3M MALAYSIA SDN BHD ======================================================================== CHEMICAL SAFETY DATA SHEET ======================================================================== Document id : 11-0744-0 Issue date : 21/08/2008 Version : 1.00 Supersedes date : --- Document status : Issued This CSDS has been prepared by Toxicology Department 3M Malaysia Sdn. Bhd. ------------------------------------------------------------------------ SECTION 1: CHEMICAL PRODUCT AND COMPANY IDENTIFICATION ------------------------------------------------------------------------ Tradename SCOTCH(TM) 2228 RUBBER MASTIC TAPE 3M Product ID: 78-8055-7098-9, 80-6103-2294-5, 80-6107-3766-2, 80-6109-2896-4, 80-6112-0077-7, 80-6112-1055-2, 80-6112-1056-0, 80-6112-1186-5, 80-6114-1998-9 Intended Use of Product ELECTRICAL INSULATION AND MOISTURE SEALING. COMPANY IDENTIFICATION ---------------------- Manufacturer's name and address 3M 3M Center St. Paul, Minnesota 55144-1000 USA Importer's name and address 3M Malaysia Sdn. Bhd. Bangunan 3M No. 6, Persiaran Tropicana 47410 Petaling Jaya Selangor Telephone number 03-7806-2888 Emergency telephone number 1-651-7376501 ( 24 hours ) CONTACT POINT ------------- Designation Toxicology Coordinator Telephone number 03-7806-2888 ------------------------------------------------------------------------ SECTION 2: COMPOSITION/INFORMATION ON INGREDIENT ------------------------------------------------------------------------ Ingredient name CAS number Percentage ------------------------------------- ------------------ ------------- ALUMINA TRIHYDRATE 21645-51-2 48 - 58 POLYISOBUTYLENE 9003-27-4 18 - 28 POLYBUTYLENE 9003-29-6 10 - 20 ETHYLENE-PROPYLENE- 25038-36-2 8 - 18 ETHYLIDENENORBORNENE TERPOLYMER CALCIUM CARBONATE 471-34-1 8 - 18 Exposure Limits: 20 mg/m3 CMRG: STEL 10 mg/m3 CMRG: TWA KAOLIN 1332-58-7 5 - 15 Exposure Limits: 2 mg/m3 ACGIH: TWA; respirable; Table A4 POLYPROPYLENE 9003-07-0 5 - 10 Exposure Limits: 5 mg/m3 10 mg/m3 CMRG TWA : AS RESPIRABLE DUST CMRG TWA : AS TOTAL DUST CARBON BLACK 1333-86-4 5 - 10 Exposure Limits: 3.5 mg/m3 0.5 mg/m3 ACGIH: TWA; Table A4 CMRG: TWA; DUPONT MSDS DATED 1/6/99 FOR 11-0018-9474-7. EPDM/POLYOLEFIN BLEND Unknown 3 - 8 ISOBUTYLENE-ISOPRENE POLYMER 9010-85-9 4 - 8 PIPERYLENE-2-METHYL-2-BUTENE POLYMER 26813-14-9 4 - 8 SOLVENT-REFINED HEAVY PARAFFINIC 64741-88-4 2 - 7 PETROLEUM DISTILLATES Exposure Limits: 5 mg/m3 CMRG: TWA 1-Hexene,polymer with 1,3- 68003-51-0 2 - 8 cyclopentadiene and other isomers ASPHALT 8052-42-4 2 - 4 Exposure Limits: 0.5 mg/m3 ACGIH: TWA - as fume; Table A4; CHEMICAL SUBSTANCE TLVS ADOPTED FOR 20 00. ZINC STEARATE 557-05-1 0.5 - 0.8 Exposure Limits: 20 mg/m3 10 mg/m3 10 mg/m3 ACGIH: STEL; Particulates not otherwise classified - changed to no print per 1998 ACGIH TLV booklet ACGIH: TWA - as total dust; Table A4; Particulates not otherwise class ified. - Category: STEARATES ACGIH: TWA; Particulates not otherwise classified - changed to no print per 1998 ACGIH TLV booklet. TETRAKIS[METHYLENE(3,5-DI-TERT-BUTYL- 6683-19-8 0.1 - 0.5 4-HYDROXYHYDROCINNAMATE)]METHANE Exposure Limits: 10 mg/m3 CMRG: TWA; Comments: Per Ciba MSDS dated 4/25/2006 for 11-0000-7738-5. CALCIUM SILICATE 1344-95-2 0.1 - 0.15 Exposure Limits: 10 mg/m3 ACGIH: TWA - as total dust; Table A4; ------------------------------------------------------------------------ SECTION 3: PHYSICAL AND CHEMICAL PROPERTIES ------------------------------------------------------------------------ Physical form,Color,Odor Black roll with release liner. Water Solubility Nil. Boiling point/boiling range N/A Melting point/melting range NOT DETERMINED Vapour pressure N/A Percent Volatile No data available. Evaporation rate N/A Vapour density N/A Specific gravity CA. 1.1 Water=1 Flash point N/A Autoflammability NOT DETERMINED Flammable Limits - LEL N/A Flammable Limits - UEL N/A Viscosity N/A ------------------------------------------------------------------------ SECTION 4: HAZARD IDENTIFICATION ------------------------------------------------------------------------ Risk Phrases May cause skin irritation. ------------------------------------------------------------------------ SECTION 5: FIRST AID MEASURES ------------------------------------------------------------------------ Instructions for Ingestion No need for first aid is anticipated. Instructions for Eye Contact No need for first aid is anticipated. Instructions for Skin Contact No need for first aid is anticipated. Instructions for Inhalation No need for first aid is anticipated. ------------------------------------------------------------------------ SECTION 6: FIRE FIGHTING MEASURES ------------------------------------------------------------------------ Suitable Extinguishing Media Carbon dioxide Dry chemical Foam Fire Fighting Procedures Not applicable Special Instructions for Fire Fighting Not applicable. ------------------------------------------------------------------------ SECTION 7: ACCIDENTAL RELEASE MEASURE ------------------------------------------------------------------------ Spill Response Not applicable. Methods for Disposal As a disposal alternative, incinerate in an industrial or commercial facility in the presence of a combustible material. Disposal alternative: Dispose of waste product in a sanitary landfill. ------------------------------------------------------------------------ SECTION 8: HANDLING AND STORAGE ------------------------------------------------------------------------ Storage Requirements Not applicable. Explosion Prevention Keep away from heat, sparks, open flame, pilot lights and other sources of ignition. ------------------------------------------------------------------------ SECTION 9: EXP0SURE CONTROL AND PERSONAL PROTECTION ------------------------------------------------------------------------ CALCIUM CARBONATE (471-34-1) Exposure Limits 20 mg/m3 CMRG: STEL 10 mg/m3 CMRG: TWA KAOLIN (1332-58-7) Exposure Limits 2 mg/m3 ACGIH: TWA; respirable; Table A4 POLYPROPYLENE (9003-07-0) Exposure Limits 5 mg/m3 10 mg/m3 CMRG TWA : AS RESPIRABLE DUST CMRG TWA : AS TOTAL DUST CARBON BLACK (1333-86-4) Exposure Limits 3.5 mg/m3 0.5 mg/m3 ACGIH: TWA; Table A4 CMRG: TWA; DUPONT MSDS DATED 1/6/99 FOR 11-0018-9474-7. SOLVENT-REFINED HEAVY PARAFFINIC PETROLEUM DISTILLATES (64741-88-4) Exposure Limits 5 mg/m3 CMRG: TWA ASPHALT (8052-42-4) Exposure Limits 0.5 mg/m3 ACGIH: TWA - as fume; Table A4; CHEMICAL SUBSTANCE TLVS ADOPTED FOR 20 00. ZINC STEARATE (557-05-1) Exposure Limits 20 mg/m3 10 mg/m3 10 mg/m3 ACGIH: STEL; Particulates not otherwise classified - changed to no print per 1998 ACGIH TLV booklet ACGIH: TWA - as total dust; Table A4; Particulates not otherwise class ified. - Category: STEARATES ACGIH: TWA; Particulates not otherwise classified - changed to no print per 1998 ACGIH TLV booklet. TETRAKIS[METHYLENE(3,5-DI-TERT-BUTYL-4-HYDROXYHYDROCINNAMATE)]METHANE (6683- 19-8) Exposure Limits 10 mg/m3 CMRG: TWA; Comments: Per Ciba MSDS dated 4/25/2006 for 11-0000-7738-5. CALCIUM SILICATE (1344-95-2) Exposure Limits 10 mg/m3 ACGIH: TWA - as total dust; Table A4; Recommended Ventilation Not applicable. Eye Protection Not applicable. Hand Protection Not applicable. Skin Protection Not applicable. Respiratory Protection Under normal use conditions, airborne exposures are not expected to be significant enough to require respiratory protection. Ingestion Not applicable. ------------------------------------------------------------------------ SECTION 10: STABILITY AND REACTIVITY ------------------------------------------------------------------------ Materials to Avoid Not applicable. Hazardous Decomposition Carbon Monoxide and Carbon Dioxide Stability and Reactivity Stable Hazardous polymerization will not occur. ------------------------------------------------------------------------ SECTION 11: TOXICOLOGICAL INFORMATION ------------------------------------------------------------------------ Effects from Eye Contact Eye contact is not expected to occur during normal use of the product. Effects from Skin Contact Product is not expected to be irritating to the skin. Effects from Inhalation No health effects are expected. Effects from Ingestion Ingestion is not a likely route of exposure to this product. No health effects are expected. Carcinogenicity WARNING: Contains a chemical which can cause cancer. (1333-86-4, 8052-42-4) (IARC possible human carcinogen 2B) Other Toxicological Information Exposure to this material in normal storage and handling has not been reported to cause significant adverse health effects. However, under normal processing conditions, e.g. grinding or heating, this product may release fumes and vapors of variable composition based on specific process conditions. These process releases may produce irritation or any of the health effects listed above when the emissions are present at elevated concentrations. Use with appropriate local exhaust ventilation. ------------------------------------------------------------------------ SECTION 12: ECOLOGICAL INFORMATION ------------------------------------------------------------------------ Environmental Data No data available. Other Ecotoxicity Information Not determined. Since regulations vary, consult applicable regulations or authorities before disposal. ------------------------------------------------------------------------ SECTION 13: DISPOSAL INFORMATION ------------------------------------------------------------------------ Product as Sold ------------------------------------------------------------------------ SECTION 14: TRANSPORT INFORMATION ------------------------------------------------------------------------ UN Number IMO Class ICAO Class Special Instructions ** NOT DANGEROUS FOR TRANSPORT FOR DOT, IMO OR IATA. ------------------------------------------------------------------------ SECTION 15: REGULATORY INFORMATION ------------------------------------------------------------------------ Symbols None Risk Phrases May cause skin irritation. Safety Phrases Avoid prolonged or repeated contact with the skin. After contact with skin, wash with soap and water. ------------------------------------------------------------------------ SECTION 16: OTHER INFORMATION ------------------------------------------------------------------------ Reason for Reissue Updated HMIS codes 06/12/01 DBC. The information on this data sheet represents our current data and best opinion as to the proper use in handling of this product under normal conditions. Any use of the product which is not in conformance with this data sheet or which involves using the product in combination with any other product or any other process is the responsibility of the user.