3M MALAYSIA SDN BHD ============================================================================ KIT Chemical Safety Data Sheet ============================================================================ Document id : 10-5608-4 Issue date : 21/02/2013 Version : 1.00 Supersedes date : --- Document status : Issued This CSDS has been prepared by Toxicology Department 3M Malaysia Sdn. Bhd. ---------------------------------------------------------------------------- 1 SECTION 1: CHEMICAL PRODUCT AND COMPANY IDENTIFICATION ---------------------------------------------------------------------------- NOTE TRANSPORTATION INFORMATION: IATA - UN3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S., (POLYMETHYLENE POLYPHENYLENE ISOCYANATE), 9, III IMO - UN3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S., (POLYMETHYLENE POLYPHENYLENE ISOCYANATE), 9, III, LIMITED QUANTITY, MARINE POLLUTANT, (POLYMETHYLENE POLYPHENYLENE ISOCYANATE) Tradename 3M(TM) KIT 85-12 (SCOTCHCAST 2104) 3M Product ID: 78-8025-2927-7, 80-6100-7711-9, 80-6112-1839-9 - 85-12 MULTI-MOLD KIT, MEXICALI ASSEMBLED,2104 RESIN UNIPAK, SIZE "B" KIT COMPONENTS 25-0742-4, 25-1043-6 The information on this data sheet represents our current data and best opinion as to the proper use in handling of this product under normal conditions. Any use of the product which is not in conformance with this data sheet or which involves using the product in combination with any other product or any other process is the responsibility of the user. 3M MALAYSIA SDN BHD ======================================================================== CHEMICAL SAFETY DATA SHEET ======================================================================== Document id : 25-1043-6 Issue date : 21/02/2013 Version : 1.00 Supersedes date : --- Document status : Issued This CSDS has been prepared by Toxicology Department 3M Malaysia Sdn. Bhd. ------------------------------------------------------------------------ SECTION 1: CHEMICAL PRODUCT AND COMPANY IDENTIFICATION ------------------------------------------------------------------------ Tradename 3M(TM) SCOTCHCAST(TM) RESIN 2104 B 3M Product ID Intended Use of Product Electrical COMPANY IDENTIFICATION ---------------------- Manufacturer's name and address 3M 3M Center St. Paul, Minnesota 55144-1000 USA Importer's name and address 3M Malaysia Sdn. Bhd. Level 8, Block F, Oasis Square, No.2, Jalan PJU 1A/7A, Ara Damansara 47301 Petaling Jaya, Selangor Telephone number 03-7884 2888 Emergency telephone number 1-651-7376501 ( 24 hours ) CONTACT POINT ------------- Designation Toxicology Coordinator Telephone number 03-7884 2888 ------------------------------------------------------------------------ SECTION 2: COMPOSITION/INFORMATION ON INGREDIENT ------------------------------------------------------------------------ Ingredient name CAS number Percentage ------------------------------------- ------------------ ------------- POLYPROPYLENE GLYCOL GLYCEROL 25791-96-2 55 - 75 TRIETHER N,N-DI(2-HYDROXYPROPYL)ANILINE 3077-13-2 5 - 20 PHTHALIC ACID, DI-C11-14-BRANCHED 68515-47-9 5 - 20 ALKYL ESTERS, C13-RICH DIPROPYLENE GLYCOL 25265-71-8 1 - 10 ------------------------------------------------------------------------ SECTION 3: PHYSICAL AND CHEMICAL PROPERTIES ------------------------------------------------------------------------ Physical form,Color,Odor NOT DETERMINED Liquid Light amber liquid with glycol odor Water Solubility NOT DETERMINED Boiling point/boiling range >= 110.0 C Melting point/melting range NOT DETERMINED Vapour pressure NOT DETERMINED Percent Volatile No data available. Evaporation rate No data available. Vapour density NOT DETERMINED Specific gravity = 1 Flash point >= 110.0 C CC Autoflammability NOT DETERMINED Flammable Limits - LEL NOT DETERMINED Flammable Limits - UEL NOT DETERMINED Viscosity 450 - 750 centipoise ------------------------------------------------------------------------ SECTION 4: HAZARD IDENTIFICATION ------------------------------------------------------------------------ Risk Phrases Risk of serious damage to eyes. ------------------------------------------------------------------------ SECTION 5: FIRST AID MEASURES ------------------------------------------------------------------------ Instructions for Ingestion Do not induce vomiting unless instructed to do so by medical personnel. Give victim two glasses of water. Never give anything by mouth to an unconscious person. Get medical attention. Instructions for Eye Contact Immediately flush eyes with large amounts of water for at least 15 minutes. Get immediate medical attention. Instructions for Skin Contact Remove contaminated clothing and shoes. Immediately flush skin with large amounts of water. Get medical attention. Wash contaminated clothing and clean shoes before reuse. Instructions for Inhalation Remove person to fresh air. If signs/symptoms develop, get medical attention. ------------------------------------------------------------------------ SECTION 6: FIRE FIGHTING