3M MALAYSIA SDN BHD ======================================================================== CHEMICAL SAFETY DATA SHEET ======================================================================== Document id : 06-8466-2 Issue date : 07/12/2006 Version : 2.00 Supersedes date : 16/08/2005 Document status : Issued This CSDS has been prepared by Toxicology Department 3M Malaysia Sdn. Bhd. ------------------------------------------------------------------------ SECTION 1: CHEMICAL PRODUCT AND COMPANY IDENTIFICATION ------------------------------------------------------------------------ Tradename 3M FIRE BARRIER 2000+ PREMIUM SILICONE SEALANT 3M Product ID: 98-0400-2843-7, 98-0400-2844-5, 98-0400-2845-2, 98-0400-5299-9, 98-0400-5300-5, 44-0029-8102-3 Intended Use of Product A FIRE STOPPING SEALANT FOR FIRE RATED WALL AND FLOOR PENETRATION AND JOINTS. COMPANY IDENTIFICATION ---------------------- Manufacturer's name and address 3M 3M Center St. Paul, Minnesota 55144-1000 USA Importer's name and address 3M Malaysia Sdn. Bhd. Bangunan 3M No. 6, Persiaran Tropicana 47410 Petaling Jaya Selangor Telephone number 03-7806-2888 Emergency telephone number 1-651-7376501 ( 24 hours ) CONTACT POINT ------------- Designation Toxicology Coordinator Telephone number 03-7806-2888 ------------------------------------------------------------------------ SECTION 2: COMPOSITION/INFORMATION ON INGREDIENT ------------------------------------------------------------------------ Ingredient name CAS number Percentage ------------------------------------- ------------------ ------------- POLYSILOXANE Trade Secret 40 - 50 CALCIUM CARBONATE TREATED WITH Unknown 40 - 50 STEARIC ACID Dimethyl Siloxane, 68083-19-2 3 - 7 Dimethylvinylsiloxy-terminated METHYLTRIMETHOXYSILANE 1185-55-3 1 - 5 ------------------------------------------------------------------------ SECTION 3: PHYSICAL AND CHEMICAL PROPERTIES ------------------------------------------------------------------------ Physical form,Color,Odor Solid Paste Gray silicone sealant paste with alcoholic odor. Water Solubility NOT DETERMINED Boiling point/boiling range N/A Melting point/melting range NOT DETERMINED Vapour pressure N/A Percent Volatile NOT DETERMINED Evaporation rate NOT DETERMINED Vapour density N/A Specific gravity 1.34 Water=1 CONDITIONS: @ 25 C. Flash point N/A Autoflammability NOT DETERMINED Flammable Limits - LEL N/A Flammable Limits - UEL N/A Viscosity NOT DETERMINED ------------------------------------------------------------------------ SECTION 4: HAZARD IDENTIFICATION ------------------------------------------------------------------------ Risk Phrases None ------------------------------------------------------------------------ SECTION 5: FIRST AID MEASURES ------------------------------------------------------------------------ Instructions for Ingestion Do not induce vomiting unless instructed to do so by medical personnel. Give victim two glasses of water. Never give anything by mouth to an unconscious person. Get medical attention. Instructions for Eye Contact Flush eyes with large amounts of water. If signs/symptoms persist, get medical attention. Instructions for Skin Contact Wash affected area with soap and water. If signs/symptoms develop, get medical attention. Instructions for Inhalation Remove person to fresh air. If signs/symptoms develop, get medical attention. ------------------------------------------------------------------------ SECTION 6: FIRE FIGHTING MEASURES ------------------------------------------------------------------------ Suitable Extinguishing Media Non-combustible. Choose material suitable for surrounding fire. Nonflammable. Fire Fighting Procedures Exposure Hazards during Fire Material will not burn. ------------------------------------------------------------------------ SECTION 7: ACCIDENTAL RELEASE MEASURE ------------------------------------------------------------------------ Spill Response Evacuate unprotected and untrained personnel from hazard area. The spill should be cleaned up by qualified personnel. Ventilate the area with fresh air. Contain spill. Collect as much of the spilled material as possible. Clean up residue with detergent and water. Collect the resulting residue containing solution. Place in a closed container approved for transportation by appropriate authorities. Dispose of collected material as soon as possible. Methods for Disposal Not applicable. ------------------------------------------------------------------------ SECTION 8: HANDLING AND STORAGE ------------------------------------------------------------------------ Storage Requirements Store under normal warehouse conditions. Use Instructions Avoid eye contact. Avoid prolonged or repeated skin contact. Do not ingest. Wash hands after handling and before eating. ------------------------------------------------------------------------ SECTION 9: EXP0SURE CONTROL AND PERSONAL PROTECTION ------------------------------------------------------------------------ Recommended Ventilation Methanol is formed on contact of product with water. Eye Protection The following should be worn alone or in combination, as appropriate, to prevent eye contact: Safety glasses with side shields Hand Protection Not applicable. Skin Protection Avoid prolonged or repeated skin contact. Respiratory Protection Select one of the following approved respirators based on airborne concentration of contaminants and in accordance with regulations: Half facepiece or fullface air-purifying respirator with organic vapor cartridges Ingestion Wash hands after handling and before eating. ------------------------------------------------------------------------ SECTION 10: STABILITY AND REACTIVITY ------------------------------------------------------------------------ Materials to Avoid None known. Hazardous Decomposition Carbon monoxide During Combustion Carbon dioxide During Combustion THERMAL BREAKDOWN OF THIS PRODUCT DURING FIRE OR VERY HIGH HEAT CONDITIONS MAY EVOLVE THE FOLLOWING HAZARDOUS DECOMPOSITION PRODUCTS: SILICONE DIOXIDE; CARBON OXIDES AND TRACES OF INCOMPLETELY BURNED CARBON COMPOUNDS; METAL OXIDES; SULFUR OXIDES; AND FORMALDEHYDE. Stability and Reactivity Stable Hazardous polymerization will not occur. ------------------------------------------------------------------------ SECTION 11: TOXICOLOGICAL INFORMATION ------------------------------------------------------------------------ Effects from Eye Contact Mild Eye Irritation: Signs/symptoms may include redness, pain, and tearing. Effects from Skin Contact Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, and itching. Effects from Inhalation Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Effects from Ingestion Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. ------------------------------------------------------------------------ SECTION 12: ECOLOGICAL INFORMATION ------------------------------------------------------------------------ Environmental Data No data available. Ecotoxicity Data Not determined. Ecofate Data Not determined. ------------------------------------------------------------------------ SECTION 13: DISPOSAL INFORMATION ------------------------------------------------------------------------ Product as Sold Dispose of completely cured (or polymerized) wastes in a sanitary landfill. As a disposal alternative, incinerate uncured product in an industrial or commercial incinerator in the presence of a combustible material. ------------------------------------------------------------------------ SECTION 14: TRANSPORT INFORMATION ------------------------------------------------------------------------ UN Number IMO Class ICAO Class Special Instructions ** NOT HAZARDOUS FOR TRANSPORT FOR DOT, IMO OR IATA. ------------------------------------------------------------------------ SECTION 15: REGULATORY INFORMATION ------------------------------------------------------------------------ Symbols None Risk Phrases None Safety Phrases Use only in well ventilated areas. S24/25 Avoid contact with the skin and eyes. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S28B After contact with skin, wash immediately with plenty of water. Special Regulatory Information Contact 3M for more information. ------------------------------------------------------------------------ SECTION 16: OTHER INFORMATION ------------------------------------------------------------------------ Reason for Reissue The MSDS has been revised because 3M has adopted the 16-section ANSI/ISO format. The potential hazards of the product have not changed. We encourage you to reread the MSDS and review the information. The information on this data sheet represents our current data and best opinion as to the proper use in handling of this product under normal conditions. Any use of the product which is not in conformance with this data sheet or which involves using the product in combination with any other product or any other process is the responsibility of the user.