3M MALAYSIA SDN BHD ======================================================================== CHEMICAL SAFETY DATA SHEET ======================================================================== Document id : 10-2861-2 Issue date : 04/11/2008 Version : 1.00 Supersedes date : --- Document status : Issued This CSDS has been prepared by Toxicology Department 3M Malaysia Sdn. Bhd. ------------------------------------------------------------------------ SECTION 1: CHEMICAL PRODUCT AND COMPANY IDENTIFICATION ------------------------------------------------------------------------ Tradename 3M(TM) Imperial(TM) Hand Glaze, P.N. 05989, 05990, 06000, 39007 3M Product ID: 60-4300-5014-0, 60-4300-5015-7, 60-4400-9668-7, 60-9800-0965-2, 60-9800-1129-4, 60-9800-1528-7, CN-1006-9456-7, XC-0616-7893-1 Intended Use of Product Automotive COMPANY IDENTIFICATION ---------------------- Manufacturer's name and address 3M 3M Center St. Paul, Minnesota 55144-1000 USA Importer's name and address 3M Malaysia Sdn. Bhd. Bangunan 3M No. 6, Persiaran Tropicana 47410 Petaling Jaya Selangor Telephone number 03-7806-2888 Emergency telephone number 1-651-7376501 ( 24 hours ) CONTACT POINT ------------- Designation Toxicology Coordinator Telephone number 03-7806-2888 ------------------------------------------------------------------------ SECTION 2: COMPOSITION/INFORMATION ON INGREDIENT ------------------------------------------------------------------------ Ingredient name CAS number Percentage ------------------------------------- ------------------ ------------- WATER 7732-18-5 60 - 90 MEDIUM ALIPHATIC SOLVENT NAPHTHA 64742-88-7 5 - 10 Exposure Limits: 100 ppm CMRG: TWA HYDROTREATED HEAVY NAPHTHA 64742-48-9 5 - 10 (PETROLEUM) Exposure Limits: 100 ppm 3M: TWA 1900 mg/m3 CMRG: TWA 300 ppm CMRG: TWA ALUMINUM SILICATE 66402-68-4 3 - 7 WHITE MINERAL OIL (PETROLEUM) 8042-47-5 3 - 7 Exposure Limits: 10 mg/m3 ACGIH: STEL; as mist; Category: OIL MIST, MINERAL 5 mg/m3 ACGIH: TWA; as mist; Category: OIL MIST, MINERAL 10 mg/m3 CMRG: STEL; Comments: PER MSDS 5 mg/m3 CMRG: TWA; Comments: PER MSDS GLYCERIN 56-81-5 1 - 5 Exposure Limits: 10 mg/m3 ACGIH: TWA - as mist; Particulates not otherwise classified. CASTOR OIL 8001-79-4 1 - 5 ------------------------------------------------------------------------ SECTION 3: PHYSICAL AND CHEMICAL PROPERTIES ------------------------------------------------------------------------ Physical form,Color,Odor Liquid Light orange-brown. Faint sweet odor. Water Solubility MOD Boiling point/boiling range 100.0 C Melting point/melting range NOT DETERMINED Vapour pressure NOT DETERMINED Percent Volatile 80 - 90 % Evaporation rate 4.4 Ether=1 Vapour density >= 1 Air=1 Specific gravity 0.996 Water=1 Flash point > 110.0 C CC Autoflammability NOT DETERMINED Flammable Limits - LEL NOT DETERMINED Flammable Limits - UEL NOT DETERMINED Viscosity No data available. ------------------------------------------------------------------------ SECTION 4: HAZARD IDENTIFICATION ------------------------------------------------------------------------ Risk Phrases Vapours may cause drowsiness and dizziness. Repeated exposure may cause skin dryness or cracking. Harmful to aquatic organisms. May cause long-term adverse effects in the aquatic environment. CONTAINS 2-((HYDROXYMETHYL)AMINO) ETHANOL. May produce an allergic reaction. ------------------------------------------------------------------------ SECTION 5: FIRST AID MEASURES ------------------------------------------------------------------------ Instructions for Ingestion Do not induce vomiting unless instructed to do so by medical personnel. Give victim two glasses of water. Never give anything by mouth to an unconscious person. Get medical attention. Instructions for Eye Contact Flush eyes with large amounts of water. If signs/symptoms persist, get medical attention. Instructions for Skin Contact Remove contaminated clothing and shoes. Immediately flush skin with large amounts of water. Get medical attention. Wash contaminated clothing and clean shoes before reuse. Instructions for Inhalation Remove person to fresh air. If signs/symptoms develop, get medical attention. ------------------------------------------------------------------------ SECTION 6: FIRE FIGHTING MEASURES ------------------------------------------------------------------------ Suitable Extinguishing Media Use fire extinguishers with class B extinguishing agents (e.g., dry chemical, carbon dioxide). Fire Fighting Procedures Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatus (SCBA). Exposure Hazards during Fire No unusual fire or explosion hazards are anticipated. ------------------------------------------------------------------------ SECTION 7: ACCIDENTAL RELEASE MEASURE ------------------------------------------------------------------------ Spill Response For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Evacuate unprotected and untrained personnel from hazard area. The spill should be cleaned up by qualified personnel. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn or explode. Contain spill. Remember, adding an absorbent material does not remove a toxic, corrosivity or flammability hazard. Collect as much of the spilled material as possible. Collect as much of the spilled material as possible using non-sparking tools. Clean up residue with detergent and water. Collect the resulting residue containing solution. Place in a closed container approved for transportation by appropriate authorities. Place in a metal container approved for transportation by appropriate authorities. Dispose of collected material as soon as possible. Methods for Disposal Not applicable. ------------------------------------------------------------------------ SECTION 8: HANDLING AND STORAGE ------------------------------------------------------------------------ Incompatible Materials Store away from acids. Store away from oxidizing agents. Fire Prevention No smoking while handling this material. Explosion Prevention Keep away from heat, sparks, open flame, pilot lights and other sources of ignition. Use Instructions Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Keep container tightly closed. Avoid breathing of vapors, mists or spray. ------------------------------------------------------------------------ SECTION 9: EXP0SURE CONTROL AND PERSONAL PROTECTION ------------------------------------------------------------------------ MEDIUM ALIPHATIC SOLVENT NAPHTHA (64742-88-7) Exposure Limits 100 ppm CMRG: TWA HYDROTREATED HEAVY NAPHTHA (PETROLEUM) (64742-48-9) Exposure Limits 100 ppm 3M: TWA 1900 mg/m3 CMRG: TWA 300 ppm CMRG: TWA WHITE MINERAL OIL (PETROLEUM) (8042-47-5) Exposure Limits 10 mg/m3 ACGIH: STEL; as mist; Category: OIL MIST, MINERAL 5 mg/m3 ACGIH: TWA; as mist; Category: OIL MIST, MINERAL 10 mg/m3 CMRG: STEL; Comments: PER MSDS 5 mg/m3 CMRG: TWA; Comments: PER MSDS GLYCERIN (56-81-5) Exposure Limits 10 mg/m3 ACGIH: TWA - as mist; Particulates not otherwise classified. Recommended Ventilation Use with appropriate local exhaust ventilation. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below Occupational Exposure Limits. If ventilation is not adequate, use respiratory protection equipment. Eye Protection Avoid eye contact. The following should be worn alone or in combination, as appropriate, to prevent eye contact: Safety glasses with side shields Hand Protection Not applicable. The following glove material(s) are recommended: nitrile rubber Skin Protection Avoid skin contact. Respiratory Protection Under normal use conditions, airborne exposures are not expected to be significant enough to require respiratory protection. Avoid breathing of vapors, mists or spray. Ingestion Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Keep out of the reach of children. ------------------------------------------------------------------------ SECTION 10: STABILITY AND REACTIVITY ------------------------------------------------------------------------ Materials to Avoid None known. Hazardous Decomposition Carbon monoxide During Combustion Carbon dioxide During Combustion Stability and Reactivity Hazardous polymerization will not occur. Stable ------------------------------------------------------------------------ SECTION 11: TOXICOLOGICAL INFORMATION ------------------------------------------------------------------------ Effects from Eye Contact Mild Eye Irritation: Signs/symptoms may include redness, pain, and tearing. Effects from Skin Contact Moderate Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness. Effects from Inhalation May be absorbed following inhalation and cause target organ effects. Intentional concentration and inhalation may be harmful or fatal. Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Effects from Ingestion May be absorbed following ingestion and cause target organ effects. Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. Other Toxicological Information Prolonged or repeated exposure may cause: Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness. ------------------------------------------------------------------------ SECTION 12: ECOLOGICAL INFORMATION ------------------------------------------------------------------------ Environmental Data No data available. Ecotoxicity Data Not determined. Ecofate Data Not determined. Special statements for 2001/58/EC A conservative assessment indicates this product presents a low environmental risk. Components released to the environment through use and disposal are expected to have minimal environmental impact. ------------------------------------------------------------------------ SECTION 13: DISPOSAL INFORMATION ------------------------------------------------------------------------ Product as Sold Incinerate in an industrial or commercial facility in the presence of a combustible material. As a disposal alternative, dispose of waste product in a facility permitted to accept chemical waste. ------------------------------------------------------------------------ SECTION 14: TRANSPORT INFORMATION ------------------------------------------------------------------------ UN Number IMO Class ICAO Class Special Instructions ** NOT DANGEROUS FOR TRANSPORT FOR DOT, IMO OR IATA. ------------------------------------------------------------------------ SECTION 15: REGULATORY INFORMATION ------------------------------------------------------------------------ Symbols None Risk Phrases Vapours may cause drowsiness and dizziness. Repeated exposure may cause skin dryness or cracking. Harmful to aquatic organisms. May cause long-term adverse effects in the aquatic environment. CONTAINS 2-((HYDROXYMETHYL)AMINO) ETHANOL. May produce an allergic reaction. Safety Phrases Avoid contact with skin. Wear suitable gloves. If swallowed, seek medical advice immediately and show this container or label. Avoid release to the environment. Refer to special instructions/safety data sheets. Keep out of the reach of children. Special Regulatory Information Contact 3M for more information. ------------------------------------------------------------------------ SECTION 16: OTHER INFORMATION ------------------------------------------------------------------------ The information on this data sheet represents our current data and best opinion as to the proper use in handling of this product under normal conditions. Any use of the product which is not in conformance with this data sheet or which involves using the product in combination with any other product or any other process is the responsibility of the user.