3M MALAYSIA SDN BHD ======================================================================== CHEMICAL SAFETY DATA SHEET ======================================================================== Document id : 28-7899-9 Issue date : 13/12/2011 Version : 1.00 Supersedes date : --- Document status : Issued This CSDS has been prepared by Toxicology Department 3M Malaysia Sdn. Bhd. ------------------------------------------------------------------------ SECTION 1: CHEMICAL PRODUCT AND COMPANY IDENTIFICATION ------------------------------------------------------------------------ Tradename 3M(TM) Hybrid Adhesive Sealant Fast Cure 4000 UV, White 3M Product ID: 62-5563-3532-1, 62-5563-3932-3, 62-5563-9532-5 Intended Use of Product Industrial Adhesive COMPANY IDENTIFICATION ---------------------- Manufacturer's name and address 3M 3M Center St. Paul, Minnesota 55144-1000 USA Importer's name and address 3M Malaysia Sdn. Bhd. Bangunan 3M No. 6, Persiaran Tropicana 47410 Petaling Jaya Selangor Telephone number 03-7806-2888 Emergency telephone number 1-651-7376501 ( 24 hours ) CONTACT POINT ------------- Designation Toxicology Coordinator Telephone number 03-7806-2888 ------------------------------------------------------------------------ SECTION 2: COMPOSITION/INFORMATION ON INGREDIENT ------------------------------------------------------------------------ Ingredient name CAS number Percentage ------------------------------------- ------------------ ------------- CALCIUM CARBONATE 471-34-1 30 - 60 Exposure Limits: 20 mg/m3 CMRG: STEL 10 mg/m3 CMRG: TWA Polyether - N.J.T.S. Reg. No. Trade Secret 15 - 40 04499600-6434 DIISODECYL PHTHALATE 68515-49-1 10 - 20 Exposure Limits: 5 mg/m3 CMRG: TWA TITANIUM DIOXIDE 13463-67-7 5 - 10 Exposure Limits: 10 mg/m3 ACGIH: TWA 5 mg/m3 CMRG: TWA; as respirable dust; Comments: DUPONT MSDS DATED 11/16/99 FOR 11-0001-3049-9. N-(3-(trimethoxysilyl)propyl) 1760-24-3 0.5 - 1.5 ethylene diamine Dioctyltinbis(acetylacetonate) 54068-28-9 0.1 - 0.5 ------------------------------------------------------------------------ SECTION 3: PHYSICAL AND CHEMICAL PROPERTIES ------------------------------------------------------------------------ Physical form,Color,Odor Solid Paste White viscous liquid with slight odor. Water Solubility NOT DETERMINED Boiling point/boiling range N/A Melting point/melting range N/A Vapour pressure N/A Percent Volatile 0.93 % by wt Evaporation rate N/A Vapour density N/A Specific gravity 1.3 - 1.5 Water=1 Flash point NIL Autoflammability NOT DETERMINED Flammable Limits - LEL N/A Flammable Limits - UEL N/A Viscosity NOT DETERMINED ------------------------------------------------------------------------ SECTION 4: HAZARD IDENTIFICATION ------------------------------------------------------------------------ Risk Phrases Contains (trimethoxysilylpropyl) ethylenediamine CONTAINS Tin, dioctylbis(2,4-pentanedionato-.kappa.O2,.kappa.O4)- May produce an allergic reaction. ------------------------------------------------------------------------ SECTION 5: FIRST AID MEASURES ------------------------------------------------------------------------ Instructions for Ingestion Do not induce vomiting unless instructed to do so by medical personnel. Give victim two glasses of water. Never give anything by mouth to an unconscious person. Get medical attention. Instructions for Eye Contact Flush eyes with large amounts of water. If signs/symptoms persist, get medical attention. Instructions for Skin Contact Remove contaminated clothing and shoes. Wash affected area with soap and water. If signs/symptoms develop, get medical attention. Wash contaminated clothing and clean shoes before reuse. Instructions for Inhalation If signs/symptoms develop, remove person to fresh air. If signs/symptoms persist, get medical attention. ------------------------------------------------------------------------ SECTION 6: FIRE FIGHTING MEASURES ------------------------------------------------------------------------ Suitable Extinguishing Media Use fire extinguishers with class B extinguishing agents (e.g., dry chemical, carbon dioxide). Fire Fighting Procedures Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatus (SCBA). Exposure Hazards during Fire No unusual fire or explosion hazards are anticipated. ------------------------------------------------------------------------ SECTION 7: ACCIDENTAL RELEASE MEASURE ------------------------------------------------------------------------ Spill Response Not applicable. Methods for Disposal Not applicable. ------------------------------------------------------------------------ SECTION 8: HANDLING AND STORAGE ------------------------------------------------------------------------ Storage Requirements Store in a cool, dry place. Incompatible Materials Store away from heat. Store out of direct sunlight. Use Instructions Avoid eye contact. Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Keep container tightly closed. Avoid breathing of vapors. Avoid breathing of dust created by cutting, sanding, grinding or machining. Do not ingest. Avoid skin contact. ------------------------------------------------------------------------ SECTION 9: EXP0SURE CONTROL AND PERSONAL PROTECTION ------------------------------------------------------------------------ CALCIUM CARBONATE (471-34-1) Exposure Limits 20 mg/m3 CMRG: STEL 10 mg/m3 CMRG: TWA DIISODECYL PHTHALATE (68515-49-1) Exposure Limits 5 mg/m3 CMRG: TWA TITANIUM DIOXIDE (13463-67-7) Exposure Limits 10 mg/m3 ACGIH: TWA 5 mg/m3 CMRG: TWA; as respirable dust; Comments: DUPONT MSDS DATED 11/16/99 FOR 11-0001-3049-9. Recommended Ventilation Use in a well-ventilated area. