3M MALAYSIA SDN BHD ======================================================================== CHEMICAL SAFETY DATA SHEET ======================================================================== Document id : 11-0426-4 Issue date : 21/09/2007 Version : 1.00 Supersedes date : --- Document status : Issued This CSDS has been prepared by Toxicology Department 3M Malaysia Sdn. Bhd. ------------------------------------------------------------------------ SECTION 1: CHEMICAL PRODUCT AND COMPANY IDENTIFICATION ------------------------------------------------------------------------ Tradename 3M(TM) GREEN CORPS (TM) FIBRE DISC PN 01921, 31922 3M Product ID: 60-9800-0987-6, 60-9800-1390-2, 60-9800-1391-0, 60-9800-4400-6, 60-9800-4406-3 Intended Use of Product COMPANY IDENTIFICATION ---------------------- Manufacturer's name and address 3M 3M Center St. Paul, Minnesota 55144-1000 USA Importer's name and address 3M Malaysia Sdn. Bhd. Bangunan 3M No. 6, Persiaran Tropicana 47410 Petaling Jaya Selangor Telephone number 03-7806-2888 Emergency telephone number 1-651-7376501 ( 24 hours ) CONTACT POINT ------------- Designation Toxicology Coordinator Telephone number 03-7806-2888 ------------------------------------------------------------------------ SECTION 2: COMPOSITION/INFORMATION ON INGREDIENT ------------------------------------------------------------------------ Ingredient name CAS number Percentage ------------------------------------- ------------------ ------------- ALUMINUM OXIDE 1344-28-1 40.0 - 80.0 PHENOL-FORMALDEHYDE POLYMER 9003-35-4 10.0 - 20.0 INORGANIC FLUORIDE 15096-52-3 10.0 - 20.0 C.I. PIGMENT GREEN 7 1328-53-6 1.0 - 5.0 HEXAMINE 100-97-0 < 2.0 PHENOL 108-95-2 < 0.5 ------------------------------------------------------------------------ SECTION 3: PHYSICAL AND CHEMICAL PROPERTIES ------------------------------------------------------------------------ Physical form,Color,Odor Green cut-off wheel. Black mesh interior. Water Solubility N/A Boiling point/boiling range N/A Melting point/melting range NOT DETERMINED Vapour pressure N/A Percent Volatile No data available. Evaporation rate N/A Vapour density N/A Specific gravity N/A Flash point N/A Autoflammability N/A Flammable Limits - LEL N/A Flammable Limits - UEL N/A Viscosity N/A ------------------------------------------------------------------------ SECTION 4: HAZARD IDENTIFICATION ------------------------------------------------------------------------ Risk Phrases None ------------------------------------------------------------------------ SECTION 5: FIRST AID MEASURES ------------------------------------------------------------------------ Instructions for Ingestion Drink two glasses of water. Call a physician. Instructions for Eye Contact Immediately flush eyes with large amounts of water. Get immediate medical attention. Instructions for Skin Contact Wash affected area with soap and water. Instructions for Inhalation If signs/symptoms occur, remove person to fresh air. If signs/symptoms continue, call a physician. ------------------------------------------------------------------------ SECTION 6: FIRE FIGHTING MEASURES ------------------------------------------------------------------------ Suitable Extinguishing Media Water Carbon dioxide Dry chemical Foam Fire Fighting Procedures None known. Special Instructions for Fire Fighting None known. ------------------------------------------------------------------------ SECTION 7: ACCIDENTAL RELEASE MEASURE ------------------------------------------------------------------------ Spill Response Not applicable. Methods for Disposal As a disposal alternative, incinerate in an industrial or commercial facility in the presence of a combustible material. Dispose of waste product in a sanitary landfill. ------------------------------------------------------------------------ SECTION 8: HANDLING AND STORAGE ------------------------------------------------------------------------ Fire Prevention Not applicable. ------------------------------------------------------------------------ SECTION 9: EXP0SURE CONTROL AND PERSONAL PROTECTION ------------------------------------------------------------------------ ALUMINUM OXIDE (1344-28-1) Exposure Limits 10 mg/m3 ACGIH: TWA; particulate matter, < 1% crystalline silica; Table A4; Comments: per ACGIH 2003, for particulate matter ct no asbestos and <1% crystalline silica. 1 FIBER/CC CMRG: TWA; Comments: MAN-MADE MINERAL FIBERS. INORGANIC FLUORIDE (15096-52-3) Exposure Limits 2 mg/m3 ACGIH: TWA; as Al; Category: ALUMINUM, SOLUBLE SALTS 2.5 mg/m3 ACGIH: TWA; as F; Table A4; Category: FLUORIDES. PHENOL (108-95-2) Exposure Limits 19 mg/m3 ACGIH: TWA; skin contact contributes to exposure; Table A4; Comments: added A4 per 2003 ACGIH book. 5 ppm ACGIH: TWA; skin contact contributes to exposure; Table A4; Comments: added A4 per 2003 ACGIH book. Recommended Ventilation Use in a well-ventilated area. If exhaust ventilation is not adequate, use appropriate respiratory protection. Eye Protection Avoid eye contact. During application, wear safety glasses and full face shield. Hand Protection Not applicable. Skin Protection Not applicable. Respiratory Protection Avoid breathing of dust created by cutting, sanding, grinding or machining. Select one of the following approved respirators based on airborne concentration of contaminants and in accordance with regulations: half-mask dust respirator Ingestion Do not ingest. Keep out of the reach of children. Special Information, Exposure/Protection Avoid prolonged or repeated skin contact of grinding dust. ------------------------------------------------------------------------ SECTION 10: STABILITY AND REACTIVITY ------------------------------------------------------------------------ Materials to Avoid None known. Hazardous Decomposition Carbon Monoxide and Carbon Dioxide Stability and Reactivity Stable Hazardous polymerization will not occur. ------------------------------------------------------------------------ SECTION 11: TOXICOLOGICAL INFORMATION ------------------------------------------------------------------------ Effects from Eye Contact Mechanical eye irritation: Signs/symptoms may include pain, redness, tearing and corneal abrasion. Effects from Skin Contact Mechanical Skin irritation: Signs/symptoms may include abrasion, redness, pain, and itching. Effects from Inhalation During application: Upper Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Effects from Ingestion Ingestion is not a likely route of exposure to this product. ------------------------------------------------------------------------ SECTION 12: ECOLOGICAL INFORMATION ------------------------------------------------------------------------ Environmental Data No data available. Other Ecotoxicity Information Not determined. Since regulations vary, consult applicable regulations or authorities before disposal. ------------------------------------------------------------------------ SECTION 13: DISPOSAL INFORMATION ------------------------------------------------------------------------ Product as Sold ------------------------------------------------------------------------ SECTION 14: TRANSPORT INFORMATION ------------------------------------------------------------------------ UN Number IMO Class ICAO Class Special Instructions ** NOT HAZARDOUS FOR TRANSPORT FOR DOT, IMO OR IATA. ------------------------------------------------------------------------ SECTION 15: REGULATORY INFORMATION ------------------------------------------------------------------------ Symbols None Risk Phrases None Safety Phrases None ------------------------------------------------------------------------ SECTION 16: OTHER INFORMATION ------------------------------------------------------------------------ Reason for Reissue ADDED PN 01922; 31922 FROM ACTION LETTER JUNE 2001. The information on this data sheet represents our current data and best opinion as to the proper use in handling of this product under normal conditions. Any use of the product which is not in conformance with this data sheet or which involves using the product in combination with any other product or any other process is the responsibility of the user.