3M MALAYSIA SDN BHD ============================================================================ KIT Chemical Safety Data Sheet ============================================================================ Document id : 16-2762-9 Issue date : 25/04/2007 Version : 1.00 Supersedes date : --- Document status : Issued This CSDS has been prepared by Toxicology Department 3M Malaysia Sdn. Bhd. ---------------------------------------------------------------------------- 1 SECTION 1: CHEMICAL PRODUCT AND COMPANY IDENTIFICATION ---------------------------------------------------------------------------- NOTE ** NOT HAZARDOUS FOR TRANSPORT FOR DOT, IMO OR IATA. Tradename PROTEMP II TEMPORARY 3M Product ID: 70-2011-0056-0 - 46001 PROTEMP II TEMP MTL INTRO KIT A1 EXTRA LIGHT A3 LIGHT, 70-2011-0057-8 - 46011 PROTEMP II TEMP MTL INTRO KIT A3 LIGHT/B3 YELLOW, 70-2011-0058-6 - 46121 PROTEMP II TEMP MTL GIANT PACK A1 EXTRA LIGHT (5 DOUBLE PACKS), 70-2011-0059-4 - 46131 PROTEMP II TEMP MTL GIANT PACK A3 LIGHT (5 DOUBLE PACKS), 70-2011-0060-2 - 46141 PROTEMP II TEMP MTL GIANT PACK B3 YELLO (5 DOUBLE PACKS), 70-2011-0061-0 - 46091 PROTEMP II TEMP MTL DOUBLE PACK A1 EXTRA LIGHT, 70-2011-0062-8 - 46101 PROTEMP II TEMP MTL DOUBLE PACK A3 LIGHT, 70-2011-0063-6 - 46111 PROTEMP II TEMP MTL DOUBLE PACK B3 YELLOW, 70-2011-1044-5 - 46090 PROTEMP II TEMP MTL DOUBLE PACK A1 EXTRA LIGHT, 70-2011-1323-3 - 46100 PROTEMP II TEMP MTL DOUBLE PACK A3 LIGHT, 70-2011-1324-1 - 46110 PROTEMP II TEMP MTL DOUBLE PACK B3 YELLOW KIT COMPONENTS The information on this data sheet represents our current data and best opinion as to the proper use in handling of this product under normal conditions. Any use of the product which is not in conformance with this data sheet or which involves using the product in combination with any other product or any other process is the responsibility of the user. 3M MALAYSIA SDN BHD ======================================================================== CHEMICAL SAFETY DATA SHEET ======================================================================== Document id : 16-2626-6 Issue date : 25/04/2007 Version : 1.00 Supersedes date : --- Document status : Issued This CSDS has been prepared by Toxicology Department 3M Malaysia Sdn. Bhd. ------------------------------------------------------------------------ SECTION 1: CHEMICAL PRODUCT AND COMPANY IDENTIFICATION ------------------------------------------------------------------------ Tradename PROTEMP II CATALYST 3M Product ID: 70-2011-0064-4, 70-2011-0358-0 Intended Use of Product Limitations on Use of Product For use only by dental professionals. COMPANY IDENTIFICATION ---------------------- Manufacturer's name and address 3M 3M Center St. Paul, Minnesota 55144-1000 USA Importer's name and address 3M Malaysia Sdn. Bhd. Bangunan 3M No. 6, Persiaran Tropicana 47410 Petaling Jaya Selangor Telephone number 03-7806-2888 Emergency telephone number 1-651-7376501 ( 24 hours ) CONTACT POINT ------------- Designation Toxicology Coordinator Telephone number 03-7806-2888 ------------------------------------------------------------------------ SECTION 2: COMPOSITION/INFORMATION ON INGREDIENT ------------------------------------------------------------------------ Ingredient name CAS number Percentage ------------------------------------- ------------------ ------------- DIACETATE Trade Secret 60 - 80 LAUROYL PEROXIDE 105-74-8 20 - 30 SUBSTITUTED SULFONAMIDE Trade Secret 20 - 30 AMORPHOUS SILICA 7631-86-9 1 - 10 ------------------------------------------------------------------------ SECTION 3: PHYSICAL AND CHEMICAL PROPERTIES ------------------------------------------------------------------------ Physical form,Color,Odor Solid Paste White & colorless paste, sweet plasticizer odor. Water Solubility NIL Boiling point/boiling range N/A Melting point/melting range NOT DETERMINED Vapour pressure N/A Percent Volatile N/A Evaporation rate N/A Vapour density N/A Specific gravity >= 1 Water=1 Flash point N/A Autoflammability NOT DETERMINED Flammable Limits - LEL N/A Flammable Limits - UEL N/A Viscosity 30000 - 150000 centipoise ------------------------------------------------------------------------ SECTION 4: HAZARD IDENTIFICATION ------------------------------------------------------------------------ Risk Phrases None ------------------------------------------------------------------------ SECTION 5: FIRST AID MEASURES ------------------------------------------------------------------------ Instructions for Ingestion Do not induce vomiting. Get immediate medical attention. Give victim two glasses of water. Never give anything by mouth to an unconscious person. Instructions for Eye Contact Flush eyes with large amounts of water. If signs/symptoms persist, get medical attention. Instructions for Skin Contact Immediately flush skin with large amounts of water. If signs/symptoms develop, get medical attention. Instructions for Inhalation No need for first aid is anticipated. ------------------------------------------------------------------------ SECTION 6: FIRE FIGHTING MEASURES ------------------------------------------------------------------------ Suitable Extinguishing Media Use fire extinguishers with class B extinguishing agents (e.g., dry chemical, carbon dioxide). Fire Fighting Procedures Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatus (SCBA). Special Instructions for Fire Fighting Not applicable. ------------------------------------------------------------------------ SECTION 7: ACCIDENTAL RELEASE MEASURE ------------------------------------------------------------------------ Spill Response Ventilate the area with fresh air. Contain spill. Collect as much of the spilled material as possible. Flush area thoroughly with water as necessary to dilute or clean up residue. Clean up residue with an appropriate organic solvent. Read and follow safety precautions on the solvent label and MSDS. Place in a closed container approved for transportation by appropriate authorities. Methods for Disposal Not applicable. ------------------------------------------------------------------------ SECTION 8: HANDLING AND STORAGE ------------------------------------------------------------------------ Incompatible Materials Store away from heat. Store out of direct sunlight. ------------------------------------------------------------------------ SECTION 9: EXP0SURE CONTROL AND PERSONAL PROTECTION ------------------------------------------------------------------------ AMORPHOUS SILICA (7631-86-9) Exposure Limits 3 mg/m3 CMRG: TWA - specific form; as respirable dust; DUPONT MSDS DATED 11/16 /99 FOR 11-0001-3049-9. Recommended Ventilation Not applicable. Eye Protection Avoid eye contact. The following should be worn alone or in combination, as appropriate, to prevent eye contact: Safety glasses with side shields Hand Protection Not applicable. Skin Protection Avoid prolonged or repeated skin contact. Gloves not normally required. Respiratory Protection Under normal use conditions, airborne exposures are not expected to be significant enough to require respiratory protection. Ingestion Do not ingest. ------------------------------------------------------------------------ SECTION 10: STABILITY AND REACTIVITY ------------------------------------------------------------------------ Materials to Avoid Heat Hazardous Decomposition Carbon monoxide During Combustion Carbon dioxide During Combustion Irritant Vapors or Gases During Combustion Stability and Reactivity Hazardous polymerization will not occur. Stable ------------------------------------------------------------------------ SECTION 11: TOXICOLOGICAL INFORMATION ------------------------------------------------------------------------ Effects from Eye Contact Single exposure may cause: Moderate Eye Irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision. Effects from Skin Contact Single exposure may cause: Moderate Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness. Effects from Inhalation No health effects are expected. Effects from Ingestion Ingestion may cause: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, nausea, diarrhea and vomiting. ------------------------------------------------------------------------ SECTION 12: ECOLOGICAL INFORMATION ------------------------------------------------------------------------ Environmental Data No data available. Ecotoxicity Data Not determined. Ecofate Data Not determined. Other Ecotoxicity Information A conservative, screening level assessment of this product indicates that its use and proper disposal are likely to present a low environmental risk. Potential use and misuse are unlikely to cause components to enter the environment in quantities or by routes that could cause adverse environmental impacts. ------------------------------------------------------------------------ SECTION 