3M MALAYSIA SDN BHD ======================================================================== CHEMICAL SAFETY DATA SHEET ======================================================================== Document id : 11-3321-4 Issue date : 21/06/2006 Version : 3.00 Supersedes date : 02/12/2004 Document status : Issued This CSDS has been prepared by Toxicology Department 3M Malaysia Sdn. Bhd. ------------------------------------------------------------------------ SECTION 1: CHEMICAL PRODUCT AND COMPANY IDENTIFICATION ------------------------------------------------------------------------ Tradename SCOTCH-WELD (TM) 110 B/A PART A GRAY EPOXY ADHESIVE 3M Product ID: 62-3633-8531-1, 62-3633-9531-0 Intended Use of Product COMPANY IDENTIFICATION ---------------------- Manufacturer's name and address 3M 3M Center St. Paul, Minnesota 55144-1000 USA Importer's name and address 3M Malaysia Sdn. Bhd. Bangunan 3M No. 6, Persiaran Tropicana 47410 Petaling Jaya Selangor Telephone number 03-7806-2888 Emergency telephone number 1-651-7376501 ( 24 hours ) CONTACT POINT ------------- Designation Toxicology Coordinator Telephone number 03-7806-2888 ------------------------------------------------------------------------ SECTION 2: COMPOSITION/INFORMATION ON INGREDIENT ------------------------------------------------------------------------ Ingredient name CAS number Percentage ------------------------------------- ------------------ ------------- Mercaptan Polymer - N.J.T.S. Reg No. Trade Secret 40 - 70 33611900-5145KP POLYAMIDE RESIN 68410-23-1 10 - 30 HYDROGENATED TERPHENYL 61788-32-7 5 - 10 2,4,6-TRIS[(DIMETHYLAMINO)METHYL] 90-72-2 1 - 5 PHENOL EPOXY RESIN 25068-38-6 1 - 5 HYDROGENATED POLYPHENYLS 68956-74-1 < 2 CARBON BLACK 1333-86-4 0.1 - 1 ------------------------------------------------------------------------ SECTION 3: PHYSICAL AND CHEMICAL PROPERTIES ------------------------------------------------------------------------ Physical form,Color,Odor Liquid Paste black, very slight odor paste Water Solubility CONDITIONS: Nil NIL Boiling point/boiling range >= 260 C Melting point/melting range N/A Vapour pressure NOT DETERMINED Percent Volatile = 0 % by wt Evaporation rate NOT DETERMINED Vapour density NOT DETERMINED Specific gravity = 1.1 Flash point = 248.89 C CC Autoflammability NOT DETERMINED Flammable Limits - LEL NOT DETERMINED Flammable Limits - UEL NOT DETERMINED Viscosity 30000 - 70000 centipoise CONDITIONS: @ 23.0 C ------------------------------------------------------------------------ SECTION 4: HAZARD IDENTIFICATION ------------------------------------------------------------------------ Risk Phrases Risk of serious damage to eyes. Irritating to skin. May cause sensitization by skin contact. Harmful to aquatic organisms. May cause long-term adverse effects in the aquatic environment. ------------------------------------------------------------------------ SECTION 5: FIRST AID MEASURES ------------------------------------------------------------------------ Instructions for Ingestion Do not induce vomiting unless instructed to do so by medical personnel. Give victim two glasses of water. Never give anything by mouth to an unconscious person. Get medical attention. Instructions for Eye Contact Get immediate medical attention. Immediately flush eyes with large amounts of water for at least 15 minutes. DO NOT ATTEMPT TO REMOVE MOLTEN MATERIAL. Instructions for Skin Contact Immediately flush skin with large amounts of cold water for at least 15 minutes. Get immediate medical attention. Remove contaminated clothing and shoes. DO NOT ATTEMPT TO REMOVE MOLTEN MATERIAL. Cover affected area with a clean dressing. Wash contaminated clothing and clean shoes before reuse. Instructions for Inhalation If signs/symptoms develop, remove person to fresh air. If signs/symptoms persist, get medical attention. ------------------------------------------------------------------------ SECTION 6: FIRE FIGHTING MEASURES ------------------------------------------------------------------------ Suitable Extinguishing Media Use fire extinguishers with class B extinguishing agents (e.g., dry chemical, carbon dioxide). Fire Fighting Procedures Water may be used to blanket the fire. Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatus (SCBA). Exposure Hazards during Fire No unusual fire or explosion hazards are anticipated. ------------------------------------------------------------------------ SECTION 7: ACCIDENTAL RELEASE MEASURE ------------------------------------------------------------------------ Spill Response Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Evacuate unprotected and untrained personnel from hazard area. The spill should be cleaned up by qualified personnel. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn or explode. Contain spill. Collect as much of the spilled material as possible. Clean up residue with an appropriate solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow safety precautions on the solvent label and MSDS. Collect the resulting residue containing solution. Place in a closed container approved for transportation by appropriate authorities. Dispose of collected material as soon as possible. Methods for Disposal Not applicable. ------------------------------------------------------------------------ SECTION 8: HANDLING AND STORAGE ------------------------------------------------------------------------ Incompatible Materials Store away from acids. Store away from heat. Store out of direct sunlight. Store away from oxidizing agents. Ventilation Keep container in well-ventilated area. Use Instructions Keep container tightly closed. For industrial or professional use only. Avoid contact with oxidizing agents. ------------------------------------------------------------------------ SECTION 9: EXP0SURE CONTROL AND PERSONAL PROTECTION ------------------------------------------------------------------------ HYDROGENATED TERPHENYL (61788-32-7) Exposure Limits 4.9 mg/m3 0.5 ppm ACGIH: TWA ACGIH: TWA 2,4,6-TRIS[(DIMETHYLAMINO)METHYL]PHENOL (90-72-2) Exposure Limits 5 ppm CMRG: TWA; CMRG AUTHORITY: ALSO ROHM & HAAS CARBON BLACK (1333-86-4) Exposure Limits 3.5 mg/m3 0.5 mg/m3 ACGIH: TWA; Table A4 CMRG: TWA; DUPONT MSDS DATED 1/6/99 FOR 11-0018-9474-7. Recommended Ventilation Provide appropriate local exhaust when product is heated. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below Occupational Exposure Limits and/or control mist, vapor, or spray. If ventilation is not adequate, use respiratory protection equipment. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below Occupational Exposure Limits. If ventilation is not adequate, use respiratory protection equipment. Eye Protection Avoid eye contact with vapors, mists, or spray. The following should be worn alone or in combination, as appropriate, to prevent eye contact: Indirect Vented Goggles Hand Protection Wear appropriate gloves, such as Nomex, when handling this material to prevent thermal burns. Avoid skin contact with hot material. The following glove material(s) are recommended: neoprene nitrile rubber Skin Protection Avoid skin contact. The following protective clothing material(s) are recommended: Apron - Neoprene Respiratory Protection Select one of the following approved respirators based on airborne concentration of contaminants and in accordance with regulations: Half facepiece or fullface air-purifying respirator with organic vapor cartridges Half facepiece or fullface pressure demand self-contained breathing apparatus Ingestion Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. ------------------------------------------------------------------------ SECTION 10: STABILITY AND REACTIVITY ------------------------------------------------------------------------ Materials to Avoid Strong Oxidizing Agents Strong Acids Avoid curing large quantities of material to prevent a premature reaction (exotherm) with production of intense heat and smoke. Hazardous Decomposition Aldehydes During Combustion Carbon monoxide During Combustion Carbon dioxide During Combustion Stability and Reactivity Stable Hazardous polymerization will not occur. ------------------------------------------------------------------------ SECTION 11: TOXICOLOGICAL INFORMATION ------------------------------------------------------------------------ Effects from Eye Contact Severe Eye Irritation: Signs/symptoms may include significant redness, swelling, pain, tearing, cloudy appearance of the cornea, and impaired vision. Vapors released during curing may cause eye irritation. Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision. Thermal Burns: Signs/symptoms may include severe pain, redness and swelling, and tissue destruction. Effects from Skin Contact Severe Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, dryness, cracking, blistering, and pain. Thermal Burns: Signs/symptoms may include intense pain, redness and swelling, and tissue destruction. Prolonged or repeated exposure may cause: Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching. Effects from Inhalation Vapors released during curing may cause irritation of the respiratory system. Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Effects from Ingestion Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. Carcinogenicity Contains a chemical or chemicals which can cause cancer. ------------------------------------------------------------------------ SECTION 12: ECOLOGICAL INFORMATION ------------------------------------------------------------------------ Environmental Data No data available. Ecotoxicity Data Not determined. Ecofate Data Not determined. ------------------------------------------------------------------------ SECTION 13: DISPOSAL INFORMATION ------------------------------------------------------------------------ Product as Sold ------------------------------------------------------------------------ SECTION 14: TRANSPORT INFORMATION ------------------------------------------------------------------------ UN Number IMO Class ICAO Class Special Instructions ** NOT HAZARDOUS FOR TRANSPORT FOR DOT, IMO, OR IATA. ------------------------------------------------------------------------ SECTION 15: REGULATORY INFORMATION ------------------------------------------------------------------------ Symbols Xi Irritant Risk Phrases Risk of serious damage to eyes. Irritating to skin. May cause sensitization by skin contact. Harmful to aquatic organisms. May cause long-term adverse effects in the aquatic environment. Safety Phrases Use only in well ventilated areas. Do not breathe vapor. S22 Do not breathe dust. S24/25 Avoid contact with the skin and eyes. Wear suitable gloves and eye protection. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S28B After contact with skin, wash immediately with plenty of water. Avoid release to the environment. Refer to special instructions/safety data sheets. Contains Epoxy Resins. See information supplied by manufacturer. Special Regulatory Information Contact 3M for more information. ------------------------------------------------------------------------ SECTION 16: OTHER INFORMATION ------------------------------------------------------------------------ Reason for Reissue New health hazard information. The information on this data sheet represents our current data and best opinion as to the proper use in handling of this product under normal conditions. Any use of the product which is not in conformance with this data sheet or which involves using the product in combination with any other product or any other process is the responsibility of the user.