MEASURES ------------------------------------------------------------------------ Suitable Extinguishing Media Ordinary combustible material. Use fire extinguishers with class A extinguishing agents (e.g., water, foam). Fire Fighting Procedures Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatus (SCBA). Exposure Hazards during Fire Non-flammable: ordinary combustible material. ------------------------------------------------------------------------ SECTION 7: ACCIDENTAL RELEASE MEASURE ------------------------------------------------------------------------ Spill Response For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Evacuate unprotected and untrained personnel from hazard area. The spill should be cleaned up by qualified personnel. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn or explode. Contain spill. Collect as much of the spilled material as possible. Clean up residue with an appropriate solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow safety precautions on the solvent label and MSDS. Collect the resulting residue containing solution. Place in a closed container approved for transportation by appropriate authorities. Dispose of collected material as soon as possible. Methods for Disposal Not applicable. ------------------------------------------------------------------------ SECTION 8: HANDLING AND STORAGE ------------------------------------------------------------------------ Storage Requirements Store in a cool, dry place. Incompatible Materials Store away from heat. Ventilation Keep container in well-ventilated area. Use Instructions Avoid eye contact with vapors, mists, or spray. Avoid prolonged or repeated skin contact. Avoid breathing of vapors, mists or spray. Do not ingest. For industrial or professional use only. ------------------------------------------------------------------------ SECTION 9: EXP0SURE CONTROL AND PERSONAL PROTECTION ------------------------------------------------------------------------ Recommended Ventilation Use in a well-ventilated area. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below Occupational Exposure Limits and/or control dust, fume, or airborne particles. If ventilation is not adequate, use respiratory protection equipment. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below Occupational Exposure Limits. If ventilation is not adequate, use respiratory protection equipment. Eye Protection Avoid eye contact with vapors, mists, or spray. The following should be worn alone or in combination, as appropriate, to prevent eye contact: Indirect Vented Goggles Hand Protection The following glove material(s) are recommended: butyl rubber polyvinyl chloride Skin Protection Avoid prolonged or repeated skin contact. Respiratory Protection Avoid breathing of vapors, mists or spray. Select one of the following approved respirators based on airborne concentration of contaminants and in accordance with regulations: Half facepiece or full facepiece air-purifying respirator suitable for particulates Ingestion Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. ------------------------------------------------------------------------ SECTION 10: STABILITY AND REACTIVITY ------------------------------------------------------------------------ Materials to Avoid None known. Hazardous Decomposition Aldehydes During Combustion Carbon monoxide During Combustion Carbon dioxide During Combustion Oxides of Nitrogen During Combustion Stability and Reactivity Hazardous polymerization will not occur. Stable ------------------------------------------------------------------------ SECTION 11: TOXICOLOGICAL INFORMATION ------------------------------------------------------------------------ Effects from Eye Contact Severe Eye Irritation: Signs/symptoms may include significant redness, swelling, pain, tearing, cloudy appearance of the cornea, and impaired vision. Effects from Skin Contact Moderate Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness. Effects from Inhalation Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Effects from Ingestion Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. ------------------------------------------------------------------------ SECTION 12: ECOLOGICAL INFORMATION ------------------------------------------------------------------------ Environmental Data No data available. Ecotoxicity Data Not determined. Ecofate Data Not determined. ------------------------------------------------------------------------ SECTION 13: DISPOSAL INFORMATION ------------------------------------------------------------------------ Product as Sold Incinerate in an industrial or commercial facility in the presence of a combustible material. As a disposal alternative, dispose of waste product in a facility permitted to accept chemical waste. ------------------------------------------------------------------------ SECTION 14: TRANSPORT INFORMATION ------------------------------------------------------------------------ UN Number Please refer to Kit MSDS IMO Class Please refer to Kit MSDS ICAO Class Please refer to Kit MSDS Special Instructions Transportation classifications are provided as a customer service. As for shipping, YOU remain responsible for complying with all applicable laws and regulations, including proper transportation classification and packaging. 