3M MALAYSIA SDN BHD ======================================================================== CHEMICAL SAFETY DATA SHEET ======================================================================== Document id : 11-6696-6 Issue date : 14/05/2007 Version : 1.00 Supersedes date : --- Document status : Issued This CSDS has been prepared by Toxicology Department 3M Malaysia Sdn. Bhd. ------------------------------------------------------------------------ SECTION 1: CHEMICAL PRODUCT AND COMPANY IDENTIFICATION ------------------------------------------------------------------------ Tradename 3M(TM) Scotchcal(TM) Translucent Graphic Film for Thermoforming 3M Product ID: 75-3465-4007-5, 75-3465-4008-3, 75-3465-4009-1, 75-3465-4010-9, 75-3465-4011-7, 75-3465-4012-5, 75-3465-4013-3, 75-3465-4014-1, 75-3465-4015-8, 75-3465-4016-6, 75-3465-4017-4, 75-3465-4018-2, 75-3465-4019-0, 75-3465-4020-8, 75-3465-4021-6, 75-3465-4022-4, 75-3465-4023-2, 75-3465-4024-0, 75-3465-4025-7, 75-3465-4026-5, 75-3465-4027-3, 75-3465-4028-1, 75-3465-4029-9, 75-3465-4030-7, 75-3465-4031-5, 75-3465-4032-3, 75-3465-4033-1, 75-3465-4034-9, 75-3465-4035-6, 75-3465-4036-4, 75-3465-4037-2, 75-3465-4082-8, 75-3465-4083-6, 75-3465-4084-4, 75-3465-4085-1, 75-3465-4086-9, 75-3465-4087-7, 75-3465-4088-5, 75-3465-4089-3, 75-3465-4090-1, 75-3465-4091-9, 75-3465-4092-7, 75-3465-4093-5, 75-3465-4094-3, 75-3465-4095-0, 75-3465-4096-8, 75-3465-4097-6, 75-3465-4098-4, 75-3465-4099-2, 75-3465-4100-8, 75-3465-4101-6, 75-3465-4102-4, 75-3465-4193-3, 75-3465-4194-1, 75-3465-4195-8, 75-3465-4196-6, 75-3465-4197-4, 75-3465-4198-2, 75-3465-4199-0, 75-3465-5200-5, 75-3465-5201-3, 75-3465-5202-1, 75-3465-5203-9, 75-3465-5204-7, 75-3465-5205-4, 75-3465-5206-2, 75-3465-5207-0, 75-3465-5208-8, 75-3465-5209-6, 75-3465-5210-4, 75-3465-5211-2, 75-3465-5212-0, 75-3465-5213-8, 75-3465-5649-3, 75-3465-5650-1, 75-3465-5651-9, 75-3465-5652-7, 75-3465-5653-5, 75-3465-5654-3, 75-3465-5655-0, 75-3465-5656-8, 75-3465-5657-6, 75-3465-5658-4, 75-3465-5659-2, 75-3465-5660-0, 75-3465-5661-8, 75-3465-5662-6, 75-3465-5663-4, 75-3465-5664-2, 75-3465-5665-9, 75-3465-5666-7, 75-3465-5667-5, 75-3465-5668-3, 75-3465-5669-1, 75-3465-7722-6, 75-3465-7723-4, 75-3465-7724-2, 75-3465-7725-9, 75-3465-7726-7, 75-3465-7727-5, 75-3465-7728-3, 75-3465-7729-1, 75-3465-7730-9, 75-3465-7731-7, 75-3465-7732-5, 75-3465-7733-3, 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75-3455-9325-7, 75-3455-9327-3, 75-3455-9335-6, 75-3465-0362-8, 75-3465-0363-6, 75-3465-0365-1, 75-3465-0377-6, 75-3465-0383-4, 75-3465-0384-2, 75-3465-0391-7, 75-3465-0514-4, 75-3465-0519-3, 75-3465-0521-9, 75-3465-0522-7, 75-3465-0524-3, 75-3465-0587-0, 75-3465-0588-8, 75-3465-0589-6, 75-3465-0590-4, 75-3465-0591-2, 75-3465-0592-0, 75-3465-0594-6, 75-3465-0595-3, 75-3465-0597-9, 75-3465-0598-7, 75-3465-0600-1, 75-3465-0601-9, 75-3465-0602-7, 75-3465-0607-6, 75-3465-0608-4, 75-3465-0609-2, 75-3465-0610-0, 75-3465-0613-4, 75-3465-0614-2, 75-3465-0615-9, 75-3465-0617-5, 75-3465-0619-1, 75-3465-0621-7, 75-3465-0622-5, 75-3465-0624-1, 75-3465-0625-8, 75-3465-0626-6, 75-3465-0628-2, 75-3465-0629-0, 75-3465-0636-5, 75-3465-0640-7, 75-3465-0643-1, 75-3465-0645-6, 75-3465-0647-2, 75-3465-0648-0, 75-3465-0649-8, 75-3465-0650-6, 75-3465-0653-0, 75-3465-0658-9, 75-3465-0661-3 Intended Use of Product Thermoforming Film. COMPANY IDENTIFICATION ---------------------- Manufacturer's name and address 3M 3M Center St. Paul, Minnesota 55144-1000 USA Importer's name and address 3M Malaysia Sdn. Bhd. Bangunan 3M No. 6, Persiaran Tropicana 47410 Petaling Jaya Selangor Telephone number 03-7806-2888 Emergency telephone number 1-651-7376501 ( 24 hours ) CONTACT POINT ------------- Designation Toxicology Coordinator Telephone number 03-7806-2888 ------------------------------------------------------------------------ SECTION 2: COMPOSITION/INFORMATION ON INGREDIENT ------------------------------------------------------------------------ Ingredient name CAS number Percentage ------------------------------------- ------------------ ------------- PVC FILM Trade Secret 70 - 90 Acrylic Adhesive Trade Secret 10 - 30 LEAD CHROMATE 7758-97-6 0 - 0.99 CARBON BLACK 1333-86-4 0 - 0.99 ------------------------------------------------------------------------ SECTION 3: PHYSICAL AND CHEMICAL PROPERTIES ------------------------------------------------------------------------ Physical form,Color,Odor Solid Film Adhesive Coated Film, Colored. Adhesive coated film. Water Solubility NIL Boiling point/boiling range N/A Melting point/melting range NOT DETERMINED Vapour pressure N/A Percent Volatile N/A Evaporation rate N/A Vapour density N/A Specific gravity N/A Flash point N/A Autoflammability NOT DETERMINED Flammable Limits - LEL N/A Flammable Limits - UEL N/A Viscosity No data available. ------------------------------------------------------------------------ SECTION 4: HAZARD IDENTIFICATION ------------------------------------------------------------------------ Risk Phrases None ------------------------------------------------------------------------ SECTION 5: FIRST AID MEASURES ------------------------------------------------------------------------ Instructions for Ingestion No need for first aid is anticipated. Instructions for Eye Contact Immediately flush eyes with large amounts of water for at least 15 minutes. DO NOT ATTEMPT TO REMOVE MOLTEN MATERIAL. Get immediate medical attention. Instructions for Skin Contact Immediately flush skin with large amounts of cold water for at least 15 minutes. DO NOT ATTEMPT TO REMOVE MOLTEN MATERIAL. Cover affected area with a clean dressing. Get immediate medical attention. Instructions for Inhalation Remove person to fresh air. If signs/symptoms develop, get medical attention. ------------------------------------------------------------------------ SECTION 6: FIRE FIGHTING MEASURES ------------------------------------------------------------------------ Suitable Extinguishing Media Ordinary combustible material. Use fire extinguishers with class A extinguishing agents (e.g., water, foam). Fire Fighting Procedures Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatus (SCBA). Special Instructions for Fire Fighting Not applicable. ------------------------------------------------------------------------ SECTION 7: ACCIDENTAL RELEASE MEASURE ------------------------------------------------------------------------ Spill Response Not applicable. Methods for Disposal Not applicable. ------------------------------------------------------------------------ SECTION 8: HANDLING AND STORAGE ------------------------------------------------------------------------ Storage Requirements Store in a cool, dry place. Use Instructions Avoid skin contact with hot material. Avoid eye contact with vapors, mists, or spray. For industrial or professional use only. ------------------------------------------------------------------------ SECTION 9: EXP0SURE CONTROL AND PERSONAL PROTECTION ------------------------------------------------------------------------ LEAD CHROMATE (7758-97-6) Exposure Limits 0.012 mg/m3 0.05 mg/m3 0.05 mg/m3 ACGIH: TWA - specific form; as Cr; Table A2; added chromium limit per 1998 ACGIH TLV booklet. ACGIH: TWA - specific form; as Pb; Table A2; further defined limit per 1998 ACGIH TLV booklet. ACGIH: TWA - specific form; as Pb; Table A3 - Category: LEAD, INORGANIC COMPOUNDS. CARBON BLACK (1333-86-4) Exposure Limits 3.5 mg/m3 0.5 mg/m3 ACGIH: TWA; Table A4 CMRG: TWA; DUPONT MSDS DATED 1/6/99 FOR 11-0018-9474-7. Recommended Ventilation Use with appropriate local exhaust ventilation. Provide appropriate local exhaust for molten or extruded material. Use in a well-ventilated area. Provide appropriate local exhaust when product is heated. Provide ventilation adequate to control dust concentrations below recommended exposure limits and/or control dust. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below Occupational Exposure Limits and/or control dust, fume, or airborne particles. If ventilation is not adequate, use respiratory protection equipment. Eye Protection Avoid eye contact with vapors, mists, or spray. Avoid eye contact with dust or airborne particles. The following should be worn alone or in combination, as appropriate, to prevent eye contact: Safety glasses with side shields Indirect Vented Goggles Hand Protection Wear appropriate gloves, such as Nomex, when handling this material to prevent thermal burns. Avoid skin contact with hot material. Gloves are not required. Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible materials. Skin Protection Avoid skin contact. Respiratory Protection Avoid breathing of vapors. Ingestion Not applicable. Not an expected route of exposure. ------------------------------------------------------------------------ SECTION 10: STABILITY AND REACTIVITY ------------------------------------------------------------------------ Materials to Avoid None known. Hazardous Decomposition Carbon monoxide During Combustion Carbon dioxide During Combustion Hydrogen Chloride During Combustion Stability and Reactivity Hazardous polymerization will not occur. Stable ------------------------------------------------------------------------ SECTION 11: TOXICOLOGICAL INFORMATION ------------------------------------------------------------------------ Effects from Eye Contact During heating: Thermal Burns: Signs/symptoms may include severe pain, redness and swelling, and tissue destruction. Vapors from heated material may cause eye irritation. Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision. Effects from Skin Contact During heating: Thermal Burns: Signs/symptoms may include intense pain, redness and swelling, and tissue destruction. Effects from Inhalation During heating: Vapors from heated material may cause irritation of the respiratory system. Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Effects from Ingestion No health effects are expected. ------------------------------------------------------------------------ SECTION 12: ECOLOGICAL INFORMATION ------------------------------------------------------------------------ Environmental Data No data available. Ecotoxicity Data Not determined. Ecofate Data Not determined. Special statements for 2001/58/EC A conservative assessment indicates this product presents a low environmental risk because use and disposal are unlikely to result in the significant release of components to the environment. ------------------------------------------------------------------------ SECTION 13: DISPOSAL INFORMATION ------------------------------------------------------------------------ Product as Sold Dispose of waste product in a permitted hazardous waste facility. ------------------------------------------------------------------------ SECTION 14: TRANSPORT INFORMATION ------------------------------------------------------------------------ UN Number IMO Class ICAO Class Special Instructions ** NOT HAZARDOUS FOR TRANSPORT FOR DOT, IMO OR IATA. ------------------------------------------------------------------------ SECTION 15: REGULATORY INFORMATION ------------------------------------------------------------------------ Symbols None Risk Phrases None Safety Phrases None Special Regulatory Information Contact 3M for more information. ------------------------------------------------------------------------ SECTION 16: OTHER INFORMATION ------------------------------------------------------------------------ Reason for Reissue The MSDS has been revised because 3M has adopted the 16-section ANSI/ISO format. The potential hazards of the product have not changed. We encourage you to reread the MSDS and review the information. The information on this data sheet represents our current data and best opinion as to the proper use in handling of this product under normal conditions. Any use of the product which is not in conformance with this data sheet or which involves using the product in combination with any other product or any other process is the responsibility of the user.