3M MALAYSIA SDN BHD ======================================================================== CHEMICAL SAFETY DATA SHEET ======================================================================== Document id : 23-2998-5 Issue date : 24/07/2012 Version : 1.00 Supersedes date : --- Document status : Issued This CSDS has been prepared by Toxicology Department 3M Malaysia Sdn. Bhd. ------------------------------------------------------------------------ SECTION 1: CHEMICAL PRODUCT AND COMPANY IDENTIFICATION ------------------------------------------------------------------------ Tradename 3M(TM) Scotch-Weld(TM) FoamFast 74 Cylinder Spray Adhesive, Clear 3M Product ID: 62-4974-8030-1, 62-4974-8300-8, 62-4974-8032-7, 62-4974-8150-7 Intended Use of Product Industrial use COMPANY IDENTIFICATION ---------------------- Manufacturer's name and address 3M 3M Center St. Paul, Minnesota 55144-1000 USA Importer's name and address 3M Malaysia Sdn. Bhd. Bangunan 3M No. 6, Persiaran Tropicana 47410 Petaling Jaya Selangor Telephone number 03-7806-2888 Emergency telephone number 1-651-7376501 ( 24 hours ) CONTACT POINT ------------- Designation Toxicology Coordinator Telephone number 03-7806-2888 ------------------------------------------------------------------------ SECTION 2: COMPOSITION/INFORMATION ON INGREDIENT ------------------------------------------------------------------------ Ingredient name CAS number Percentage ------------------------------------- ------------------ ------------- N.J.T.S. Reg No. 04499600-6501P Trade Secret 30 - 40 DIMETHYL ETHER 115-10-6 20 - 30 Exposure Limits: 1880 mg/m3 AIHA: TWA 1000 ppm AIHA: TWA 1000 ppm CMRG: TWA ACETONE 67-64-1 10 - 20 Exposure Limits: 2380 mg/m3 ACGIH: STEL; Table A4; Comments: Added A4 per 2003 ACGIH updates LAM 750 ppm ACGIH: STEL; Table A4; Comments: Added A4 per 2003 ACGIH updates LAM 1780 mg/m3 ACGIH: TWA; Table A4; Comments: Added A4 per 2003 ACGIH updates LAM 500 ppm ACGIH: TWA; Table A4; Comments: Added A4 per 2003 ACGIH updates LAM PENTANE 109-66-0 5 - 15 Exposure Limits: 600 ppm ACGIH: TWA 600 ppm ACGIH: TWA; Category: Pentane METHYL ACETATE 79-20-9 5 - 10 Exposure Limits: 760 mg/m3 ACGIH: STEL 250 ppm ACGIH: STEL 606 mg/m3 ACGIH: TWA 200 ppm ACGIH: TWA ISOBUTANE 75-28-5 5 - 10 PROPANE 74-98-6 5 - 10 Exposure Limits: 2500 ppm ACGIH: TWA; Changed from Simple asphyxiant per 1998 ACGIH TLV booklet CYCLOHEXANE 110-82-7 1 - 5 Exposure Limits: 100 ppm ACGIH: TWA; Comments: Changed limit values per May 2002 RDC database. Change on 7/22/02 does not require reissue. HYDROTREATED HEAVY NAPHTHA 64742-48-9 1 - 5 (PETROLEUM) Exposure Limits: 100 ppm 3M: TWA ------------------------------------------------------------------------ SECTION 3: PHYSICAL AND CHEMICAL PROPERTIES ------------------------------------------------------------------------ Physical form,Color,Odor Gas clear, solvent odor Water Solubility NIL Boiling point/boiling range <= 20.0 C Melting point/melting range N/A Vapour pressure 84.7 psia CONDITIONS: @ 20.0 C Percent Volatile No data available. Evaporation rate NOT DETERMINED Vapour density >= 1 Specific gravity 0.716 Water=1 Flash point -45.56 C CC DETAILS: Flammable Gas Autoflammability NOT DETERMINED Flammable Limits - LEL 1.2 % by vol Flammable Limits - UEL 27 % by vol Viscosity N/A ------------------------------------------------------------------------ SECTION 4: HAZARD IDENTIFICATION ------------------------------------------------------------------------ Risk Phrases Extremely flammable. Risk of serious damage to eyes. Repeated exposure may cause skin dryness or cracking. Vapours may cause drowsiness and dizziness. Toxic to aquatic organisms. May cause long-term adverse effects in the aquatic environment. ------------------------------------------------------------------------ SECTION 5: FIRST AID MEASURES ------------------------------------------------------------------------ Instructions for Ingestion Do not induce vomiting unless instructed to do so by medical personnel. Give victim two glasses of water. Never give anything by mouth to an unconscious person. Get medical attention. Instructions for Eye Contact Immediately flush eyes with large amounts of water for at least 15 minutes. Get immediate medical attention. Instructions for Skin Contact Remove contaminated clothing and shoes. Wash affected area with soap and water. If signs/symptoms develop, get medical attention. Wash contaminated clothing and clean shoes before reuse. Instructions for Inhalation If signs/symptoms develop, remove person to fresh air. If signs/symptoms persist, get medical attention. ------------------------------------------------------------------------ SECTION 6: FIRE FIGHTING MEASURES ------------------------------------------------------------------------ Suitable Extinguishing Media Use fire extinguishers with class B extinguishing agents (e.g., dry chemical, carbon dioxide). Fire Fighting Procedures Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and prevent explosive rupture. Water may be used to blanket the fire. Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatus (SCBA). Exposure Hazards during Fire Vapors may travel long distances along the ground or floor to an ignition source and flash back. ------------------------------------------------------------------------ SECTION 7: ACCIDENTAL RELEASE MEASURE ------------------------------------------------------------------------ Spill Response Not applicable. Methods for Disposal Not applicable. ------------------------------------------------------------------------ SECTION 8: HANDLING AND STORAGE ------------------------------------------------------------------------ Incompatible Materials Store away from heat. Store out of direct sunlight. Store away from oxidizing agents. Ventilation Keep container in well-ventilated area. Fire Prevention Ground containers securely when transferring contents. Wear low static or properly grounded shoes. Extremely flammable liquid and vapor. Explosion Prevention Keep away from heat, sparks, open flame, pilot lights and other sources of ignition. Static Prevention Avoid static discharge. Use Instructions Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Contents may be under pressure, open carefully. Keep container tightly closed. Avoid breathing of vapors, mists or spray. Avoid skin contact. Avoid eye contact with vapors, mists, or spray. Vapors may ignite explosively. May cause flash fire. Prevent build-up of vapors - open all windows and doors. Maintain vapor concentrations below recommended exposure limits. Use only with cross-ventilation. Without adequate ventilation, vapors may settle in low-lying areas. Keep away from heat, sparks, and open flame. Do not smoke or ignite matches, lighters, etc. For industrial or professional use only. Avoid contact with oxidizing agents. ------------------------------------------------------------------------ SECTION 9: EXP0SURE CONTROL AND PERSONAL PROTECTION ------------------------------------------------------------------------ DIMETHYL ETHER (115-10-6) Exposure Limits 1880 mg/m3 AIHA: TWA 1000 ppm AIHA: TWA 1000 ppm CMRG: TWA ACETONE (67-64-1) Exposure Limits 2380 mg/m3 ACGIH: STEL; Table A4; Comments: Added A4 per 2003 ACGIH updates LAM 750 ppm ACGIH: STEL; Table A4; Comments: Added A4 per 2003 ACGIH updates LAM 1780 mg/m3 ACGIH: TWA; Table A4; Comments: Added A4 per 2003 ACGIH updates LAM 500 ppm ACGIH: TWA; Table A4; Comments: Added A4 per 2003 ACGIH updates LAM PENTANE (109-66-0) Exposure Limits 600 ppm ACGIH: TWA 600 ppm ACGIH: TWA; Category: Pentane METHYL ACETATE (79-20-9) Exposure Limits 760 mg/m3 ACGIH: STEL 250 ppm ACGIH: STEL 606 mg/m3 ACGIH: TWA 200 ppm ACGIH: TWA PROPANE (74-98-6) Exposure Limits 2500 ppm ACGIH: TWA; Changed from Simple asphyxiant per 1998 ACGIH TLV booklet CYCLOHEXANE (110-82-7) Exposure Limits 100 ppm ACGIH: TWA; Comments: Changed limit values per May 2002 RDC database. Change on 7/22/02 does not require reissue. HYDROTREATED HEAVY NAPHTHA (PETROLEUM) (64742-48-9) Exposure Limits 100 ppm 3M: TWA Recommended Ventilation Use with functioning spray booth or local exhaust. Do not use in a confined area or areas with little or no air movement. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below Occupational Exposure Limits and/or control mist, vapor, or spray. If ventilation is not adequate, use respiratory protection equipment. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below Occupational Exposure Limits. If ventilation is not adequate, use respiratory protection equipment. Eye Protection Avoid eye contact with vapors, mists, or spray. The following should be worn alone or in combination, as appropriate, to prevent eye contact: Safety glasses with side shields Indirect Vented Goggles Hand Protection The following glove material(s) are recommended: nitrile rubber polyvinyl alcohol Skin Protection Avoid skin contact. Respiratory Protection Avoid breathing of vapors, mists or spray. Organic vapor cartridges may have short service life. Select one of the following approved respirators based on airborne concentration of contaminants and in accordance with regulations: Half facepiece or full facepiece air-purifying respirator suitable for organic vapors Ingestion Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. ------------------------------------------------------------------------ SECTION 10: STABILITY AND REACTIVITY ------------------------------------------------------------------------ Conditions to Avoid Sparks and/or Flames Heat Materials to Avoid Strong Oxidizing Agents Hazardous Decomposition Hydrocarbons During Combustion Formaldehyde During Combustion Carbon monoxide During Combustion Carbon dioxide During Combustion Stability and Reactivity Hazardous polymerization will not occur. Stable This material may be reactive with certain agents under certain conditions - see the remaining headings in this section ------------------------------------------------------------------------ SECTION 11: TOXICOLOGICAL INFORMATION ------------------------------------------------------------------------ Effects from Eye Contact Corrosive (Eye Burns): Signs/symptoms may include cloudy appearance of the cornea, chemical burns, severe pain, tearing, ulcerations, significantly impaired vision or complete loss of vision. Effects from Skin Contact Moderate Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness. Effects from Inhalation Intentional concentration and inhalation may be harmful or fatal. Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. May be absorbed following inhalation and cause target organ effects. Effects from Ingestion Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. May be absorbed following ingestion and cause target organ effects. Other Toxicological Information Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness. ------------------------------------------------------------------------ SECTION 12: ECOLOGICAL INFORMATION ------------------------------------------------------------------------ Environmental Data No data available. Ecotoxicity Data Not determined. Ecofate Data Not determined. ------------------------------------------------------------------------ SECTION 13: DISPOSAL INFORMATION ------------------------------------------------------------------------ Product as Sold Incinerate in a permitted hazardous waste incinerator. As a disposal alternative, dispose of waste product in a permitted hazardous waste facility. The facility should be equipped to handle gaseous waste. ------------------------------------------------------------------------ SECTION 14: TRANSPORT INFORMATION ------------------------------------------------------------------------ UN Number IATA- UN3161, LIQUEFIED GAS, FLAMMABLE, N.O.S., (DIMETHYL ETHER AND PROPANE), 2.1 IMO- UN3161, LIQUEFIED GAS, FLAMMABLE, N.O.S., (DIMETHYL ETHER AND PROPANE), 2.1 IMO Class IMO- UN3161, LIQUEFIED GAS, FLAMMABLE, N.O.S., (DIMETHYL ETHER AND PROPANE), 2.1 ICAO Class IATA- UN3161, LIQUEFIED GAS, FLAMMABLE, N.O.S., (DIMETHYL ETHER AND PROPANE), 2.1 Special Instructions Transportation classifications are provided as a customer service. As for shipping, YOU remain responsible for complying with all applicable laws and regulations, including proper transportation classification and packaging. 3M's transportation classifications are based on product formulation, packaging, 3M policies and 3M's understanding of applicable current regulations. 3M does not guarantee the accuracy of this classification information. This information applies only to transportation classification and not the packaging, labeling or marking requirements. The above information is only for reference. If you are shipping by air or ocean, YOU are advised to check & meet applicable regulatory requirements. ------------------------------------------------------------------------ SECTION 15: REGULATORY INFORMATION ------------------------------------------------------------------------ Symbols F+ Extremely Flammable Xi Irritant N Dangerous to environment Risk Phrases Extremely flammable. Risk of serious damage to eyes. Repeated exposure may cause skin dryness or cracking. Vapours may cause drowsiness and dizziness. Toxic to aquatic organisms. May cause long-term adverse effects in the aquatic environment. Safety Phrases Keep away from sources of ignition - No Smoking. Do not breathe vapor or spray. Use only in well ventilated areas. Avoid contact with skin. Wear eye protection. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Avoid release to the environment. Refer to special instructions/safety data sheets. Special Regulatory Information Contact 3M for more information. ------------------------------------------------------------------------ SECTION 16: OTHER INFORMATION ------------------------------------------------------------------------ The information on this data sheet represents our current data and best opinion as to the proper use in handling of this product under normal conditions. Any use of the product which is not in conformance with this data sheet or which involves using the product in combination with any other product or any other process is the responsibility of the user.