3M MALAYSIA SDN BHD ======================================================================== CHEMICAL SAFETY DATA SHEET ======================================================================== Document id : 11-2781-0 Issue date : 06/02/2008 Version : 3.00 Supersedes date : 23/05/2006 Document status : Issued This CSDS has been prepared by Toxicology Department 3M Malaysia Sdn. Bhd. ------------------------------------------------------------------------ SECTION 1: CHEMICAL PRODUCT AND COMPANY IDENTIFICATION ------------------------------------------------------------------------ Tradename 3M(TM) FINESSE-IT(TM) COMPOUNDING MATERIAL - IVORY, P.N. 49800, 77340, 83481, 83984 3M Product ID: 60-9800-1151-8, 60-9800-1996-6, 60-9800-2186-3, 60-9800-3539-2 Intended Use of Product Automotive COMPANY IDENTIFICATION ---------------------- Manufacturer's name and address 3M 3M Center St. Paul, Minnesota 55144-1000 USA Importer's name and address 3M Malaysia Sdn. Bhd. Bangunan 3M No. 6, Persiaran Tropicana 47410 Petaling Jaya Selangor Telephone number 03-7806-2888 Emergency telephone number 1-651-7376501 ( 24 hours ) CONTACT POINT ------------- Designation Toxicology Coordinator Telephone number 03-7806-2888 ------------------------------------------------------------------------ SECTION 2: COMPOSITION/INFORMATION ON INGREDIENT ------------------------------------------------------------------------ Ingredient name CAS number Percentage ------------------------------------- ------------------ ------------- QUARTZ SILICA 14808-60-7 15 - 40 WATER 7732-18-5 15 - 40 KEROSENE 8008-20-6 10 - 30 HYDROTREATED LIGHT PETROLEUM 64742-47-8 5 - 10 DISTILLATES PINE OIL 8002-09-3 1 - 5 OLEIC ACID 112-80-1 1 - 5 TRIETHANOLAMINE 102-71-6 1 - 5 NAPHTHALENE 91-20-3 < 0.1 ETHYLBENZENE 100-41-4 < 0.02 BENZENE 71-43-2 < 0.0021 ------------------------------------------------------------------------ SECTION 3: PHYSICAL AND CHEMICAL PROPERTIES ------------------------------------------------------------------------ Physical form,Color,Odor Liquid Slight pine odor, white, viscous liquid. Viscous liquid. Water Solubility N/A Boiling point/boiling range 100.0 C Melting point/melting range NOT DETERMINED Vapour pressure <= 16 psia CONDITIONS: @ 55.0 C. Percent Volatile 29.2 % Evaporation rate >= 1 Ether=1 Vapour density NOT DETERMINED Specific gravity 1.17 - 1.22 Water=1 Flash point >= 82.22 C Autoflammability NOT DETERMINED Flammable Limits - LEL NOT DETERMINED Flammable Limits - UEL NOT DETERMINED Viscosity 13000 - 19000 centipoise ------------------------------------------------------------------------ SECTION 4: HAZARD IDENTIFICATION ------------------------------------------------------------------------ Risk Phrases Harmful: danger of serious damage to health by prolonged exposure through inhalation. Toxic to aquatic organisms. May cause long-term adverse effects in the aquatic environment. ------------------------------------------------------------------------ SECTION 5: FIRST AID MEASURES ------------------------------------------------------------------------ Instructions for Ingestion Do not induce vomiting unless instructed to do so by medical personnel. Give victim two glasses of water. Never give anything by mouth to an unconscious person. Get medical attention. Instructions for Eye Contact Flush eyes with large amounts of water. If signs/symptoms persist, get medical attention. Instructions for Skin Contact Remove contaminated clothing and shoes. Immediately flush skin with large amounts of water. Get medical attention. Wash contaminated clothing and clean shoes before reuse. Instructions for Inhalation Remove person to fresh air. If signs/symptoms develop, get medical attention. ------------------------------------------------------------------------ SECTION 6: FIRE FIGHTING MEASURES ------------------------------------------------------------------------ Suitable Extinguishing Media Use fire extinguishers with class B extinguishing agents (e.g., dry chemical, carbon dioxide). Fire Fighting Procedures Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and prevent explosive rupture. Water may be used to blanket the fire. Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatus (SCBA). Exposure Hazards during Fire Closed containers exposed to heat from fire may build pressure and explode. Vapors may travel long distances along the ground or floor to an ignition source and flash back. ------------------------------------------------------------------------ SECTION 7: ACCIDENTAL RELEASE MEASURE ------------------------------------------------------------------------ Spill Response For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Evacuate unprotected and untrained personnel from hazard area. The spill should be cleaned up by qualified personnel. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn or explode. Contain spill. Collect as much of the spilled material as possible using non-sparking tools. Clean up residue with detergent and water. Place in a metal container approved for transportation by appropriate authorities. Dispose of collected material as soon as possible. Methods for Disposal Not applicable. ------------------------------------------------------------------------ SECTION 8: HANDLING AND STORAGE ------------------------------------------------------------------------ Storage Requirements Keep from freezing. Incompatible Materials Store away from acids. Store away from heat. Store out of direct sunlight. Store away from oxidizing agents. Ventilation Keep container in well-ventilated area. Fire Prevention No smoking while handling this material. Explosion Prevention Keep away from heat, sparks, open flame, pilot lights and other sources of ignition. Use Instructions Avoid eye contact. Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Contents may be under pressure, open carefully. Avoid breathing of vapors, mists or spray. Avoid prolonged or repeated skin contact. Avoid eye contact with vapors, mists, or spray. Do not breathe vapors. Do not breathe dust. Avoid contact with oxidizing agents. ------------------------------------------------------------------------ SECTION 9: EXP0SURE CONTROL AND PERSONAL PROTECTION ------------------------------------------------------------------------ QUARTZ SILICA (14808-60-7) Exposure Limits 0.025 mg/m3 ACGIH: TWA; respirable; Table A2; Comments: From 2006 ACGIH TLV Book. KEROSENE (8008-20-6) Exposure Limits 200 mg/m3 2000 mg/m3 500 ppm ACGIH: TWA - as vapor; Skin Notation;Table A3; as total hydrocarbon; a dded per RDC and Ariel data CMRG: TWA CMRG: TWA HYDROTREATED LIGHT PETROLEUM DISTILLATES (64742-47-8) Exposure Limits 300 ppm CMRG: TWA; PER EXXON MSDS 5/22/91 FOR EXXSOL D 110 PINE OIL (8002-09-3) Exposure Limits 100 ppm CMRG: TWA; IF USED UNDER CONDITIONS THAT GENERATE PARTICULATES (MIST), THE ACGIH TLV-TWA OF 3 MG/M3 RESPIRABLE FRACTION (10MG/M3 TOTAL) SHOU LD BE OBSERVED. TRIETHANOLAMINE (102-71-6) Exposure Limits 5 mg/m3 ACGIH: TWA NAPHTHALENE (91-20-3) Exposure Limits 79 mg/m3 15 ppm 52 mg/m3 10 ppm ACGIH: STEL; skin contact contributes to exposure; Table A4; Comments: added Skin designation per 2003 ACGIH book ACGIH: STEL; skin contact contributes to exposure; Table A4; Comments: added Skin designation per 2003 ACGIH book ACGIH: TWA; skin contact contributes to exposure; Table A4; Comments: added Skin designation per 2003 ACGIH book ACGIH: TWA; skin contact contributes to exposure; Table A4; Comments: added Skin designation per 2003 ACGIH book ETHYLBENZENE (100-41-4) Exposure Limits 125 ppm ACGIH: STEL; Table A3; Comments: added A3 per 2003 ACGIH book 100 ppm ACGIH: TWA; Table A3; Comments: added A3 per 2003 ACGIH book. BENZENE (71-43-2) Exposure Limits 2.5 ppm ACGIH: STEL; skin contact contributes to exposure; Table A1; Comments: added STEL per 1998 ACGIH TLV booklet. 30 mg/m3 ACGIH: TWA; skin contact contributes to exposure; Table A1; Comments: updated limits and appendix per 1998 ACGIH TLV booklet. 0.5 ppm ACGIH: TWA; skin contact contributes to exposure; Table A1; Comments: updated limits and appendix per 1998 ACGIH TLV booklet. Recommended Ventilation Use with appropriate local exhaust ventilation. Provide appropriate local exhaust ventilation on open containers. Use in an enclosed process area is recommended. If exhaust ventilation is not available, use appropriate respiratory protection. Eye Protection Avoid eye contact. Avoid eye contact with vapors, mists, or spray. The following should be worn alone or in combination, as appropriate, to prevent eye contact: Safety glasses with side shields Indirect Vented Goggles Hand Protection The following glove material(s) are recommended: neoprene nitrile rubber Skin Protection Avoid skin contact. Respiratory Protection Avoid breathing of vapors, mists or spray. Avoid breathing of dust. Do not breathe vapors. Do not breathe dust. Consult the current 3M Respirator Selection Guide for additional information or call 1-800-243-4630 for 3M technical assistance. Continuous spurring of dry buff pads may produce dust conditions in excess of the OSHA Permissible Exposure Limit (PEL) or the Threshold Limit Value (TLV) for crystalline silica. When cleaning or spurring a dry buff pad used with this product, use appropriate local exhaust to control