3M's transportation classifications are based on product formulation, packaging, 3M policies and 3M's understanding of applicable current regulations. 3M does not guarantee the accuracy of this classification information. This information applies only to transportation classification and not the packaging, labeling or marking requirements. The above information is only for reference. If you are shipping by air or ocean, YOU are advised to check & meet applicable regulatory requirements. ------------------------------------------------------------------------ SECTION 15: REGULATORY INFORMATION ------------------------------------------------------------------------ Symbols Xi Irritant Risk Phrases Risk of serious damage to eyes. Safety Phrases Wear eye protection. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Special Regulatory Information Contact 3M for more information. ------------------------------------------------------------------------ SECTION 16: OTHER INFORMATION ------------------------------------------------------------------------ The information on this data sheet represents our current data and best opinion as to the proper use in handling of this product under normal conditions. Any use of the product which is not in conformance with this data sheet or which involves using the product in combination with any other product or any other process is the responsibility of the user. 3M MALAYSIA SDN BHD ======================================================================== CHEMICAL SAFETY DATA SHEET ======================================================================== Document id : 25-0742-4 Issue date : 21/02/2013 Version : 1.00 Supersedes date : --- Document status : Issued This CSDS has been prepared by Toxicology Department 3M Malaysia Sdn. Bhd. ------------------------------------------------------------------------ SECTION 1: CHEMICAL PRODUCT AND COMPANY IDENTIFICATION ------------------------------------------------------------------------ Tradename 3M(TM) SCOTCHCAST(TM) RESIN 2104 A 3M Product ID Intended Use of Product Electrical COMPANY IDENTIFICATION ---------------------- Manufacturer's name and address 3M 3M Center St. Paul, Minnesota 55144-1000 USA Importer's name and address 3M Malaysia Sdn. Bhd. Level 8, Block F, Oasis Square, No.2, Jalan PJU 1A/7A, Ara Damansara 47301 Petaling Jaya, Selangor Telephone number 03-7884 2888 Emergency telephone number 1-651-7376501 ( 24 hours ) CONTACT POINT ------------- Designation Toxicology Coordinator Telephone number 03-7884 2888 ------------------------------------------------------------------------ SECTION 2: COMPOSITION/INFORMATION ON INGREDIENT ------------------------------------------------------------------------ Ingredient name CAS number Percentage ------------------------------------- ------------------ ------------- PHTHALIC ACID, DI-C11-14-BRANCHED 68515-47-9 35 - 50 ALKYL ESTERS, C13-RICH POLYMETHYLENE POLYPHENYLENE 9016-87-9 15 - 35 ISOCYANATE Exposure Limits: 0.02 ppm 3M: STEL; Category: FREE ISOCYANATES 0.0050 ppm 3M: TWA; Category: FREE ISOCYANATES 0.0050 ppm ACGIH: TWA; Category: Benzene, 1, 1'-methylenebis[4-isocyanato- 1,3-BUTADIENE, HOMOPOLYMER, HYDROXY- 69102-90-5 15 - 25 TERMINATED P,P'-METHYLENEBIS(PHENYL ISOCYANATE) 101-68-8 5 - 20 Exposure Limits: 0.02 ppm 3M: STEL; Category: FREE ISOCYANATES 0.0050 ppm 3M: TWA; Category: FREE ISOCYANATES 0.0050 ppm ACGIH: TWA 0.0050 ppm ACGIH: TWA; Category: Benzene, 1, 1'-methylenebis[4-isocyanato- 1,1'-METHYLENEBIS(ISOCYANATOBENZENE) 26447-40-5 0 - 10 Exposure Limits: 0.02 ppm 3M: STEL; Category: FREE ISOCYANATES 0.0050 ppm 3M: TWA; Category: FREE ISOCYANATES ------------------------------------------------------------------------ SECTION 3: PHYSICAL AND CHEMICAL PROPERTIES ------------------------------------------------------------------------ Physical form,Color,Odor DETAILS: Resin Liquid Dark green liquid with isocyanate odor Water Solubility NOT DETERMINED Boiling point/boiling range >= 110.0 C Melting point/melting range NOT DETERMINED Vapour pressure NOT DETERMINED Percent Volatile <<< Evaporation rate No data available. Vapour density NOT DETERMINED Specific gravity = 1.04 Flash point = 110.0 C CC Autoflammability NOT DETERMINED Flammable Limits - LEL NOT DETERMINED Flammable Limits - UEL NOT DETERMINED Viscosity 1400 - 2000 ------------------------------------------------------------------------ SECTION 4: HAZARD IDENTIFICATION ------------------------------------------------------------------------ Risk Phrases Harmful by inhalation. Irritating to eyes, respiratory system and skin. May cause sensitization by inhalation and skin contact. Harmful: danger of serious damage