3M MALAYSIA SDN BHD ======================================================================== CHEMICAL SAFETY DATA SHEET ======================================================================== Document id : 18-0901-1 Issue date : 17/10/2007 Version : 1.00 Supersedes date : --- Document status : Issued This CSDS has been prepared by Toxicology Department 3M Malaysia Sdn. Bhd. ------------------------------------------------------------------------ SECTION 1: CHEMICAL PRODUCT AND COMPANY IDENTIFICATION ------------------------------------------------------------------------ Tradename 3M(TM) Scotch-Weld(TM) Concrete Repair 600, Self-Leveling, Gray (Part B) 3M Product ID: 62-2649-8535-9, 62-2649-9535-8 Intended Use of Product Structural adhesive COMPANY IDENTIFICATION ---------------------- Manufacturer's name and address 3M 3M Center St. Paul, Minnesota 55144-1000 USA Importer's name and address 3M Malaysia Sdn. Bhd. Bangunan 3M No. 6, Persiaran Tropicana 47410 Petaling Jaya Selangor Telephone number 03-7806-2888 Emergency telephone number 1-651-7376501 ( 24 hours ) CONTACT POINT ------------- Designation Toxicology Coordinator Telephone number 03-7806-2888 ------------------------------------------------------------------------ SECTION 2: COMPOSITION/INFORMATION ON INGREDIENT ------------------------------------------------------------------------ Ingredient name CAS number Percentage ------------------------------------- ------------------ ------------- Polyether Polyol 9082-00-2 40 - 70 Propoxylated trimethylolpropane 25723-16-4 10 - 30 Tetrakis(2-hydroxypropyl) 102-60-3 10 - 30 ethylenediamine Amorphous Silica 68611-44-9 1 - 5 m-Xylene-alpha,alpha-diamine 1477-55-0 0.1 - 1 BIS(1,2,2,6,6-PENTAMETHYL-4- 41556-26-7 0.1 - 1 PIPERIDINYL) SEBACATE Polymeric Benzotriazole Derivative 104810-48-2 0.1 - 0.3 Polymeric Benzotriazole 104810-47-1 0.1 - 0.3 Substituted Piperydinyl Sebacate 82919-37-7 0.05 - 0.2 ------------------------------------------------------------------------ SECTION 3: PHYSICAL AND CHEMICAL PROPERTIES ------------------------------------------------------------------------ Physical form,Color,Odor Liquid Slight ammonia like odor, gray. Water Solubility <<< Boiling point/boiling range >= 204.44 C Melting point/melting range NOT DETERMINED Vapour pressure N/A Percent Volatile <= 1 % by vol Estimated Evaporation rate <= 1 Vapour density >= 1 Specific gravity 1.04 Flash point >= 143.33 C TCC Autoflammability N/A Flammable Limits - LEL N/A Flammable Limits - UEL N/A Viscosity 3,200 - 5,600 centipoise ------------------------------------------------------------------------ SECTION 4: HAZARD IDENTIFICATION ------------------------------------------------------------------------ Risk Phrases None ------------------------------------------------------------------------ SECTION 5: FIRST AID MEASURES ------------------------------------------------------------------------ Instructions for Ingestion Do not induce vomiting. Give victim two glasses of water. Never give anything by mouth to an unconscious person. Get immediate medical attention. Instructions for Eye Contact Flush eyes with large amounts of water. If signs/symptoms persist, get medical attention. Instructions for Skin Contact Remove contaminated clothing and shoes. Immediately flush skin with large amounts of water. Get medical attention. Wash contaminated clothing and clean shoes before reuse. Instructions for Inhalation If signs/symptoms develop, remove person to fresh air. If signs/symptoms persist, get medical attention. ------------------------------------------------------------------------ SECTION 6: FIRE FIGHTING MEASURES ------------------------------------------------------------------------ Suitable Extinguishing Media Use fire extinguishers with class B extinguishing agents (e.g., dry chemical, carbon dioxide). Fire Fighting Procedures Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatus (SCBA). Special Instructions for Fire Fighting Not applicable. Exposure Hazards during Fire Non-flammable: ordinary combustible material. ------------------------------------------------------------------------ SECTION 7: ACCIDENTAL RELEASE MEASURE ------------------------------------------------------------------------ Spill Response For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water. Evacuate unprotected and untrained personnel from hazard area. The spill should be cleaned up by qualified personnel. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn or explode. Contain spill. Collect as much of the spilled material as possible. Clean up residue with an appropriate organic solvent. Read and follow safety precautions on the solvent label and MSDS. Collect the resulting residue containing solution. Place in a closed container approved for transportation by appropriate authorities. Dispose of collected material as soon as possible. Methods for Disposal Not applicable. ------------------------------------------------------------------------ SECTION 8: HANDLING AND STORAGE ------------------------------------------------------------------------ Incompatible Materials Store away from acids. Store away from oxidizing agents. Use Instructions Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Avoid eye contact with vapors, mists, or spray. Avoid breathing of dust created by cutting, sanding, grinding or machining. Avoid contact with oxidizing agents. ------------------------------------------------------------------------ SECTION 9: EXP0SURE CONTROL AND PERSONAL PROTECTION ------------------------------------------------------------------------ m-Xylene-alpha,alpha-diamine (1477-55-0) Exposure Limits 0.1 mg/m3 ACGIH: CEIL; skin contact contributes to exposure; Removed A4 Designat ion LAM 5/13/2003 BIS(1,2,2,6,6-PENTAMETHYL-4-PIPERIDINYL) SEBACATE (41556-26-7) Exposure Limits 1 mg/m3 CMRG: TWA; Comments: DEVELOPMENT ASSOCIATES MSDS DATED 10/18/2000 FOR 11-0018-9391-3. Substituted Piperydinyl Sebacate (82919-37-7) Exposure Limits 1 mg/m3 CMRG: TWA; Comments: DEVELOPMENT ASSOCIATES MSDS DATED 10/18/2000 FOR 11-0018-9391-3. Recommended Ventilation Provide appropriate local exhaust for cutting, grinding, sanding or machining. Eye Protection Avoid eye contact with vapors, mists, or spray. Hand Protection The following glove material(s) are recommended: butyl rubber Skin Protection Avoid skin contact. Respiratory Protection Under normal use conditions, airborne exposures are not expected to be significant enough to require respiratory protection. Avoid breathing of dust created by cutting, sanding, grinding or machining. Consult the current 3M Respirator Selection Guide for additional information or call 1-800-243-4630 for 3M technical assistance. During application and curing: Select one of the following NIOSH approved respirators based on airborne concentration of contaminants and in accordance with OSHA regulations: Half facepiece or fullface air-purifying respirator with organic vapor cartridges. Cutting, Grinding or Sanding Cured Material: Select one of the following NIOSH approved respirators based on airborne concentration of contaminants and in accordance with OSHA regulations: air-purifying respirator with N95 filter. Ingestion Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. ------------------------------------------------------------------------ SECTION 10: STABILITY AND REACTIVITY ------------------------------------------------------------------------ Materials to Avoid Strong Acids Strong Oxidizing Agents Hazardous Decomposition Carbon monoxide During Combustion Carbon dioxide During Combustion Hydrogen Chloride During Combustion Oxides of Nitrogen During Combustion Stability and Reactivity Hazardous polymerization will not occur. Stable ------------------------------------------------------------------------ SECTION 11: TOXICOLOGICAL INFORMATION ------------------------------------------------------------------------ Effects from Eye Contact Moderate Eye Irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision. Vapors released during curing may cause eye irritation. Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision. Dust created by cutting, grinding, sanding, or machining may cause eye irritation. Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision. Effects from Skin Contact Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, and itching. Prolonged or repeated exposure may cause: Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering and itching. Effects from Inhalation Vapors released during curing may cause irritation of the respiratory system. Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Dust from cutting, grinding, sanding or machining may cause irritation of the respiratory system. Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Effects from Ingestion Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, nausea, diarrhea and vomiting. ------------------------------------------------------------------------ SECTION 12: ECOLOGICAL INFORMATION ------------------------------------------------------------------------ Environmental Data No data available. Ecotoxicity Data Not determined. Ecofate Data Not determined. Special statements for 2001/58/EC One or more components of this product have significant known or predicted environmental hazards, but a conservative assessment indicates a low environmental risk. Intended use and proper disposal are unlikely to cause the environmentally hazardous component(s) to enter the environment in quantities or by routes that could cause the adverse environmental impacts. ------------------------------------------------------------------------ SECTION 13: DISPOSAL INFORMATION ------------------------------------------------------------------------ Product as Sold Dispose of completely cured (or polymerized) wastes in a sanitary landfill. As a disposal alternative, incinerate uncured product in an industrial or commercial incinerator in the presence of a combustible material. Combustion products will include HCl. Facility must be capable of handling halogenated materials. ------------------------------------------------------------------------ SECTION 14: TRANSPORT INFORMATION ------------------------------------------------------------------------ UN Number IMO Class ICAO Class Special Instructions ** NOT HAZARDOUS FOR TRANSPORT FOR DOT, IMO OR IATA. ------------------------------------------------------------------------ SECTION 15: REGULATORY INFORMATION ------------------------------------------------------------------------ Symbols None Risk Phrases None Safety Phrases None Special Regulatory Information Contact 3M for more information. ------------------------------------------------------------------------ SECTION 16: OTHER INFORMATION ------------------------------------------------------------------------ Reason for Reissue New health hazard information. The information on this data sheet represents our current data and best opinion as to the proper use in handling of this product under normal conditions. Any use of the product which is not in conformance with this data sheet or which involves using the product in combination with any other product or any other process is the responsibility of the user.