3M MALAYSIA SDN BHD ======================================================================== CHEMICAL SAFETY DATA SHEET ======================================================================== Document id : 18-9027-6 Issue date : 03/01/2007 Version : 1.00 Supersedes date : --- Document status : Issued This CSDS has been prepared by Toxicology Department 3M Malaysia Sdn. Bhd. ------------------------------------------------------------------------ SECTION 1: CHEMICAL PRODUCT AND COMPANY IDENTIFICATION ------------------------------------------------------------------------ Tradename 3M(TM) ESPE(TM) ADPER(TM) SINGLE BOND 2 3M Product ID: 70-2010-3677-2, 70-2010-3787-9, 70-2010-5196-1 Intended Use of Product Limitations on Use of Product For use only by dental professionals. COMPANY IDENTIFICATION ---------------------- Manufacturer's name and address 3M 3M Center St. Paul, Minnesota 55144-1000 USA Importer's name and address 3M Malaysia Sdn. Bhd. Bangunan 3M No. 6, Persiaran Tropicana 47410 Petaling Jaya Selangor Telephone number 03-7806-2888 Emergency telephone number 1-651-7376501 ( 24 hours ) CONTACT POINT ------------- Designation Toxicology Coordinator Telephone number 03-7806-2888 ------------------------------------------------------------------------ SECTION 2: COMPOSITION/INFORMATION ON INGREDIENT ------------------------------------------------------------------------ Ingredient name CAS number Percentage ------------------------------------- ------------------ ------------- ETHYL ALCOHOL 64-17-5 25 - 35 BISPHENOL A DIGLYCIDYL ETHER 1565-94-2 10 - 20 DIMETHACRYLATE SILANE TREATED SILICA (NANOFILLER) Unknown 10 - 20 2-HYDROXYETHYL METHACRYLATE 868-77-9 5 - 15 GLYCEROL 1,3-DIMETHACRYLATE 1830-78-0 5 - 10 COPOLYMER OF ACRYLIC AND ITACONIC 25948-33-8 5 - 10 ACIDS DIURETHANE DIMETHACRYLATE 72869-86-4 1 - 5 WATER 7732-18-5 < 5 ------------------------------------------------------------------------ SECTION 3: PHYSICAL AND CHEMICAL PROPERTIES ------------------------------------------------------------------------ Physical form,Color,Odor DETAILS: Liquid. Liquid Slight acrylate odor, white to clear in color. Water Solubility <<< Boiling point/boiling range = 78 C Melting point/melting range N/A Vapour pressure NOT DETERMINED Percent Volatile No data available. Evaporation rate No data available. Vapour density NOT DETERMINED Specific gravity = 1.075 Flash point = 18.5 C CC Autoflammability = 410 C Flammable Limits - LEL NOT DETERMINED Flammable Limits - UEL NOT DETERMINED Viscosity No data available. ------------------------------------------------------------------------ SECTION 4: HAZARD IDENTIFICATION ------------------------------------------------------------------------ Risk Phrases None ------------------------------------------------------------------------ SECTION 5: FIRST AID MEASURES ------------------------------------------------------------------------ Instructions for Ingestion Do not induce vomiting. Get immediate medical attention. Give victim two glasses of water. Never give anything by mouth to an unconscious person. Instructions for Eye Contact Flush eyes with large amounts of water. If signs/symptoms persist, get medical attention. Instructions for Skin Contact Remove contaminated clothing and shoes. Immediately flush skin with large amounts of water. Get medical attention. Wash contaminated clothing and clean shoes before reuse. Instructions for Inhalation Remove person to fresh air. If signs/symptoms develop, get medical attention. ------------------------------------------------------------------------ SECTION 6: FIRE FIGHTING MEASURES ------------------------------------------------------------------------ Suitable Extinguishing Media Use fire extinguishers with class B extinguishing agents (e.g., dry chemical, carbon dioxide). Fire Fighting Procedures Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and prevent explosive rupture. Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatus (SCBA). Exposure Hazards during Fire Closed containers exposed to heat from fire may build pressure and explode. Vapors may travel long distances along the ground or floor to an ignition source and flash back. ------------------------------------------------------------------------ SECTION 7: ACCIDENTAL RELEASE MEASURE ------------------------------------------------------------------------ Spill Response Seal the container. Ventilate the area with fresh air. Contain spill. Cover with absorbent material. Collect as much of the spilled material as possible. Clean up residue. Collect the resulting residue containing solution. Dispose of collected material as soon as possible. Methods for Disposal Not applicable. ------------------------------------------------------------------------ SECTION 8: HANDLING AND STORAGE ------------------------------------------------------------------------ Incompatible Materials Store away from heat. Store out of direct sunlight. Explosion Prevention Flammable liquid and vapor. Keep away from heat, sparks, open flame, pilot lights and other sources of ignition. Use Instructions Keep container tightly closed. ------------------------------------------------------------------------ SECTION 9: EXP0SURE CONTROL AND PERSONAL PROTECTION ------------------------------------------------------------------------ ETHYL ALCOHOL (64-17-5) Exposure Limits 1880 mg/m3 ACGIH: TWA; Table A4. 