to health by prolonged exposure through inhalation. Limited evidence of a carcinogenic effect. Harmful to aquatic organisms. May cause long-term adverse effects in the aquatic environment. ------------------------------------------------------------------------ SECTION 5: FIRST AID MEASURES ------------------------------------------------------------------------ Instructions for Ingestion Do not induce vomiting unless instructed to do so by medical personnel. Give victim two glasses of water. Never give anything by mouth to an unconscious person. Get medical attention. Instructions for Eye Contact Immediately flush eyes with large amounts of water for at least 15 minutes. Get immediate medical attention. Instructions for Skin Contact Remove contaminated clothing and shoes. Immediately flush skin with large amounts of water. Get medical attention. Wash contaminated clothing and clean shoes before reuse. Instructions for Inhalation Remove person to fresh air. If signs/symptoms develop, get medical attention. ------------------------------------------------------------------------ SECTION 6: FIRE FIGHTING MEASURES ------------------------------------------------------------------------ Suitable Extinguishing Media Use fire extinguishers with class B extinguishing agents (e.g., dry chemical, carbon dioxide). Fire Fighting Procedures Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatus (SCBA). Special Instructions for Fire Fighting Not applicable. Exposure Hazards during Fire No unusual fire or explosion hazards are anticipated. Non-flammable: ordinary combustible material. ------------------------------------------------------------------------ SECTION 7: ACCIDENTAL RELEASE MEASURE ------------------------------------------------------------------------ Spill Response For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water. Pour isocyanate decontaminant solution (90% water, 8% concentrated ammonia, 2% detergent) on spill and allow to react for 10 minutes. Or pour water on spill and allow to react for more than 30 minutes. Cover with absorbent material. Place in a container approved for transportation by appropriate authorities, but do not seal the container for 48 hours to avoid pressure build-up. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Evacuate unprotected and untrained personnel from hazard area. The spill should be cleaned up by qualified personnel. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn or explode. Contain spill. Collect as much of the spilled material as possible. Clean up residue with an appropriate solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow safety precautions on the solvent label and MSDS. Collect the resulting residue containing solution. Place in a closed container approved for transportation by appropriate authorities. Dispose of collected material as soon as possible. Methods for Disposal Not applicable. ------------------------------------------------------------------------ SECTION 8: HANDLING AND STORAGE ------------------------------------------------------------------------ Storage Requirements Store in a cool, dry place. Incompatible Materials Store away from heat. Avoid contact with water. Ventilation Keep container in well-ventilated area. Use Instructions Keep container tightly closed. Avoid eye contact with vapors, mists, or spray. Avoid skin contact. Avoid breathing of vapors, mists or spray. Do not ingest. For industrial or professional use only. ------------------------------------------------------------------------ SECTION 9: EXP0SURE CONTROL AND PERSONAL PROTECTION ------------------------------------------------------------------------ POLYMETHYLENE POLYPHENYLENE ISOCYANATE (9016-87-9) Exposure Limits 0.02 ppm 3M: STEL; Category: FREE ISOCYANATES 0.0050 ppm 3M: TWA; Category: FREE ISOCYANATES 0.0050 ppm ACGIH: TWA; Category: Benzene, 1, 1'-methylenebis[4-isocyanato- P,P'-METHYLENEBIS(PHENYL ISOCYANATE) (101-68-8) Exposure Limits 0.02 ppm 3M: STEL; Category: FREE ISOCYANATES 0.0050 ppm 3M: TWA; Category: FREE ISOCYANATES 0.0050 ppm ACGIH: TWA 0.0050 ppm ACGIH: TWA; Category: Benzene, 1, 1'-methylenebis[4-isocyanato- 1,1'-METHYLENEBIS(ISOCYANATOBENZENE) (26447-40-5) Exposure Limits 0.02 ppm 3M: STEL; Category: FREE ISOCYANATES 0.0050 ppm 3M: TWA; Category: FREE ISOCYANATES Recommended Ventilation Use with appropriate local exhaust ventilation. If exhaust ventilation is not available, use appropriate respiratory protection. