3M MALAYSIA SDN BHD ======================================================================== CHEMICAL SAFETY DATA SHEET ======================================================================== Document id : 19-0174-3 Issue date : 03/05/2007 Version : 1.00 Supersedes date : --- Document status : Issued This CSDS has been prepared by Toxicology Department 3M Malaysia Sdn. Bhd. ------------------------------------------------------------------------ SECTION 1: CHEMICAL PRODUCT AND COMPANY IDENTIFICATION ------------------------------------------------------------------------ Tradename 1923 3M(TM) ESPE(TM) SCOTCHBOND(TM) ETCHING LIQUID 3M Product ID: 70-2010-1427-4 Intended Use of Product Limitations on Use of Product For use only by dental professionals. COMPANY IDENTIFICATION ---------------------- Manufacturer's name and address 3M 3M Center St. Paul, Minnesota 55144-1000 USA Importer's name and address 3M Malaysia Sdn. Bhd. Bangunan 3M No. 6, Persiaran Tropicana 47410 Petaling Jaya Selangor Telephone number 03-7806-2888 Emergency telephone number 1-651-7376501 ( 24 hours ) CONTACT POINT ------------- Designation Toxicology Coordinator Telephone number 03-7806-2888 ------------------------------------------------------------------------ SECTION 2: COMPOSITION/INFORMATION ON INGREDIENT ------------------------------------------------------------------------ Ingredient name CAS number Percentage ------------------------------------- ------------------ ------------- WATER 7732-18-5 60 - 70 PHOSPHORIC ACID 7664-38-2 30 - 40 ------------------------------------------------------------------------ SECTION 3: PHYSICAL AND CHEMICAL PROPERTIES ------------------------------------------------------------------------ Physical form,Color,Odor DETAILS: Liquid. Liquid Clear, odorless. Water Solubility N/A COMPLETE Boiling point/boiling range 35 C Melting point/melting range N/A Vapour pressure <= 16 psi Percent Volatile NOT DETERMINED Evaporation rate NOT DETERMINED Vapour density NOT DETERMINED Specific gravity = 1 Flash point N/A Autoflammability N/A Flammable Limits - LEL N/A Flammable Limits - UEL N/A Viscosity = 10 centipoise ------------------------------------------------------------------------ SECTION 4: HAZARD IDENTIFICATION ------------------------------------------------------------------------ Risk Phrases None ------------------------------------------------------------------------ SECTION 5: FIRST AID MEASURES ------------------------------------------------------------------------ Instructions for Ingestion Do not induce vomiting. Get immediate medical attention. Give victim two glasses of water. Never give anything by mouth to an unconscious person. Instructions for Eye Contact Get immediate medical attention. Immediately flush eyes with large amounts of water for at least 15 minutes. Instructions for Skin Contact Immediately flush skin with large amounts of water for at least 15 minutes. Get immediate medical attention. Remove contaminated clothing and shoes. Wash contaminated clothing and clean shoes before reuse. Instructions for Inhalation Remove person to fresh air. If signs/symptoms develop, get medical attention. ------------------------------------------------------------------------ SECTION 6: FIRE FIGHTING MEASURES ------------------------------------------------------------------------ Suitable Extinguishing Media Fire Fighting Procedures Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatus (SCBA). Special Instructions for Fire Fighting Contact with aluminum or zinc in a pressurized system may generate hydrogen gas which could create an explosion hazard. Exposure Hazards during Fire Material will not burn. ------------------------------------------------------------------------ SECTION 7: ACCIDENTAL RELEASE MEASURE ------------------------------------------------------------------------ Spill Response Place in a metal container approved for use in transportation by appropriate authorities. The container must be lined with polyethylene plastic or contain a plastic drum liner made of polyethylene. Ventilate the area with fresh air. Contain spill. Collect as much of the spilled material as possible. Clean up residue. Cover, but do not seal for 48 hours. Dispose of collected material as soon as possible. Methods for Disposal Not applicable. ------------------------------------------------------------------------ SECTION 8: HANDLING AND STORAGE ------------------------------------------------------------------------ ------------------------------------------------------------------------ SECTION 9: EXP0SURE CONTROL AND PERSONAL PROTECTION ------------------------------------------------------------------------ PHOSPHORIC ACID (7664-38-2) Exposure Limits 3 mg/m3 1 mg/m3 ACGIH: STEL ACGIH: TWA Recommended Ventilation Not applicable. Eye Protection Avoid eye contact. The following should be worn alone or in combination, as appropriate, to prevent eye contact: Safety glasses with side shields Hand Protection Not applicable. Skin Protection Avoid skin contact. Respiratory Protection Under normal use conditions, airborne exposures are not expected to be significant enough to require respiratory protection. Ingestion Do not ingest. ------------------------------------------------------------------------ SECTION 10: STABILITY AND REACTIVITY ------------------------------------------------------------------------ Materials to Avoid Strong Bases Hazardous Decomposition None known. Stability and Reactivity Hazardous polymerization will not occur. Stable ------------------------------------------------------------------------ SECTION 11: TOXICOLOGICAL INFORMATION ------------------------------------------------------------------------ Effects from Eye Contact Corrosive (Eye Burns): Signs/symptoms may include cloudy appearance of the cornea, chemical burns, severe pain, tearing, ulcerations, significantly impaired vision or complete loss of vision. Effects from Skin Contact Corrosive (Skin Burns): Signs/symptoms may include localized redness, swelling, itching, intense pain, blistering, ulceration, and tissue destruction. Effects from Inhalation Upper Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Prolonged or repeated exposure, above recommended guidelines, may cause: Pulmonary Edema: Signs/symptoms may include chest discomfort, shortness of breath, significant cough with frothy sputum production, bluish colored skin (cyanosis), increased heart rate and possible respiratory failure, and may be fatal. Effects from Ingestion Gastrointestinal Corrosion: Signs/symptoms may include severe mouth, throat and abdominal pain; nausea; vomiting; and diarrhea; blood in the feces and/or vomitus may also be seen. ------------------------------------------------------------------------ SECTION 12: ECOLOGICAL INFORMATION ------------------------------------------------------------------------ Environmental Data No data available. Ecotoxicity Data Not determined. Ecofate Data Not determined. ------------------------------------------------------------------------ SECTION 13: DISPOSAL INFORMATION ------------------------------------------------------------------------ Product as Sold Incinerate in a permitted hazardous waste incinerator. As a disposal alternative, dispose of waste product in a permitted hazardous waste facility. ------------------------------------------------------------------------ SECTION 14: TRANSPORT INFORMATION ------------------------------------------------------------------------ UN Number UN 1805. IMO Class FORBIDDEN 3M DIVISION POLICY. ICAO Class DANGEROUS GOODS IN EXCEPTED QUANTITIES OF CLASS 8. ------------------------------------------------------------------------ SECTION 15: REGULATORY INFORMATION ------------------------------------------------------------------------ Symbols None Risk Phrases None Safety Phrases None Special Regulatory Information Contact 3M for more information. ------------------------------------------------------------------------ SECTION 16: OTHER INFORMATION ------------------------------------------------------------------------ Reason for Reissue The MSDS has been revised because 3M has adopted the 16-section ANSI/ISO format. The potential hazards of the product have not changed. We encourage you to reread the MSDS and review the information. Change in product name. The information on this data sheet represents our current data and best opinion as to the proper use in handling of this product under normal conditions. Any use of the product which is not in conformance with this data sheet or which involves using the product in combination with any other product or any other process is the responsibility of the user.