1000 ppm ACGIH: TWA; Table A4. Recommended Ventilation Not applicable. Eye Protection Avoid eye contact. Avoid eye contact. The following should be worn alone or in combination, as appropriate, to prevent eye contact: Safety glasses with side shields Hand Protection A no-touch technique is recommended. If skin contact occurs, wash skin with soap and water. Acrylates may penetrate commonly-used gloves. If product contacts glove, remove and discard glove, wash hands immediately with soap and water and then re-glove. Skin Protection Avoid skin contact. Avoid skin contact. Respiratory Protection Under normal use conditions, airborne exposures are not expected to be significant enough to require respiratory protection. Ingestion Do not ingest. ------------------------------------------------------------------------ SECTION 10: STABILITY AND REACTIVITY ------------------------------------------------------------------------ Materials to Avoid Heat Sparks and/or Flames Hazardous Decomposition Carbon monoxide During Combustion Carbon dioxide During Combustion Stability and Reactivity Hazardous polymerization will not occur. Stable ------------------------------------------------------------------------ SECTION 11: TOXICOLOGICAL INFORMATION ------------------------------------------------------------------------ Effects from Eye Contact Moderate Eye Irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision. Effects from Skin Contact Moderate Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness. Prolonged or repeated exposure may cause: Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering and itching. Effects from Inhalation May be absorbed following inhalation and cause target organ effects. Upper Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Effects from Ingestion May be absorbed following ingestion and cause target organ effects. Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, nausea, diarrhea and vomiting. Carcinogenicity Note: This product contains ethanol. In IARC published Monograph No. 44, entitled, 'Alcohol Drinking', the carcinogenicity of ethanol was determined based on chronic exposure to ethanol through human consumption of alcoholic beverages. This is not an expected effect during the foreseeable use of this product. Other Toxicological Information Prolonged or repeated exposure, above recommended guidelines, may cause: Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness. ------------------------------------------------------------------------ SECTION 12: ECOLOGICAL INFORMATION ------------------------------------------------------------------------ Environmental Data No data available. Ecotoxicity Data Not determined. Ecofate Data Not determined. Special statements for 2001/58/EC A conservative assessment indicates this product presents a low environmental risk because use and disposal are unlikely to result in the significant release of components to the environment. ------------------------------------------------------------------------ SECTION 13: DISPOSAL INFORMATION ------------------------------------------------------------------------ Product as Sold Incinerate in a permitted hazardous waste incinerator. As a disposal alternative, dispose of waste product in a permitted hazardous waste facility. ------------------------------------------------------------------------ SECTION 14: TRANSPORT INFORMATION ------------------------------------------------------------------------ UN Number UN 1133. IMO Class FORBIDDEN 3M DIVISION POLICY. ICAO Class DANGEROUS GOODS IN EXCEPTED QUANTITIES OF CLASS 3. ------------------------------------------------------------------------ SECTION 15: REGULATORY INFORMATION ------------------------------------------------------------------------ Symbols None Risk Phrases None Safety Phrases None Special Regulatory Information Contact 3M for more information. ------------------------------------------------------------------------ SECTION 16: OTHER INFORMATION ------------------------------------------------------------------------ Reason for Reissue New or changed physical property data. Change in MSDS ingredient disclosure. Change in product name. The information on this data sheet represents our current data and best opinion as to the proper use in handling of this product under normal conditions. Any use of the product which is not in conformance with this data sheet or which involves using the product in combination with any other product or any other process is the responsibility of the user.