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below Occupational Exposure Limits. If ventilation is not adequate, use respiratory protection equipment. Eye Protection Avoid eye contact with vapors, mists, or spray. The following should be worn alone or in combination, as appropriate, to prevent eye contact: Full faceshield Indirect Vented Goggles Hand Protection The following glove material(s) are recommended: nitrile rubber polyvinyl alcohol Skin Protection Avoid skin contact. Respiratory Protection Avoid breathing of vapors, mists or spray. Select one of the following approved respirators based on airborne concentration of contaminants and in accordance with regulations: Full facepiece supplied-air respirator Ingestion Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. ------------------------------------------------------------------------ SECTION 10: STABILITY AND REACTIVITY ------------------------------------------------------------------------ Materials to Avoid Amines Alcohols Water Hazardous Decomposition Isocyanates During Combustion Carbon monoxide During Combustion Carbon dioxide During Combustion Hydrogen Cyanide During Combustion Oxides of Nitrogen During Combustion Stability and Reactivity Hazardous polymerization will not occur. Stable ------------------------------------------------------------------------ SECTION 11: TOXICOLOGICAL INFORMATION ------------------------------------------------------------------------ Effects from Eye Contact Severe Eye Irritation: Signs/symptoms may include significant redness, swelling, pain, tearing, cloudy appearance of the cornea, and impaired vision. Effects from Skin Contact Severe Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, dryness, cracking, blistering, and pain. Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering and itching. Effects from Inhalation May be harmful or fatal if inhaled. Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Allergic Respiratory Reaction: Signs/symptoms may include difficulty breathing, wheezing, cough, and tightness of chest. Prolonged or repeated exposure may cause: Respiratory Effects: Signs/symptoms may include cough, shortness of breath, chest tightness, wheezing, increased heart rate, bluish colored skin (cyanosis), sputum production, changes in lung function tests, and/or respiratory failure. Effects from Ingestion Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. ------------------------------------------------------------------------ SECTION 12: ECOLOGICAL INFORMATION ------------------------------------------------------------------------ Environmental Data No data available. Ecotoxicity Data Not determined. Ecofate Data Not determined. ------------------------------------------------------------------------ SECTION 13: DISPOSAL INFORMATION ------------------------------------------------------------------------ Product as Sold Incinerate in an industrial or commercial facility in the presence of a combustible material. As a disposal alternative, dispose of waste product in a facility permitted to accept chemical waste. ------------------------------------------------------------------------ SECTION 14: TRANSPORT INFORMATION ------------------------------------------------------------------------ UN Number Please refer to Kit MSDS IMO Class Please refer to Kit MSDS ICAO Class Please refer to Kit MSDS Special Instructions Transportation classifications are provided as a customer service. As for shipping, YOU remain responsible for complying with all applicable laws and regulations, including proper transportation classification and packaging. 3M's transportation classifications are based on product formulation, packaging, 3M policies and 3M's understanding of applicable current regulations. 3M does not guarantee the accuracy of this classification information. This information applies only to transportation classification and not the packaging, labeling or marking requirements. The above information is only for reference. If you are shipping by air or ocean, YOU are advised to check & meet applicable regulatory requirements. ------------------------------------------------------------------------ SECTION 15: REGULATORY INFORMATION ------------------------------------------------------------------------ Symbols Xn Harmful Risk Phrases Harmful by inhalation. Irritating to eyes, respiratory system and skin. May cause sensitization by inhalation and skin contact. Harmful: danger of serious damage to health by prolonged exposure through inhalation. Limited evidence of a carcinogenic effect. Harmful to aquatic organisms. May cause long-term adverse effects in the aquatic environment. Safety Phrases Do not breathe vapor. Wear suitable protective clothing and gloves. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Avoid release to the environment. Refer to special instructions/safety data sheets. Contains isocyanates. See information supplied by manufacturer. Special Regulatory Information Contact 3M for more information. ------------------------------------------------------------------------ SECTION 16: OTHER INFORMATION ------------------------------------------------------------------------ The information on this data sheet represents our current data and best opinion as to the proper use in handling of this product under normal conditions. Any use of the product which is not in conformance with this data sheet or which involves using the product in combination with any other product or any other process is the responsibility of the user.