3M MALAYSIA SDN BHD ======================================================================== CHEMICAL SAFETY DATA SHEET ======================================================================== Document id : 11-2664-8 Issue date : 27/06/2006 Version : 4.00 Supersedes date : 09/11/2004 Document status : Issued This CSDS has been prepared by Toxicology Department 3M Malaysia Sdn. Bhd. ------------------------------------------------------------------------ SECTION 1: CHEMICAL PRODUCT AND COMPANY IDENTIFICATION ------------------------------------------------------------------------ Tradename PRONTO (TM) CA-100 INSTANT ADHESIVE (PA) 3M Product ID: 62-3873-0330-8, 62-3873-0335-7, 62-3873-3830-4 Intended Use of Product Structural Strength Instant Adhesive. COMPANY IDENTIFICATION ---------------------- Manufacturer's name and address 3M 3M Center St. Paul, Minnesota 55144-1000 USA Importer's name and address 3M Malaysia Sdn. Bhd. Bangunan 3M No. 6, Persiaran Tropicana 47410 Petaling Jaya Selangor Telephone number 03-7806-2888 Emergency telephone number 1-651-7376501 ( 24 hours ) CONTACT POINT ------------- Designation Toxicology Coordinator Telephone number 03-7806-2888 ------------------------------------------------------------------------ SECTION 2: COMPOSITION/INFORMATION ON INGREDIENT ------------------------------------------------------------------------ Ingredient name CAS number Percentage ------------------------------------- ------------------ ------------- ETHYL CYANOACRYLATE 7085-85-0 60 - 100 POLY(METHYL METHACRYLATE) 9011-14-7 10 - 30 HYDROQUINONE 123-31-9 0.1 - 0.5 ------------------------------------------------------------------------ SECTION 3: PHYSICAL AND CHEMICAL PROPERTIES ------------------------------------------------------------------------ Physical form,Color,Odor DETAILS: Viscous Liquid Liquid Clear, colorless, sharp irritating odor thin liquid Water Solubility NOT DETERMINED NIL Boiling point/boiling range = 65 C CONDITIONS: @ 6 MMHG Melting point/melting range N/A Vapour pressure = 1 mmHg CONDITIONS: @ 20 C NOT DETERMINED Percent Volatile = 0 % by wt N/A Evaporation rate N/A <<< Vapour density NOT DETERMINED NOT DETERMINED Specific gravity = 1.05 Water=1 Flash point = 85 C TCC Autoflammability NOT DETERMINED Flammable Limits - LEL NOT DETERMINED Flammable Limits - UEL NOT DETERMINED Viscosity 2500 - 4500 centipoise ------------------------------------------------------------------------ SECTION 4: HAZARD IDENTIFICATION ------------------------------------------------------------------------ Risk Phrases CYANOACRYLATE, DANGER: Bonds skin and eyes in seconds. Irritating to eyes, respiratory system and skin. CONTAINS HYDROQUINONE. May produce an allergic reaction. ------------------------------------------------------------------------ SECTION 5: FIRST AID MEASURES ------------------------------------------------------------------------ Instructions for Ingestion Do not induce vomiting. Get immediate medical attention. Give victim two glasses of water. Never give anything by mouth to an unconscious person. Instructions for Eye Contact Get immediate medical attention. Immediately flush eyes with large amounts of water for at least 15 minutes. DO NOT force eyelids open. Instructions for Skin Contact FOR SKIN BONDS: Quickly soak in warm water and avoid use of excessive force to free bonded area. If unable to free bonded area, or if lips or mouth are bonded, get medical attention. If irritation persists, get medical attention. Instructions for Inhalation Remove person to fresh air. If signs/symptoms develop, get medical attention. ------------------------------------------------------------------------ SECTION 6: FIRE FIGHTING MEASURES ------------------------------------------------------------------------ Suitable Extinguishing Media Use fire extinguishers with class B extinguishing agents (e.g., dry chemical, carbon dioxide). Fire Fighting Procedures Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and prevent explosive rupture. Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatus (SCBA). Exposure Hazards during Fire Closed containers exposed to heat from fire may build pressure and explode. Vapors may travel long distances along the ground or floor to an ignition source and flash back. ------------------------------------------------------------------------ SECTION 7: ACCIDENTAL RELEASE MEASURE ------------------------------------------------------------------------ Spill Response Evacuate unprotected and untrained personnel from hazard area. The spill should be cleaned up by qualified personnel. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn or explode. Contain spill. Collect as much of the spilled material as possible. Collect as much of the spilled material as possible using non-sparking tools. Place in a closed container approved for transportation by appropriate authorities. Methods for Disposal Not applicable. Special Instructions, Accidental Release DO NOT wipe spill or residue with cleanup materials containing cotton. ------------------------------------------------------------------------ SECTION 8: HANDLING AND STORAGE ------------------------------------------------------------------------ Storage Requirements Store away from flammable and combustible materials. Incompatible Materials Store away from acids. Store away from heat. Store out of direct sunlight. Store away from oxidizing agents. Explosion Prevention Keep away from heat, sparks, open flame, pilot lights and other sources of ignition. Combustible liquid and vapor. Use Instructions Keep container tightly closed. Avoid contact with oxidizing agents. ------------------------------------------------------------------------ SECTION 9: EXP0SURE CONTROL AND PERSONAL PROTECTION ------------------------------------------------------------------------ ETHYL CYANOACRYLATE (7085-85-0) Exposure Limits 0.2 ppm ACGIH: TWA; ADDED per 1998 ACGIH TLV booklet HYDROQUINONE (123-31-9) Exposure Limits 2 mg/m3 4 mg/m3 ACGIH: TWA; Table A3; added A3 per 1998 ACGIH TLV booklet CMRG: STEL; Per Rohm & Haas MSDS dated 6/10/1998 for 11-0000-3327-1 Recommended Ventilation Use with appropriate local exhaust ventilation. Do not use in a confined area or areas with little or no air movement. