3M MALAYSIA SDN BHD ======================================================================== CHEMICAL SAFETY DATA SHEET ======================================================================== Document id : 10-2676-4 Issue date : 20/02/2012 Version : 5.00 Supersedes date : 23/04/2008 Document status : Issued This CSDS has been prepared by Toxicology Department 3M Malaysia Sdn. Bhd. ------------------------------------------------------------------------ SECTION 1: CHEMICAL PRODUCT AND COMPANY IDENTIFICATION ------------------------------------------------------------------------ Tradename SCOTCH-WELD (TM) 2214 HIGH DENSITY EPOXY ADHESIVE 3M Product ID: 62-3414-2930-6, 62-3414-2932-2, 62-3414-2935-5, 62-3414-8530-8 Intended Use of Product Industrial use COMPANY IDENTIFICATION ---------------------- Manufacturer's name and address 3M 3M Center St. Paul, Minnesota 55144-1000 USA Importer's name and address 3M Malaysia Sdn. Bhd. Bangunan 3M No. 6, Persiaran Tropicana 47410 Petaling Jaya Selangor Telephone number 03-7806-2888 Emergency telephone number 1-651-7376501 ( 24 hours ) CONTACT POINT ------------- Designation Toxicology Coordinator Telephone number 03-7806-2888 ------------------------------------------------------------------------ SECTION 2: COMPOSITION/INFORMATION ON INGREDIENT ------------------------------------------------------------------------ Ingredient name CAS number Percentage ------------------------------------- ------------------ ------------- EPOXY RESIN 25068-38-6 30 - 60 ALUMINUM PIGMENTS 7429-90-5 30 - 60 Exposure Limits: 1 mg/m3 ACGIH: TWA; respirable fraction 1 mg/m3 ACGIH: TWA; respirable fraction; Category: Aluminum Synthetic Elastomer - N.J.T.S. Reg Trade Secret 1 - 5 No. 04499600-5709P Epoxy Resin 41638-13-5 1 - 5 AMORPHOUS SILICA 67762-90-7 1 - 5 Exposure Limits: 5 mg/m3 CMRG: CEIL; Comments: DOC CORNING MSDS DATED 9/10/97 FOR 11-0003-9094-5. PARA-CHLOROPHENOL-DIMETHYLUREA 150-68-5 1 - 5 DICYANDIAMIDE 461-58-5 1 - 5 1,4-BIS[(2,3-EPOXYPROPOXY)METHYL] 14228-73-0 0.1 - 1 CYCLOHEXANE ------------------------------------------------------------------------ SECTION 3: PHYSICAL AND CHEMICAL PROPERTIES ------------------------------------------------------------------------ Physical form,Color,Odor Solid Paste Gray, epoxy odor. Viscous paste Water Solubility NIL Boiling point/boiling range N/A Melting point/melting range NOT DETERMINED Vapour pressure N/A Percent Volatile 0 % by wt Evaporation rate N/A Vapour density N/A Specific gravity 1.5 Water=1 Flash point 248.89 C CC Autoflammability NOT DETERMINED Flammable Limits - LEL N/A Flammable Limits - UEL N/A Viscosity 789000 centipoise CONDITIONS: @ 23.0 C ------------------------------------------------------------------------ SECTION 4: HAZARD IDENTIFICATION ------------------------------------------------------------------------ Risk Phrases Irritating to eyes and skin. May cause sensitization by skin contact. Limited evidence of a carcinogenic effect. Toxic to aquatic organisms. May cause long-term adverse effects in the aquatic environment. ------------------------------------------------------------------------ SECTION 5: FIRST AID MEASURES ------------------------------------------------------------------------ Instructions for Ingestion Do not induce vomiting unless instructed to do so by medical personnel. Give victim two glasses of water. Never give anything by mouth to an unconscious person. Get medical attention. Instructions for Eye Contact Flush eyes with large amounts of water. If signs/symptoms persist, get medical attention. Instructions for Skin Contact Remove contaminated clothing and shoes. Wash affected area with soap and water. If signs/symptoms develop, get medical attention. Wash contaminated clothing and clean shoes before reuse. Instructions for Inhalation If signs/symptoms develop, remove person to fresh air. If signs/symptoms persist, get medical attention. ------------------------------------------------------------------------ SECTION 6: FIRE FIGHTING MEASURES ------------------------------------------------------------------------ Suitable Extinguishing Media Use fire extinguishers with class B extinguishing agents (e.g., dry chemical, carbon dioxide). Fire Fighting Procedures Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and prevent explosive rupture. Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatus (SCBA). Exposure Hazards during Fire Closed containers exposed to heat from fire may build pressure and explode. Flammable solid. ------------------------------------------------------------------------ SECTION 7: ACCIDENTAL RELEASE MEASURE ------------------------------------------------------------------------ Spill Response Not applicable. Methods for Disposal Not applicable. ------------------------------------------------------------------------ SECTION 8: HANDLING AND STORAGE ------------------------------------------------------------------------ Storage Requirements Store in a cool, dry place. Store at O F or below. Incompatible Materials Store away from acids. Store away from heat. Store out of direct sunlight. Store away from oxidizing agents. Ventilation Keep container in well-ventilated area. Fire Prevention No smoking while handling this material. Do not heat under confinement to avoid risk of explosion Explosion Prevention Keep away from heat, sparks, open flame, pilot lights and other sources of ignition. Use Instructions Avoid eye contact. Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Keep container tightly closed. Avoid skin contact. Avoid breathing of dust created by cutting, sanding, grinding or machining. Avoid contact with oxidizing agents. ------------------------------------------------------------------------ SECTION 9: EXP0SURE CONTROL AND PERSONAL PROTECTION ------------------------------------------------------------------------ ALUMINUM PIGMENTS (7429-90-5) Exposure Limits 1 mg/m3 ACGIH: TWA; respirable fraction 1 mg/m3 ACGIH: TWA; respirable fraction; Category: Aluminum AMORPHOUS SILICA (67762-90-7) Exposure Limits 5 mg/m3 CMRG: CEIL; Comments: DOC CORNING MSDS DATED 9/10/97 FOR 11-0003-9094-5. Recommended Ventilation Use with appropriate local exhaust ventilation. Provide appropriate local exhaust ventilation at transfer points. Provide appropriate local exhaust for cutting, grinding, sanding or machining. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below Occupational Exposure Limits and/or control dust, fume, or airborne particles. If ventilation is not adequate, use respiratory protection equipment. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below Occupational Exposure Limits. If ventilation is not adequate, use respiratory protection equipment. Eye Protection Avoid eye contact. Avoid eye contact with dust or airborne particles. The following should be worn alone or in combination, as appropriate, to prevent eye contact: Safety glasses with side shields Hand Protection The following glove material(s) are recommended: butyl rubber neoprene nitrile rubber Polymer laminate Skin Protection Avoid skin contact. Respiratory Protection Avoid breathing of dust created by cutting, sanding, grinding or machining. Select one of the following approved respirators based on airborne concentration of contaminants and in accordance with regulations: Half facepiece or fullface air-purifying respirator with P100 particulate filters Half facepiece or fullface air-purifying respirator with P95 particulate filters Half facepiece or fullface air-purifying respirator with N95 particulate prefilters Ingestion Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. ------------------------------------------------------------------------ SECTION 10: STABILITY AND REACTIVITY ------------------------------------------------------------------------ Conditions to Avoid Sparks and/or Flames Avoid curing large quantities of material to prevent a premature reaction (exotherm) with production of intense heat and smoke. Heat Materials to Avoid Strong Oxidizing Agents Strong Acids Strong Bases Amines Hazardous Decomposition Aldehydes During Combustion Chlorine During Combustion. Carbon monoxide During Combustion Carbon dioxide During Combustion Hydrogen Chloride During Combustion Hydrogen Cyanide During Combustion Ammonia During Combustion Oxides of Nitrogen During Combustion Stability and Reactivity Hazardous polymerization will not occur. Stable ------------------------------------------------------------------------ SECTION 11: TOXICOLOGICAL INFORMATION ------------------------------------------------------------------------ Effects from Eye Contact Moderate Eye Irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision. Vapors released during curing may cause eye irritation. Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision. Dust created by cutting, grinding, sanding, or machining may cause eye irritation. Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision. Effects from Skin Contact Moderate Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness. Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering and itching. Effects from Inhalation Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Dust from cutting, grinding, sanding or machining may cause irritation of the respiratory system. Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. May be absorbed following inhalation and cause target organ effects. Effects from Ingestion Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. May be absorbed following ingestion and cause target organ effects. Other Toxicological Information Methemoglobinemia: Signs/symptoms may include headache, dizziness, nausea, difficulty breathing, and generalized weakness. Prolonged or repeated exposure may cause: Central Neuropathy: Signs/symptoms may include irritability, memory impairment, personality changes, sleep disorders, and decreased ability to concentrate. Hard Tissue Effects: Signs/symptoms may include color changes in the teeth and nails; changes in development of bone, teeth or nails; weakening of the bones; and/or hair loss. Hematopoietic Effects: Signs/symptoms may include generalized weakness, fatigue and alterations in numbers of circulating blood cells. Liver Effects: Signs/symptoms may include loss of appetite, weight loss, fatigue, weakness, abdominal tenderness and jaundice. ------------------------------------------------------------------------ SECTION 12: ECOLOGICAL INFORMATION ------------------------------------------------------------------------ Environmental Data No data available. Ecotoxicity Data Not determined. Ecofate Data Not determined. ------------------------------------------------------------------------ SECTION 13: DISPOSAL INFORMATION ------------------------------------------------------------------------ Product as Sold Dispose of completely cured (or polymerized) wastes in a sanitary landfill. Incinerate in an industrial or commercial facility in the presence of a combustible material. As a disposal alternative, incinerate in an industrial or commercial facility. As a disposal alternative, dispose of waste product in a facility permitted to accept chemical waste. Combustion products will include HCl. Facility must be capable of handling halogenated materials. ------------------------------------------------------------------------ SECTION 14: TRANSPORT INFORMATION ------------------------------------------------------------------------ UN Number UN3088, SELF-HEATING SOLID, ORGANIC, N.O.S., (DICYANDIAMIDE AND PARA-CHLOROPHENYL-DIMETHYLUREA) , 4.2, II UN1845, CARBON DIOXIDE, SOLID, 9 IMO Class FORBIDDEN 3M DIVISION POLICY ICAO Class Special Instructions Transportation classifications are provided as a customer service. As for shipping, YOU remain responsible for complying with all applicable laws and regulations, including proper transportation classification and packaging. 3M's transportation classifications are based on product formulation, packaging, 3M policies and 3M's understanding of applicable current regulations. 3M does not guarantee the accuracy of this classification information. This information applies only to transportation classification and not the packaging, labeling or marking requirements. The above information is only for reference. If you are shipping by air or ocean, YOU are advised to check & meet applicable regulatory requirements. ------------------------------------------------------------------------ SECTION 15: REGULATORY INFORMATION ------------------------------------------------------------------------ Symbols Xn Harmful N Dangerous to environment Risk Phrases Irritating to eyes and skin. May cause sensitization by skin contact. Limited evidence of a carcinogenic effect. Toxic to aquatic organisms. May cause long-term adverse effects in the aquatic environment. Safety Phrases Wear suitable protective clothing and gloves. Avoid release to the environment. Refer to special instructions/safety data sheets. Contains Epoxy Resins. See information supplied by manufacturer. Special Regulatory Information Contact 3M for more information. ------------------------------------------------------------------------ SECTION 16: OTHER INFORMATION ------------------------------------------------------------------------ The information on this data sheet represents our current data and best opinion as to the proper use in handling of this product under normal conditions. Any use of the product which is not in conformance with this data sheet or which involves using the product in combination with any other product or any other process is the responsibility of the user.