consult applicable regulations or authorities before disposal. ------------------------------------------------------------------------ SECTION 13: DISPOSAL INFORMATION ------------------------------------------------------------------------ Product as Sold ------------------------------------------------------------------------ SECTION 14: TRANSPORT INFORMATION ------------------------------------------------------------------------ UN Number IMO Class ICAO Class ------------------------------------------------------------------------ SECTION 15: REGULATORY INFORMATION ------------------------------------------------------------------------ Symbols None Risk Phrases None Safety Phrases None ------------------------------------------------------------------------ SECTION 16: OTHER INFORMATION ------------------------------------------------------------------------ Reason for Reissue Division name change. The information on this data sheet represents our current data and best opinion as to the proper use in handling of this product under normal conditions. Any use of the product which is not in conformance with this data sheet or which involves using the product in combination with any other product or any other process is the responsibility of the user.