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below Occupational Exposure Limits and/or control mist, vapor, or spray. If ventilation is not adequate, use respiratory protection equipment. Eye Protection Avoid eye contact with vapors, mists, or spray. The following should be worn alone or in combination, as appropriate, to prevent eye contact: Safety glasses with side shields Indirect Vented Goggles Hand Protection The following glove material(s) are recommended: butyl rubber polyethylene/ethylene vinyl alcohol polyvinyl alcohol Skin Protection Avoid skin contact. DO NOT wear cotton gloves. The following protective clothing material(s) are recommended: Apron - Polyethylene/ethylene vinyl alcohol Respiratory Protection Avoid breathing of vapors, mists or spray. Select one of the following approved respirators based on airborne concentration of contaminants and in accordance with regulations: Half facepiece air-purifying respirator with organic vapor cartridges and N95 particulate prefilters Ingestion Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Keep out of the reach of children. ------------------------------------------------------------------------ SECTION 10: STABILITY AND REACTIVITY ------------------------------------------------------------------------ Materials to Avoid Strong Bases Amines May occur in large quantities only. Hazardous Decomposition Carbon monoxide During Combustion Carbon dioxide During Combustion Oxides of Nitrogen During Combustion Stability and Reactivity Stable Hazardous polymerization may occur. ------------------------------------------------------------------------ SECTION 11: TOXICOLOGICAL INFORMATION ------------------------------------------------------------------------ Effects from Eye Contact Severe Eye Irritation: Signs/symptoms may include significant redness, swelling, pain, tearing, cloudy appearance of the cornea, and impaired vision. Bonds eyelids rapidly. Effects from Skin Contact Moderate Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness. Bonds skin rapidly. Prolonged or repeated exposure may cause: Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching. Effects from Inhalation Upper Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Effects from Ingestion Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, nausea, diarrhea and vomiting. ------------------------------------------------------------------------ SECTION 12: ECOLOGICAL INFORMATION ------------------------------------------------------------------------ Environmental Data No data available. Ecotoxicity Data Not determined. Ecofate Data Not determined. ------------------------------------------------------------------------ SECTION 13: DISPOSAL INFORMATION ------------------------------------------------------------------------ Product as Sold Dispose of completely cured (or polymerized) wastes in a sanitary landfill. Incinerate in an industrial or commercial facility. As a disposal alternative, dispose of waste product in a facility permitted to accept chemical waste. Potential for Recycling Reclaim if feasible. ------------------------------------------------------------------------ SECTION 14: TRANSPORT INFORMATION ------------------------------------------------------------------------ UN Number IMO Class ICAO Class Special Instructions ** NOT HAZARDOUS FOR TRANSPORT FOR DOT, IMO, OR IATA. ------------------------------------------------------------------------ SECTION 15: REGULATORY INFORMATION ------------------------------------------------------------------------ Symbols Xi Irritant Risk Phrases CYANOACRYLATE, DANGER: Bonds skin and eyes in seconds. Irritating to eyes, respiratory system and skin. CONTAINS HYDROQUINONE. May produce an allergic reaction. Safety Phrases Keep out of the reach of children. Use only in well ventilated areas. Do not breathe vapor. S24/25 Avoid contact with the skin and eyes. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. If eyelids are bonded, do not force open. In case of skin bonding, quickly soak in warm water and avoid excessive force to free bonded area. Special Regulatory Information Contact 3M for more information. ------------------------------------------------------------------------ SECTION 16: OTHER INFORMATION ------------------------------------------------------------------------ Reason for Reissue Change in product name. Complete document review with multiple sections updated. New health hazard information. The information on this data sheet represents our current data and best opinion as to the proper use in handling of this product under normal conditions. Any use of the product which is not in conformance with this data sheet or which involves using the product in combination with any other product or any other process is the responsibility of the user.