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below Occupational Exposure Limits and/or control mist, vapor, or spray. If ventilation is not adequate, use respiratory protection equipment. Eye Protection Avoid eye contact. The following should be worn alone or in combination, as appropriate, to prevent eye contact: Indirect Vented Goggles Hand Protection The following glove material(s) are recommended: polyethylene polyvinyl alcohol Skin Protection Avoid skin contact. Respiratory Protection Avoid breathing of vapors. Avoid breathing of dust created by cutting, sanding, grinding or machining. Select one of the following approved respirators based on airborne concentration of contaminants and in accordance with regulations: Half facepiece or fullface air-purifying respirator with organic vapor cartridges and N95 particulate prefilters Ingestion Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. ------------------------------------------------------------------------ SECTION 10: STABILITY AND REACTIVITY ------------------------------------------------------------------------ Conditions to Avoid Heat Materials to Avoid Amines Alcohols Water Hazardous Decomposition Carbon monoxide During Combustion Carbon dioxide During Combustion Irritant Vapors or Gases During Combustion Stability and Reactivity Hazardous polymerization will not occur. Stable This material may be reactive with certain agents under certain conditions - see the remaining headings in this section ------------------------------------------------------------------------ SECTION 11: TOXICOLOGICAL INFORMATION ------------------------------------------------------------------------ Effects from Eye Contact Mild Eye Irritation: Signs/symptoms may include redness, pain, and tearing. Effects from Skin Contact Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, and itching. Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering and itching. Effects from Inhalation Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Effects from Ingestion Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. May be absorbed following ingestion and cause target organ effects. Sensitization Information Persons previously sensitized to amines may develop a cross-sensitization reaction to certain other amines. Reproductive Effects Contains a chemical or chemicals which can cause birth defects or other reproductive harm. ------------------------------------------------------------------------ SECTION 12: ECOLOGICAL INFORMATION ------------------------------------------------------------------------ Environmental Data No data available. Ecotoxicity Data Not determined. Ecofate Data Not determined. Special statements for 2001/58/EC A conservative assessment indicates this product presents a low environmental risk because use and disposal are unlikely to result in the significant release of components to the environment. Other Ecotoxicity Information Take precautions to prevent direct release of this product to the environment. ------------------------------------------------------------------------ SECTION 13: DISPOSAL INFORMATION ------------------------------------------------------------------------ Product as Sold Do not release to ground water or waterways. Dispose of completely cured (or polymerized) material in a facility permitted to accept chemical wastes. As a disposal alternative, incinerate uncured product in an industrial or commercial incinerator in the presence of a combustible material. ------------------------------------------------------------------------ SECTION 14: TRANSPORT INFORMATION ------------------------------------------------------------------------ UN Number NOT HAZARDOUS FOR TRANSPORT FOR DOT, IMO, OR IATA. IMO Class NOT HAZARDOUS FOR TRANSPORT FOR DOT, IMO, OR IATA. ICAO Class Special Instructions Transportation classifications are provided as a customer service. As for shipping, YOU remain responsible for complying with all applicable laws and regulations, including proper transportation classification and packaging. 3M's transportation classifications are based on product formulation, packaging, 3M policies and 3M's understanding of applicable current regulations. 3M does not guarantee the accuracy of this classification information. This information applies only to transportation classification and not the packaging, labeling or marking requirements. The above information is only for reference. If you are shipping by air or ocean, YOU are advised to check & meet applicable regulatory requirements. ------------------------------------------------------------------------ SECTION 15: REGULATORY INFORMATION ------------------------------------------------------------------------ Symbols None Risk Phrases Contains (trimethoxysilylpropyl) ethylenediamine CONTAINS Tin, dioctylbis(2,4-pentanedionato-.kappa.O2,.kappa.O4)- May produce an allergic reaction. Safety Phrases None Special Regulatory Information Contact 3M for more information. ------------------------------------------------------------------------ SECTION 16: OTHER INFORMATION ------------------------------------------------------------------------ The information on this data sheet represents our current data and best opinion as to the proper use in handling of this product under normal conditions. Any use of the product which is not in conformance with this data sheet or which involves using the product in combination with any other product or any other process is the responsibility of the user.