3M MALAYSIA SDN BHD ======================================================================== CHEMICAL SAFETY DATA SHEET ======================================================================== Document id : 10-2796-0 Issue date : 09/10/2012 Version : 1.00 Supersedes date : --- Document status : Issued This CSDS has been prepared by Toxicology Department 3M Malaysia Sdn. Bhd. ------------------------------------------------------------------------ SECTION 1: CHEMICAL PRODUCT AND COMPANY IDENTIFICATION ------------------------------------------------------------------------ Tradename 3M(TM) Scotch-Weld(TM) Neoprene Rubber and Gasket Adhesive 2141 3M Product ID: 62-2141-2630-2, 62-2141-5530-1, 62-2141-6530-0, 62-2141-6535-9, 62-2141-7530-9, 62-2141-8530-8, 62-2141-9530-7, RE-0009-6552-5, XS-0414-1079-5 Intended Use of Product Industrial use COMPANY IDENTIFICATION ---------------------- Manufacturer's name and address 3M 3M Center St. Paul, Minnesota 55144-1000 USA Importer's name and address 3M Malaysia Sdn. Bhd. Bangunan 3M No. 6, Persiaran Tropicana 47410 Petaling Jaya Selangor Telephone number 03-7806-2888 Emergency telephone number 1-651-7376501 ( 24 hours ) CONTACT POINT ------------- Designation Toxicology Coordinator Telephone number 03-7806-2888 ------------------------------------------------------------------------ SECTION 2: COMPOSITION/INFORMATION ON INGREDIENT ------------------------------------------------------------------------ Ingredient name CAS number Percentage ------------------------------------- ------------------ ------------- TOLUENE 108-88-3 30 - 40 Exposure Limits: 20 ppm ACGIH: TWA 75 ppm CMRG: STEL; skin contact contributes to exposure; Comments: ROHM & HAAS MSDS DATED 2/20/01 FOR 11-0018-3267-1. LIGHT SOLVENT NAPTHA 64741-84-0 15 - 25 ACETONE 67-64-1 10 - 20 Exposure Limits: 750 ppm ACGIH: STEL 500 ppm ACGIH: TWA GLYCEROL ESTERS OF ROSIN ACIDS 8050-31-5 1 - 5 ZINC OXIDE 1314-13-2 < 1 Exposure Limits: 10 mg/m3 ACGIH: STEL; respirable fraction 2 mg/m3 ACGIH: TWA; respirable fraction Magnesium resinate 68037-42-3 10 - 20 POLYCHLOROPRENE 9010-98-4 10 - 20 HEXANE 110-54-3 3 - 8 Exposure Limits: 50 ppm ACGIH: TWA; skin contact contributes to exposure 50 ppm ACGIH: TWA; skin contact contributes to exposure; Category: Hexane ------------------------------------------------------------------------ SECTION 3: PHYSICAL AND CHEMICAL PROPERTIES ------------------------------------------------------------------------ Physical form,Color,Odor Liquid Tan, sweet petroleum odor. medium syrup Water Solubility <<< Boiling point/boiling range >= 56 C DETAILS: Acetone Melting point/melting range N/A Vapour pressure <= 185 mmHg CONDITIONS: @ 20.0 C Percent Volatile 65 - 75 % by wt Evaporation rate >= 2.5 Vapour density 2 Specific gravity 0.86 Water=1 Flash point -20.0 C CC DETAILS: Petroleum Distillate Autoflammability 465 C Flammable Limits - LEL 1 % by vol Flammable Limits - UEL 12.8 % by vol Viscosity 900 - 1500 centipoise CONDITIONS: @ 23.0 C ------------------------------------------------------------------------ SECTION 4: HAZARD IDENTIFICATION ------------------------------------------------------------------------ Risk Phrases Highly flammable. Irritating to skin. Vapours may cause drowsiness and dizziness. Harmful: danger of serious damage to health by prolonged exposure through inhalation. Possible risk of impaired fertility. Possible risk of harm to the unborn child. Toxic to aquatic organisms. May cause long-term adverse effects in the aquatic environment. ------------------------------------------------------------------------ SECTION 5: FIRST AID MEASURES ------------------------------------------------------------------------ Instructions for Ingestion Do not induce vomiting unless instructed to do so by medical personnel. Give victim two glasses of water. Never give anything by mouth to an unconscious person. Get medical attention. Instructions for Eye Contact Flush eyes with large amounts of water. If signs/symptoms persist, get medical attention. Instructions for Skin Contact Remove contaminated clothing and shoes. Wash affected area with soap and water. If signs/symptoms develop, get medical attention. Wash contaminated clothing and clean shoes before reuse. Instructions for Inhalation If signs/symptoms develop, remove person to fresh air. If signs/symptoms persist, get medical attention. ------------------------------------------------------------------------ SECTION 6: FIRE FIGHTING MEASURES ------------------------------------------------------------------------ Suitable Extinguishing Media Use fire extinguishers with class B extinguishing agents (e.g., dry chemical, carbon dioxide). Fire Fighting Procedures Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and prevent explosive rupture. Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatus (SCBA). Exposure Hazards during Fire Closed containers exposed to heat from fire may build pressure and explode. Vapors may travel long distances along the ground or floor to an ignition source and flash back. ------------------------------------------------------------------------ SECTION 7: ACCIDENTAL RELEASE MEASURE ------------------------------------------------------------------------ Spill Response Not applicable. Methods for Disposal Not applicable. ------------------------------------------------------------------------ SECTION 8: HANDLING AND STORAGE ------------------------------------------------------------------------ Incompatible Materials Store away from acids. Store away from heat. Store out of direct sunlight. Store away from oxidizing agents. Ventilation Keep container in well-ventilated area. Fire Prevention Ground containers securely when transferring contents. Wear low static or properly grounded shoes. Extremely flammable liquid and vapor. Static Prevention Avoid static discharge. Use Instructions Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Contents may be under pressure, open carefully. Keep container tightly closed. Avoid breathing of vapors, mists or spray. Avoid eye contact with vapors, mists, or spray. Vapors may ignite explosively. May cause flash fire. Prevent build-up of vapors - open all windows and doors. Maintain vapor concentrations below recommended exposure limits. Use only with cross-ventilation. Without adequate ventilation, vapors may settle in low-lying areas. Keep away from heat, sparks, and open flame. Do not smoke or ignite matches, lighters, etc. For industrial or professional use only. Do not breathe vapors. Avoid contact with oxidizing agents. ------------------------------------------------------------------------ SECTION 9: EXP0SURE CONTROL AND PERSONAL PROTECTION ------------------------------------------------------------------------ TOLUENE (108-88-3) Exposure Limits 20 ppm ACGIH: TWA 75 ppm CMRG: STEL; skin contact contributes to exposure; Comments: ROHM & HAAS MSDS DATED 2/20/01 FOR 11-0018-3267-1. ACETONE (67-64-1) Exposure Limits 750 ppm ACGIH: STEL 500 ppm ACGIH: TWA ZINC OXIDE (1314-13-2) Exposure Limits 10 mg/m3 ACGIH: STEL; respirable fraction 2 mg/m3 ACGIH: TWA; respirable fraction HEXANE (110-54-3) Exposure Limits 50 ppm ACGIH: TWA; skin contact contributes to exposure 50 ppm ACGIH: TWA; skin contact contributes to exposure; Category: Hexane Recommended Ventilation Use with appropriate local exhaust ventilation. Provide appropriate local exhaust ventilation at transfer points. Provide appropriate local exhaust ventilation on open containers. Use in an enclosed process area is recommended. Do not use in a confined area or areas with little or no air movement. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below Occupational Exposure Limits and/or control mist, vapor, or spray. If ventilation is not adequate, use respiratory protection equipment. Eye Protection Avoid eye contact with vapors, mists, or spray. The following should be worn alone or in combination, as appropriate, to prevent eye contact: Indirect Vented Goggles Hand Protection The following glove material(s) are recommended: butyl rubber Polymer laminate Skin Protection Avoid skin contact. Respiratory Protection Avoid breathing of vapors, mists or spray. Avoid breathing of vapors. Do not breathe vapors. Select one of the following approved respirators based on airborne concentration of contaminants and in accordance with regulations: Half facepiece or full facepiece air-purifying respirator suitable for organic vapors Ingestion Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. ------------------------------------------------------------------------ SECTION 10: STABILITY AND REACTIVITY ------------------------------------------------------------------------ Conditions to Avoid Sparks and/or Flames Heat Materials to Avoid Strong Oxidizing Agents Hazardous Decomposition Aldehydes During Combustion Carbon monoxide During Combustion Carbon dioxide During Combustion Stability and Reactivity Hazardous polymerization will not occur. Stable ------------------------------------------------------------------------ SECTION 11: TOXICOLOGICAL INFORMATION ------------------------------------------------------------------------ Effects from Eye Contact Moderate Eye Irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision. Prolonged or repeated exposure may cause: Ocular Effects: Signs/symptoms may include blurred or significantly impaired vision. Effects from Skin Contact