dust, or use appropriate respiratory protection to avoid inhalation of dusts. Select one of the following approved respirators based on airborne concentration of contaminants and in accordance with regulations: Half facepiece or fullface air-purifying respirator with P95 particulate filters Ingestion Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Keep out of the reach of children. ------------------------------------------------------------------------ SECTION 10: STABILITY AND REACTIVITY ------------------------------------------------------------------------ Materials to Avoid Strong Oxidizing Agents Hazardous Decomposition Carbon Monoxide Carbon Dioxide Stability and Reactivity Stable Hazardous polymerization will not occur. ------------------------------------------------------------------------ SECTION 11: TOXICOLOGICAL INFORMATION ------------------------------------------------------------------------ Effects from Eye Contact Mild Eye Irritation: Signs/symptoms may include redness, pain, and tearing. Effects from Skin Contact May be absorbed through skin and cause target organ effects. Moderate Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness. Effects from Inhalation May be absorbed following inhalation and cause target organ effects. Intentional concentration and inhalation may be harmful or fatal. Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Prolonged or repeated exposure may cause: Silicosis: Signs/symptoms may include breathlessness, weakness, chest pain, persistent cough, increased amounts of sputum, and heart disease. Effects from Ingestion May be absorbed following ingestion and cause target organ effects. Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. Carcinogenicity Contains a chemical or chemicals which can cause cancer. Other Toxicological Information Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness. Prolonged or repeated exposure may cause: Kidney/Bladder Effects: Signs/symptoms may include changes in urine production, abdominal or lower back pain, increased protein in urine, increased blood urea nitrogen (BUN), blood in urine, and painful urination. ------------------------------------------------------------------------ SECTION 12: ECOLOGICAL INFORMATION ------------------------------------------------------------------------ Environmental Data No data available. Ecotoxicity Data Not determined. Ecofate Data Not determined. Special statements for 2001/58/EC European VOC content 382.26 g/L. ------------------------------------------------------------------------ SECTION 13: DISPOSAL INFORMATION ------------------------------------------------------------------------ Product as Sold Incinerate in a permitted hazardous waste incinerator. As a disposal alternative, dispose of waste product in a permitted hazardous waste facility. ------------------------------------------------------------------------ SECTION 14: TRANSPORT INFORMATION ------------------------------------------------------------------------ UN Number IMO Class ICAO Class Special Instructions ** NOT HAZARDOUS FOR TRANSPORT FOR DOT, IMO, OR IATA. ------------------------------------------------------------------------ SECTION 15: REGULATORY INFORMATION ------------------------------------------------------------------------ Symbols Xn Harmful N Dangerous to environment Risk Phrases Harmful: danger of serious damage to health by prolonged exposure through inhalation. Toxic to aquatic organisms. May cause long-term adverse effects in the aquatic environment. Safety Phrases S22 Do not breathe dust. Do not breathe vapor. Use only in well ventilated areas. S24/25 Avoid contact with the skin and eyes. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S28B After contact with skin, wash immediately with plenty of water. If swallowed, seek medical advice immediately and show this container or label. Avoid release to the environment. Refer to special instructions/safety data sheets. Keep out of the reach of children. Special Regulatory Information Contact 3M for more information. ------------------------------------------------------------------------ SECTION 16: OTHER INFORMATION ------------------------------------------------------------------------ Reason for Reissue Reissued due to exposure limit changes. The information on this data sheet represents our current data and best opinion as to the proper use in handling of this product under normal conditions. Any use of the product which is not in conformance with this data sheet or which involves using the product in combination with any other product or any other process is the responsibility of the user.