3M MALAYSIA SDN BHD ======================================================================== CHEMICAL SAFETY DATA SHEET ======================================================================== Document id : 06-4427-8 Issue date : 10/08/2007 Version : 1.00 Supersedes date : --- Document status : Issued This CSDS has been prepared by Toxicology Department 3M Malaysia Sdn. Bhd. ------------------------------------------------------------------------ SECTION 1: CHEMICAL PRODUCT AND COMPANY IDENTIFICATION ------------------------------------------------------------------------ Tradename SCOTCHRAP BRAND PIPE PRIMER 3M Product ID: 80-6107-3581-5, 80-6108-3280-2, 80-6109-2573-9 Intended Use of Product PIPE PRIMER. COMPANY IDENTIFICATION ---------------------- Manufacturer's name and address 3M 3M Center St. Paul, Minnesota 55144-1000 USA Importer's name and address 3M Malaysia Sdn. Bhd. Bangunan 3M No. 6, Persiaran Tropicana 47410 Petaling Jaya Selangor Telephone number 03-7806-2888 Emergency telephone number 1-651-7376501 ( 24 hours ) CONTACT POINT ------------- Designation Toxicology Coordinator Telephone number 03-7806-2888 ------------------------------------------------------------------------ SECTION 2: COMPOSITION/INFORMATION ON INGREDIENT ------------------------------------------------------------------------ Ingredient name CAS number Percentage ------------------------------------- ------------------ ------------- SOLVENT NAPHTHA (PETROLEUM), LIGHT 64742-89-8 55 - 65 ALIPHATIC CALCIUM ZINC RESINATE 68334-35-0 10 - 15 Butyl rubber 9010-85-9 10 - 15 TOLUENE 108-88-3 4 - 6 KAOLINITE 1318-74-7 1 - 5 ETHYL ALCOHOL 64-17-5 1 - 5 QUARTZ SILICA 14808-60-7 < 5 PIPERYLENE-2-METHYL-2-BUTENE POLYMER 26813-14-9 < 2 MICA-GROUP MINERALS 12001-26-2 < 2 CARBON BLACK 1333-86-4 < 2 BENZENE 71-43-2 < 0.003 ------------------------------------------------------------------------ SECTION 3: PHYSICAL AND CHEMICAL PROPERTIES ------------------------------------------------------------------------ Physical form,Color,Odor Liquid Black-Solvent odor. Water Solubility CONDITIONS: Nil. Boiling point/boiling range 90 - 100 C DETAILS: MITS data. Melting point/melting range NOT DETERMINED Vapour pressure 130 mmHg CONDITIONS: @ 20.0 C DETAILS: MITS data. Percent Volatile CONDITIONS: 60. Evaporation rate NOT DETERMINED Vapour density NOT DETERMINED Specific gravity CONDITIONS: 0.83. Flash point CONDITIONS: -14F Closed Cup. Autoflammability 246.11 - 260.0 C Flammable Limits - LEL NOT DETERMINED Flammable Limits - UEL NOT DETERMINED Viscosity CONDITIONS: 300cps. ------------------------------------------------------------------------ SECTION 4: HAZARD IDENTIFICATION ------------------------------------------------------------------------ Risk Phrases None ------------------------------------------------------------------------ SECTION 5: FIRST AID MEASURES ------------------------------------------------------------------------ Instructions for Ingestion Do not induce vomiting unless instructed to do so by medical personnel. Give victim two glasses of water. Never give anything by mouth to an unconscious person. Get medical attention. Instructions for Eye Contact Flush eyes with large amounts of water. If signs/symptoms persist, get medical attention. Instructions for Skin Contact Wash affected area with soap and water. If signs/symptoms develop, get medical attention. Instructions for Inhalation Remove person to fresh air. If signs/symptoms develop, get medical attention. ------------------------------------------------------------------------ SECTION 6: FIRE FIGHTING MEASURES ------------------------------------------------------------------------ Suitable Extinguishing Media Use fire extinguishers with class B extinguishing agents (e.g., dry chemical, carbon dioxide). Fire Fighting Procedures Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and prevent explosive rupture. Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatus (SCBA). Exposure Hazards during Fire Closed containers exposed to heat from fire may build pressure and explode. Vapors may travel long distances along the ground or floor to an ignition source and flash back. ------------------------------------------------------------------------ SECTION 7: ACCIDENTAL RELEASE MEASURE ------------------------------------------------------------------------ Spill Response For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Evacuate unprotected and untrained personnel from hazard area. The spill should be cleaned up by qualified personnel. Remove all ignition sources such as flames, smoking materials, and electrical spark sources. Use only non-sparking tools. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn or explode. Contain spill. Cover spill area with a fire-extinguishing foam. An aqueous film forming foam (AFFF) is recommended. Collect as much of the spilled material as possible using non-sparking tools. Clean up residue with an appropriate organic solvent. Read and follow safety precautions on the solvent label and MSDS. Place in a metal container approved for transportation by appropriate authorities. Dispose of collected material as soon as possible. Methods for Disposal Not applicable. ------------------------------------------------------------------------ SECTION 8: HANDLING AND STORAGE ------------------------------------------------------------------------ Incompatible Materials Store away from acids. Store away from heat. Store out of direct sunlight. Store away from oxidizing agents. Ventilation Keep container in well-ventilated area. Fire Prevention Ground containers securely when transferring contents. Wear low static or properly grounded shoes. No smoking while handling this material. Extremely flammable liquid and vapor. Explosion Prevention Keep away from heat, sparks, open flame, pilot lights and other sources of ignition. Static Prevention Avoid static discharge. Use Instructions Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Contents may be under pressure, open carefully. Keep container tightly closed. Avoid breathing of vapors, mists or spray. Avoid eye contact with vapors, mists, or spray. For industrial or professional use only. Avoid contact with oxidizing agents. ------------------------------------------------------------------------ SECTION 9: EXP0SURE CONTROL AND PERSONAL PROTECTION ------------------------------------------------------------------------ SOLVENT NAPHTHA (PETROLEUM), LIGHT ALIPHATIC (64742-89-8) Exposure Limits 300 ppm CMRG: TWA; MSDS FOR 11-0000-2129-2 TOLUENE (108-88-3) Exposure Limits 20 ppm ACGIH: TWA; Table A4 75 ppm CMRG: STEL; skin contact contributes to exposure; Comments: ROHM & HAAS MSDS DATED 2/20/01 FOR 11-0018-3267-1. ETHYL ALCOHOL (64-17-5) Exposure Limits 1880 mg/m3 ACGIH: TWA; Table A4. 1000 ppm ACGIH: TWA; Table A4. QUARTZ SILICA (14808-60-7) Exposure Limits 0.025 mg/m3 ACGIH: TWA; respirable; Table A2; Comments: From 2006 ACGIH TLV Book. MICA-GROUP MINERALS (12001-26-2) Exposure Limits 3 mg/m3 ACGIH: TWA - respirable; CARBON BLACK (1333-86-4) Exposure Limits 3.5 mg/m3 0.5 mg/m3 ACGIH: TWA; Table A4 CMRG: TWA; DUPONT MSDS DATED 1/6/99 FOR 11-0018-9474-7. BENZENE (71-43-2) Exposure Limits 2.5 ppm ACGIH: STEL; skin contact contributes to exposure; Table A1; Comments: added STEL per 1998 ACGIH TLV booklet. 30 mg/m3 ACGIH: TWA; skin contact contributes to exposure; Table A1; Comments: updated limits and appendix per 1998 ACGIH TLV booklet. 0.5 ppm ACGIH: TWA; skin contact contributes to exposure; Table A1; Comments: updated limits and appendix per 1998 ACGIH TLV booklet. Recommended Ventilation Use with appropriate local exhaust ventilation. Provide appropriate local exhaust ventilation at transfer points. Provide appropriate local exhaust ventilation on open containers. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below Occupational Exposure Limits and/or control mist, vapor, or spray. If ventilation is not adequate, use respiratory protection equipment. Eye Protection Avoid eye contact with vapors, mists, or spray. The following should be worn alone or in combination, as appropriate, to prevent eye contact: Indirect Vented Goggles Hand Protection Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible materials. Skin Protection Avoid skin contact. Respiratory Protection Avoid breathing of vapors, mists or spray. Select one of the following approved respirators based on airborne concentration of contaminants and in accordance with regulations: Half facepiece or fullface air-purifying respirator with organic vapor cartridges Ingestion Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Not applicable. ------------------------------------------------------------------------ SECTION 10: STABILITY AND REACTIVITY ------------------------------------------------------------------------ Materials to Avoid Heat Sparks and/or Flames Strong Oxidizing Agents Temperatures above the boiling point Hazardous Decomposition Carbon monoxide During Combustion Carbon dioxide During Combustion Aldehydes with Oxidative Degradation Stability and Reactivity Hazardous polymerization will not occur. Stable ------------------------------------------------------------------------ SECTION 11: TOXICOLOGICAL INFORMATION ------------------------------------------------------------------------ Effects from Eye Contact Moderate Eye Irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision. Effects from Skin Contact May be absorbed through skin and cause target organ effects. Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, and itching. Effects from Inhalation May be absorbed following inhalation and cause target organ effects. Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Effects from Ingestion May be absorbed following ingestion and cause target organ effects. Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. Carcinogenicity Contains a chemical or chemicals which can cause cancer. Note: This product contains ethanol. In IARC published Monograph No. 44, entitled, 'Alcohol Drinking', the carcinogenicity of ethanol was determined based on chronic exposure to ethanol through human consumption of alcoholic beverages. This is not an expected effect during the foreseeable use of this product. Reproductive Effects Contains a chemical or chemicals which can cause birth defects or other reproductive harm. Other Toxicological Information Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness. Prolonged or repeated exposure may cause: Liver Effects: Signs/symptoms may include loss of appetite, weight loss, fatigue, weakness, abdominal tenderness and jaundice. Central Neuropathy: Signs/symptoms may include irritability, memory impairment, personality changes, sleep disorders, and decreased ability to concentrate. ------------------------------------------------------------------------ SECTION 12: ECOLOGICAL INFORMATION ------------------------------------------------------------------------ Environmental Data No data available. Ecotoxicity Data Not determined. Ecofate Data Not determined. ------------------------------------------------------------------------ SECTION 13: DISPOSAL INFORMATION ------------------------------------------------------------------------ Product as Sold Incinerate in a permitted hazardous waste incinerator. As a disposal alternative, dispose of waste product in a permitted hazardous waste facility. ------------------------------------------------------------------------ SECTION 14: TRANSPORT INFORMATION ------------------------------------------------------------------------ UN Number UN 1133. IMO Class ADHESIVES, 3, II, LIMITED QUANTITY, -007C. ICAO Class ADHESIVES, 3, II. Special Instructions Transportation classifications are provided as a customer service. As for shipping, YOU remain responsible for complying with all applicable laws and regulations, including proper transportation classification and packaging. 3M's transportation classifications are based on product formulation, packaging, 3M policies and 3M's understanding of applicable current regulations. 3M does not guarantee the accuracy of this classification information. This information applies only to transportation classification and not the packaging, labeling or marking requirements. The above information is only for reference. If you are shipping by air or ocean, YOU are advised to check & meet applicable regulatory requirements. ------------------------------------------------------------------------ SECTION 15: REGULATORY INFORMATION ------------------------------------------------------------------------ Symbols None Risk Phrases None Safety Phrases None Special Regulatory Information Contact 3M for more information. ------------------------------------------------------------------------ SECTION 16: OTHER INFORMATION ------------------------------------------------------------------------ Reason for Reissue The MSDS has been revised because 3M has adopted the 16-section ANSI/ISO format. The potential hazards of the product have not changed. We encourage you to reread the MSDS and review the information. Division name change. The information on this data sheet represents our current data and best opinion as to the proper use in handling of this product under normal conditions. Any use of the product which is not in conformance with this data sheet or which involves using the product in combination with any other product or any other process is the responsibility of the user.