Severe Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, dryness, cracking, blistering, and pain. Effects from Inhalation Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. May be absorbed following inhalation and cause target organ effects. Prolonged or repeated exposure may cause: Respiratory Effects: Signs/symptoms may include cough, shortness of breath, chest tightness, wheezing, increased heart rate, bluish colored skin (cyanosis), sputum production, changes in lung function tests, and/or respiratory failure. Effects from Ingestion Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. May be absorbed following ingestion and cause target organ effects. Reproductive Effects Contains a chemical or chemicals which can cause birth defects or other reproductive harm. Other Toxicological Information Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness. Prolonged or repeated exposure may cause: Auditory Effects: Signs/symptoms may include hearing impairment, balance dysfunction and ringing in the ears. Olfactory Effects: Signs/symptoms may include decreased ability to detect odors and/or complete loss of smell. Neurological Effects: Signs/symptoms may include personality changes, lack of coordination, sensory loss, tingling or numbness of the extremities, weakness, tremors, and/or changes in blood pressure and heart rate. ------------------------------------------------------------------------ SECTION 12: ECOLOGICAL INFORMATION ------------------------------------------------------------------------ Environmental Data No data available. Ecotoxicity Data Not determined. Ecofate Data Not determined. ------------------------------------------------------------------------ SECTION 13: DISPOSAL INFORMATION ------------------------------------------------------------------------ Product as Sold Incinerate in a permitted hazardous waste incinerator. As a disposal alternative, dispose of waste product in a permitted hazardous waste facility. ------------------------------------------------------------------------ SECTION 14: TRANSPORT INFORMATION ------------------------------------------------------------------------ UN Number IATA - UN1133, ADHESIVES, 3, II IMO - UN1133, ADHESIVES, 3, II, LIMITED QUANTITY, MARINE POLLUTANT, (NAPTHA(PETROLEUM), SOLVENT-REFINED LIGHT AND ZINC OXIDE), -020C IMO Class UN1133, ADHESIVES, 3, II, LIMITED QUANTITY, MARINE POLLUTANT, (NAPTHA(PETROLEUM), SOLVENT-REFINED LIGHT AND ZINC OXIDE), -020C ICAO Class UN1133, ADHESIVES, 3, II Special Instructions Transportation classifications are provided as a customer service. As for shipping, YOU remain responsible for complying with all applicable laws and regulations, including proper transportation classification and packaging. 3M's transportation classifications are based on product formulation, packaging, 3M policies and 3M's understanding of applicable current regulations. 3M does not guarantee the accuracy of this classification information. This information applies only to transportation classification and not the packaging, labeling or marking requirements. The above information is only for reference. If you are shipping by air or ocean, YOU are advised to check & meet applicable regulatory requirements. ------------------------------------------------------------------------ SECTION 15: REGULATORY INFORMATION ------------------------------------------------------------------------ Symbols Xn Harmful F Highly Flammable N Dangerous to environment Risk Phrases Highly flammable. Irritating to skin. Vapours may cause drowsiness and dizziness. Harmful: danger of serious damage to health by prolonged exposure through inhalation. Possible risk of impaired fertility. Possible risk of harm to the unborn child. Toxic to aquatic organisms. May cause long-term adverse effects in the aquatic environment. Safety Phrases Do not breathe vapor. Keep away from sources of ignition - No Smoking. Wear suitable protective clothing and gloves. If swallowed, do not induce vomiting: Seek medical advice immediately and show this container or label. Avoid release to the environment. Refer to special instructions/safety data sheets. Special Regulatory Information Contact 3M for more information. ------------------------------------------------------------------------ SECTION 16: OTHER INFORMATION ------------------------------------------------------------------------ The information on this data sheet represents our current data and best opinion as to the proper use in handling of this product under normal conditions. Any use of the product which is not in conformance with this data sheet or which involves using the product in combination with any other product or any other process is the responsibility of the user.