13: DISPOSAL INFORMATION ------------------------------------------------------------------------ Product as Sold Cure (harden, set, or react) the product according to product instructions. Dispose of completely cured (or polymerized) wastes in a sanitary landfill. As a disposal alternative, incinerate uncured product in an industrial or commercial incinerator in the presence of a combustible material. ------------------------------------------------------------------------ SECTION 14: TRANSPORT INFORMATION ------------------------------------------------------------------------ UN Number IMO Class ICAO Class Special Instructions ** NOT HAZARDOUS FOR TRANSPORT FOR DOT, IMO OR IATA. ------------------------------------------------------------------------ SECTION 15: REGULATORY INFORMATION ------------------------------------------------------------------------ Symbols None Risk Phrases None Safety Phrases None Special Regulatory Information Contact 3M for more information. ------------------------------------------------------------------------ SECTION 16: OTHER INFORMATION ------------------------------------------------------------------------ Reason for Reissue Change in MSDS ingredient disclosure. The information on this data sheet represents our current data and best opinion as to the proper use in handling of this product under normal conditions. Any use of the product which is not in conformance with this data sheet or which involves using the product in combination with any other product or any other process is the responsibility of the user. 3M MALAYSIA SDN BHD ======================================================================== CHEMICAL SAFETY DATA SHEET ======================================================================== Document id : 16-2761-1 Issue date : 25/04/2007 Version : 1.00 Supersedes date : --- Document status : Issued This CSDS has been prepared by Toxicology Department 3M Malaysia Sdn. Bhd. ------------------------------------------------------------------------ SECTION 1: CHEMICAL PRODUCT AND COMPANY IDENTIFICATION ------------------------------------------------------------------------ Tradename PROTEMP II BASE 3M Product ID: BA-ESPE-4600-1 Intended Use of Product Limitations on Use of Product For use only by dental professionals. COMPANY IDENTIFICATION ---------------------- Manufacturer's name and address 3M 3M Center St. Paul, Minnesota 55144-1000 USA Importer's name and address 3M Malaysia Sdn. Bhd. Bangunan 3M No. 6, Persiaran Tropicana 47410 Petaling Jaya Selangor Telephone number 03-7806-2888 Emergency telephone number 1-651-7376501 ( 24 hours ) CONTACT POINT ------------- Designation Toxicology Coordinator Telephone number 03-7806-2888 ------------------------------------------------------------------------ SECTION 2: COMPOSITION/INFORMATION ON INGREDIENT ------------------------------------------------------------------------ Ingredient name CAS number Percentage ------------------------------------- ------------------ ------------- BISPHENOL A POLYETHYLENE GLYCOL Trade Secret 50 - 70 DIETHER DIMETHACRYLATE GLASS POWDER 65997-17-3 20 - 30 SILANE TREATED SILICA 68909-20-6 10 - 20 VINYL ETHER COPOLYMER Trade Secret 1 - 5 VINYL ACETATE DIBUTYL MALEATE POLYMER Trade Secret 1 - 5 ------------------------------------------------------------------------ SECTION 3: PHYSICAL AND CHEMICAL PROPERTIES ------------------------------------------------------------------------ Physical form,Color,Odor Solid Paste Different colored pastes, slight acrylate odor. Water Solubility NIL Boiling point/boiling range N/A Melting point/melting range NOT DETERMINED Vapour pressure N/A Percent Volatile N/A Evaporation rate N/A Vapour density N/A Specific gravity CA. 1 Flash point N/A Autoflammability NOT DETERMINED Flammable Limits - LEL N/A Flammable Limits - UEL N/A Viscosity 30000 - 150000 centipoise ------------------------------------------------------------------------ SECTION 4: HAZARD IDENTIFICATION ------------------------------------------------------------------------ Risk Phrases None ------------------------------------------------------------------------ SECTION 5: FIRST AID MEASURES ------------------------------------------------------------------------ Instructions for Ingestion Do not induce vomiting. Get immediate medical attention. Give victim two glasses of water. Never give anything by mouth to an unconscious person. Instructions