3M MALAYSIA SDN BHD ======================================================================== CHEMICAL SAFETY DATA SHEET ======================================================================== Document id : 10-2611-1 Issue date : 05/10/2006 Version : 2.00 Supersedes date : 21/03/2005 Document status : Issued This CSDS has been prepared by Toxicology Department 3M Malaysia Sdn. Bhd. ------------------------------------------------------------------------ SECTION 1: CHEMICAL PRODUCT AND COMPANY IDENTIFICATION ------------------------------------------------------------------------ Tradename SCOTCHCAST BRAND ELECTRICAL INSULATING RESIN 2104 3M Product ID: 78-8018-9985-3, 78-8019-0094-1, 78-8019-0095-8, 78-8019-0233-5, 78-8019-0234-3, 80-6100-7143-5, 80-6100-7360-5, 80-6100-7365-4, 80-6100-7661-6, 80-6100-7662-4, 80-6107-3738-1, 80-6107-3739-9, 80-6112-1872-0, 80-6112-1873-8, 80-6112-1874-6, 80-6112-1875-3, 80-6112-1876-1 Intended Use of Product COMPANY IDENTIFICATION ---------------------- Manufacturer's name and address 3M 3M Center St. Paul, Minnesota 55144-1000 USA Importer's name and address 3M Malaysia Sdn. Bhd. Bangunan 3M No. 6, Persiaran Tropicana 47410 Petaling Jaya Selangor Telephone number 03-7806-2888 Emergency telephone number 1-651-7376501 ( 24 hours ) CONTACT POINT ------------- Designation Toxicology Coordinator Telephone number 03-7806-2888 ------------------------------------------------------------------------ SECTION 2: COMPOSITION/INFORMATION ON INGREDIENT ------------------------------------------------------------------------ Ingredient name CAS number Percentage ------------------------------------- ------------------ ------------- PART A: DITRIDECYL PHTHALATE 119-06-2 30 - 45 MDI POLYURETHANE PREPOLYMER 68442-03-5 15 - 25 POLYMETHYLENE POLYPHENYLENE 9016-87-9 15 - 25 ISOCYANATE C.I. SOLVENT YELLOW 3 97-56-3 < 0.015 P,P'-METHYLENEBIS(PHENYL ISOCYANATE) 101-68-8 15 - 20 1,1'-METHYLENEBIS(ISOCYANATOBENZENE) 26447-40-5 1 - 5 PART B: POLYPROPYLENE GLYCOL 25791-96-2 55 - 65 GLYCEROL TRIETHER N,N-DI(2-HYDROXYPROPYL)ANILINE 3077-13-2 10.0 - 20.0 DITRIDECYL PHTHALATE 119-06-2 10.0 - 20.0 DIPROPYLENE GLYCOL 25265-71-8 5.0 - 10.0 ------------------------------------------------------------------------ SECTION 3: PHYSICAL AND CHEMICAL PROPERTIES ------------------------------------------------------------------------ Physical form,Color,Odor PREPOLYMER: Green, viscous liquid. POLYOL: Amber liquid. Water Solubility Reacts. Boiling point/boiling range N/A Melting point/melting range NOT DETERMINED Vapour pressure N/A Percent Volatile No data available. Evaporation rate N/A Vapour density N/A Specific gravity PRE.:1.05. POL.:1.00. Flash point Both >270F. Closed Cup. Autoflammability NOT DETERMINED Flammable Limits - LEL NOT DETERMINED Flammable Limits - UEL NOT DETERMINED Viscosity PRE.:17p. POL.:6p. ------------------------------------------------------------------------ SECTION 4: HAZARD IDENTIFICATION ------------------------------------------------------------------------ Risk Phrases Harmful by inhalation. Risk of serious damage to eyes. Irritating to respiratory system and skin. May cause sensitization by inhalation and skin contact. ------------------------------------------------------------------------ SECTION 5: FIRST AID MEASURES ------------------------------------------------------------------------ Instructions for Ingestion Do not induce vomiting. Drink two glasses of water. Call a physician. Instructions for Eye Contact Immediately flush eyes with large amounts of water. Get immediate medical attention. Instructions for Skin Contact Immediately wash skin with soap and large amounts of water. Remove contaminated clothing. If signs/symptoms occur, call a physician. Wash contaminated clothing before reuse and dispose of contaminated shoes. Instructions for Inhalation If signs/symptoms occur, remove person to fresh air. If signs/symptoms continue, call a physician. ------------------------------------------------------------------------ SECTION 6: FIRE FIGHTING MEASURES ------------------------------------------------------------------------ Suitable Extinguishing Media Carbon dioxide Dry chemical Foam Fire Fighting Procedures Wear full protective clothing, including helmet, self-contained, positive pressure or pressure demand breathing apparatus, bunker coat and pants, bands around arms, waist and legs, face mask, and protective covering for exposed areas of the head. ------------------------------------------------------------------------ SECTION 7: ACCIDENTAL RELEASE MEASURE ------------------------------------------------------------------------ Spill Response Not applicable. Methods for Disposal Not applicable. Special Instructions, Accidental Release Follow precautionary information. PREPOLYMER: Wear an organic vapor mask. Pour decontaminant (8% conc. ammonia, 2% liquid detergent, 90% water) over spill and react 10 minutes. If these reagents are not available, use water and allow a longer reaction time. Pour adsorbent over neutralized spill. Collect and drum. Let drum sit with excess decontaminant for 24 hours before sealing. POLYOL: Pour adsorbent over spill. Collect and drum. ------------------------------------------------------------------------ SECTION 8: HANDLING AND STORAGE ------------------------------------------------------------------------ Storage Requirements Not applicable. Fire Prevention Not applicable. ------------------------------------------------------------------------ SECTION 9: EXP0SURE CONTROL AND PERSONAL PROTECTION ------------------------------------------------------------------------ P,P'-METHYLENEBIS(PHENYL ISOCYANATE) (101-68-8) Exposure Limits 0.02 ppm 0.005 ppm 0.051 mg/m3 0.005 ppm 3M: STEL - Category: FREE ISOCYANATES 3M: TWA - Category: FREE ISOCYANATES ACGIH: TWA ACGIH: TWA 1,1'-METHYLENEBIS(ISOCYANATOBENZENE) (26447-40-5) Exposure Limits 0.02 ppm 0.005 ppm 0.051 mg/m3 0.005 ppm 3M: STEL - Category: FREE ISOCYANATES 3M: TWA - Category: FREE ISOCYANATES ACGIH: TWA ACGIH: TWA Recommended Ventilation Use with appropriate local exhaust ventilation. Provide ventilated enclosure for heat curing. Use in a well-ventilated area. If exhaust ventilation is not adequate, use appropriate respiratory protection. Eye Protection Avoid eye contact. Hand Protection Wear appropriate gloves when handling this material. Skin Protection Avoid prolonged or repeated skin contact. Respiratory Protection Avoid breathing of vapors created during the cure cycle. Avoid prolonged breathing of vapors. Select one of the following approved respirators based on airborne concentration of contaminants and in accordance with regulations: half-mask supplied air respirator Ingestion Wash hands after handling and before eating. ------------------------------------------------------------------------ SECTION 10: STABILITY AND REACTIVITY ------------------------------------------------------------------------ Materials to Avoid Amines Alcohols Water Reaction with water, alcohols and amines is not hazardous if container can vent to the atmosphere to prevent pressure buildup. This refers to Part A (prepolymer). Hazardous Decomposition Carbon Monoxide and Carbon Dioxide Oxides of Nitrogen Hydrogen Cyanide Isocyanates Toxic Vapors, Gases or Particulates Irritant Vapors or Gases Stability and Reactivity Stable Hazardous polymerization will not occur. ------------------------------------------------------------------------ SECTION 11: TOXICOLOGICAL INFORMATION ------------------------------------------------------------------------ Effects from Eye Contact Mild Eye Irritation: Signs/symptoms may include redness, pain, and tearing. Effects from Skin Contact Mild Skin Irritation (after prolonged or repeated contact): signs/symptoms can include redness, swelling, and itching. Effects from Inhalation PREPOLYMER contains methylene bisphenyl diisocyanate (MDI) which is a respiratory irritant and may cause respiratory sensitization resulting in asthmatic-like symptoms. The low vapor pressure of MDI precludes significant hazard at room temperature. Effects from Ingestion Swallowing a relatively large amount of this material is unlikely to produce serious illness or death. Other Toxicological Information Part A (prepolymer) and the mixture of Part A with Part B (polyol) may cause an allergic skin reaction in certain susceptible individuals. ------------------------------------------------------------------------ SECTION 12: ECOLOGICAL INFORMATION ------------------------------------------------------------------------ Environmental Data No data available. Other Ecotoxicity Information No data available. ------------------------------------------------------------------------ SECTION 13: DISPOSAL INFORMATION ------------------------------------------------------------------------ Product as Sold Special Instructions for Disposal PREPOLYMER or POLYOL: Should be buried in a secure landfill or incinerated in accordance with local and state regulations. Cured resin may be buried in a sanitary landfill in accordance with local and state regulations. ------------------------------------------------------------------------ SECTION 14: TRANSPORT INFORMATION ------------------------------------------------------------------------ UN Number IMO Class ICAO Class Special Instructions ** NOT HAZARDOUS FOR TRANSPORT FOR DOT, IMO, OR IATA. ------------------------------------------------------------------------ SECTION 15: REGULATORY INFORMATION ------------------------------------------------------------------------ Symbols Xn Harmful Risk Phrases Harmful by inhalation. Risk of serious damage to eyes. Irritating to respiratory system and skin. May cause sensitization by inhalation and skin contact. Safety Phrases Use only in well ventilated areas. Do not breathe vapor. S24/25 Avoid contact with the skin and eyes. Wear suitable gloves and eye and face protection. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S28B After contact with skin, wash immediately with plenty of water. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Contains isocyanates. See information supplied by manufacturer. ------------------------------------------------------------------------ SECTION 16: OTHER INFORMATION ------------------------------------------------------------------------ Reason for Reissue ADDED STOCK NUMBERS The information on this data sheet represents our current data and best opinion as to the proper use in handling of this product under normal conditions. Any use of the product which is not in conformance with this data sheet or which involves using the product in combination with any other product or any other process is the responsibility of the user.