3M MALAYSIA SDN BHD ======================================================================== CHEMICAL SAFETY DATA SHEET ======================================================================== Document id : 05-9830-0 Issue date : 30/10/2007 Version : 1.00 Supersedes date : --- Document status : Issued This CSDS has been prepared by Toxicology Department 3M Malaysia Sdn. Bhd. ------------------------------------------------------------------------ SECTION 1: CHEMICAL PRODUCT AND COMPANY IDENTIFICATION ------------------------------------------------------------------------ Tradename 3M(TM)Roto Peen Flap Assembly 3M Product ID: 61-0000-1012-6, 61-5000-9107-1, 61-5000-9108-9, 61-5001-3887-2, 61-5001-3888-0, 61-5002-8003-9, 61-9865-1035-4, 61-9865-1036-2, 61-9865-1059-4 Intended Use of Product Abrasive Product COMPANY IDENTIFICATION ---------------------- Manufacturer's name and address 3M 3M Center St. Paul, Minnesota 55144-1000 USA Importer's name and address 3M Malaysia Sdn. Bhd. Bangunan 3M No. 6, Persiaran Tropicana 47410 Petaling Jaya Selangor Telephone number 03-7806-2888 Emergency telephone number 1-651-7376501 ( 24 hours ) CONTACT POINT ------------- Designation Toxicology Coordinator Telephone number 03-7806-2888 ------------------------------------------------------------------------ SECTION 2: COMPOSITION/INFORMATION ON INGREDIENT ------------------------------------------------------------------------ Ingredient name CAS number Percentage ------------------------------------- ------------------ ------------- TUNGSTEN CARBIDE BALLS 12070-12-1 35 - 55 CURED RESIN Mixture 30 - 40 Nylon Cloth Unknown 15 - 25 ------------------------------------------------------------------------ SECTION 3: PHYSICAL AND CHEMICAL PROPERTIES ------------------------------------------------------------------------ Physical form,Color,Odor Solid Abrasive flap with small Tungsten Carbide balls attached to edge. Water Solubility N/A Boiling point/boiling range N/A Melting point/melting range N/A Vapour pressure N/A Percent Volatile N/A Evaporation rate N/A Vapour density N/A Specific gravity N/A Flash point N/A Autoflammability N/A Flammable Limits - LEL N/A Flammable Limits - UEL N/A Viscosity N/A ------------------------------------------------------------------------ SECTION 4: HAZARD IDENTIFICATION ------------------------------------------------------------------------ Risk Phrases None ------------------------------------------------------------------------ SECTION 5: FIRST AID MEASURES ------------------------------------------------------------------------ Instructions for Ingestion No need for first aid is anticipated. Instructions for Eye Contact Flush eyes with large amounts of water. If signs/symptoms persist, get medical attention. Instructions for Skin Contact Wash affected area with soap and water. If signs/symptoms develop, get medical attention. Instructions for Inhalation If signs/symptoms develop, remove person to fresh air. If signs/symptoms persist, get medical attention. Special Instructions for First Aid All first aid statements refer to exposure of dust created by cutting, sanding or grinding. ------------------------------------------------------------------------ SECTION 6: FIRE FIGHTING MEASURES ------------------------------------------------------------------------ Suitable Extinguishing Media Ordinary combustible material. Use fire extinguishers with class A extinguishing agents (e.g., water, foam). Fire Fighting Procedures Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatus (SCBA). Special Instructions for Fire Fighting Not applicable. Exposure Hazards during Fire Material will not burn. ------------------------------------------------------------------------ SECTION 7: ACCIDENTAL RELEASE MEASURE ------------------------------------------------------------------------ Spill Response Not applicable. Methods for Disposal Not applicable. ------------------------------------------------------------------------ SECTION 8: HANDLING AND STORAGE ------------------------------------------------------------------------ Storage Requirements Store in a cool, dry place. Ventilation Avoid breathing of dust created by sanding, grinding or machining. Use Instructions For industrial or professional use only. Damaged product can break apart during use and cause serious injury to face or eyes. Check product for damage such as cracks or nicks prior to use. Replace if damaged. Always wear eye and face protection when working at sanding or grinding operations or when near such operations. Sparks and particles flying from the product during sanding or grinding can cause injury and fire. ------------------------------------------------------------------------ SECTION 9: EXP0SURE CONTROL AND PERSONAL PROTECTION ------------------------------------------------------------------------ TUNGSTEN CARBIDE BALLS (12070-12-1) Exposure Limits 10 mg/m3 5 mg/m3 ACGIH: STEL - specific form; as W - Category: TUNGSTEN, INSOLUBLE COMPOUNDS. ACGIH: TWA - specific form; as W - Category: TUNGSTEN, INSOLUBLE COMPOUNDS. Recommended Ventilation Provide ventilation adequate to control dust concentrations below recommended exposure limits and/or control dust. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below Occupational Exposure Limits and/or control dust, fume, or airborne particles. If ventilation is not adequate, use respiratory protection equipment. Use particulate collection systems. Eye Protection Avoid eye contact. Avoid eye contact with dust or airborne particles. To minimize the risk of injury to face and eyes, always wear eye and face protection when working at sanding or grinding operations or when near such operations. Use protective glasses and/or face shield as recommended in ANSI Standard Z87.1. The following should be worn alone or in combination, as appropriate, to prevent eye contact: Safety glasses with side shields Hand Protection Wear appropriate gloves to minimize risk of injury to skin from contact with dust or physical abrasion from grinding or sanding. Skin Protection Avoid skin contact. Respiratory Protection Provide appropriate local exhaust ventilation for sanding, grinding or machining. Avoid breathing of dust created by sanding, grinding or machining. Assess exposure concentrations of all materials involved in the work process. Consider material being abraded when determining the appropriate resipratory protection. Select and use appropriate respirators to prevent inhalation overexposure. Select one of the following approved respirators based on airborne concentration of contaminants and in accordance with regulations: Half facepiece or fullface air-purifying respirator with N95 particulate prefilters Ingestion Wash hands after handling and before eating. Not an expected route of exposure. ------------------------------------------------------------------------ SECTION 10: STABILITY AND REACTIVITY ------------------------------------------------------------------------ Materials to Avoid None known. Hazardous Decomposition Carbon monoxide During Combustion Carbon dioxide During Combustion Under recommended usage conditions, hazardous decomposition products are not expected. Hazardous decomposition products may occur as a result of oxidation, heating, or reaction with another material. No hazardous decomposition products are expected during normal use of this product. However, during flaming conditions or excessive heating the following may be emitted: carbon monoxide, carbon dioxide, oxides of nitrogen, cyanides Stability and Reactivity Hazardous polymerization will not occur. Stable ------------------------------------------------------------------------ SECTION 11: TOXICOLOGICAL INFORMATION ------------------------------------------------------------------------ Effects from Eye Contact Mechanical eye irritation: Signs/symptoms may include pain, redness, tearing and corneal abrasion. Dust created by cutting, grinding, sanding, or machining may cause eye irritation. Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision. Effects from Skin Contact Mechanical Skin irritation: Signs/symptoms may include abrasion, redness, pain, and itching. Effects from Inhalation Dust from cutting, grinding, sanding or machining may cause irritation of the respiratory system. Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Effects from Ingestion No health effects are expected. Other Toxicological Information This document covers only the 3M product. For complete assessment, when determining the degree of hazard, the material being abraded must also be considered. ------------------------------------------------------------------------ SECTION 12: ECOLOGICAL INFORMATION ------------------------------------------------------------------------ Environmental Data No data available. Ecotoxicity Data Not determined. Ecofate Data Not determined. ------------------------------------------------------------------------ SECTION 13: DISPOSAL INFORMATION ------------------------------------------------------------------------ Product as Sold Dispose of large quantities in a sanitary landfill. Incinerate in an industrial or commercial facility in the presence of a combustible material. As a disposal alternative, incinerate in an industrial or commercial facility in the presence of a combustible material. Combustion products will include HF. Facility must be capable of handling halogenated materials. Product after Use The substrate that was abraded must be considered as a factor in the disposal method for this product. ------------------------------------------------------------------------ SECTION 14: TRANSPORT INFORMATION ------------------------------------------------------------------------ UN Number IMO Class ICAO Class Special Instructions ** NOT HAZARDOUS FOR TRANSPORT FOR DOT, IMO OR IATA. ------------------------------------------------------------------------ SECTION 15: REGULATORY INFORMATION ------------------------------------------------------------------------ Symbols None Risk Phrases None Safety Phrases None Special Regulatory Information Contact 3M for more information. ------------------------------------------------------------------------ SECTION 16: OTHER INFORMATION ------------------------------------------------------------------------ Reason for Reissue The MSDS has been revised because 3M has adopted the 16-section ANSI/ISO format. The potential hazards of the product have not changed. We encourage you to reread the MSDS and review the information. The information on this data sheet represents our current data and best opinion as to the proper use in handling of this product under normal conditions. Any use of the product which is not in conformance with this data sheet or which involves using the product in combination with any other product or any other process is the responsibility of the user.