for Eye Contact Flush eyes with large amounts of water. If signs/symptoms persist, get medical attention. Instructions for Skin Contact Wash affected area with soap and water. If signs/symptoms develop, get medical attention. Instructions for Inhalation No need for first aid is anticipated. ------------------------------------------------------------------------ SECTION 6: FIRE FIGHTING MEASURES ------------------------------------------------------------------------ Suitable Extinguishing Media Use fire extinguishers with class B extinguishing agents (e.g., dry chemical, carbon dioxide). Fire Fighting Procedures Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatus (SCBA). Special Instructions for Fire Fighting Not applicable. ------------------------------------------------------------------------ SECTION 7: ACCIDENTAL RELEASE MEASURE ------------------------------------------------------------------------ Spill Response Ventilate the area with fresh air. Contain spill. Collect as much of the spilled material as possible. Clean up residue with an appropriate organic solvent. Read and follow safety precautions on the solvent label and MSDS. Place in a closed container approved for transportation by appropriate authorities. Methods for Disposal Not applicable. ------------------------------------------------------------------------ SECTION 8: HANDLING AND STORAGE ------------------------------------------------------------------------ Incompatible Materials Store away from heat. Store out of direct sunlight. ------------------------------------------------------------------------ SECTION 9: EXP0SURE CONTROL AND PERSONAL PROTECTION ------------------------------------------------------------------------ GLASS POWDER (65997-17-3) Exposure Limits 10 mg/m3 3M: TWA; as dust; Comments: nuisance particulate. Recommended Ventilation Not applicable. Eye Protection Avoid eye contact. The following should be worn alone or in combination, as appropriate, to prevent eye contact: Safety glasses with side shields Hand Protection A no-touch technique is recommended. If skin contact occurs, wash skin with soap and water. Acrylates may penetrate commonly-used gloves. If product contacts glove, remove and discard glove, wash hands immediately with soap and water and then re-glove. Skin Protection Avoid prolonged or repeated skin contact. Respiratory Protection Under normal use conditions, airborne exposures are not expected to be significant enough to require respiratory protection. Ingestion Do not ingest. Special Information, Exposure/Protection For skin protection information, see section 7.1. ------------------------------------------------------------------------ SECTION 10: STABILITY AND REACTIVITY ------------------------------------------------------------------------ Materials to Avoid Heat Hazardous Decomposition Carbon monoxide During Combustion Carbon dioxide During Combustion Irritant Vapors or Gases During Combustion Stability and Reactivity Hazardous polymerization will not occur. Stable ------------------------------------------------------------------------ SECTION 11: TOXICOLOGICAL INFORMATION ------------------------------------------------------------------------ Effects from Eye Contact Single exposure may cause: Moderate Eye Irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision. Effects from Skin Contact Prolonged or repeated exposure may cause: Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, and itching. Effects from Inhalation No health effects are expected. Effects from Ingestion Ingestion may cause: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, nausea, diarrhea and vomiting. ------------------------------------------------------------------------ SECTION 12: ECOLOGICAL INFORMATION ------------------------------------------------------------------------ Environmental Data No data available. Ecotoxicity Data Not determined. Ecofate Data Not determined. Other Ecotoxicity Information A conservative, screening level assessment of this product indicates that its use and proper disposal are likely to present a low environmental risk. Potential use and misuse are unlikely to cause components to enter the environment in quantities or by routes that could cause adverse environmental impacts. ------------------------------------------------------------------------ SECTION 13: DISPOSAL INFORMATION ------------------------------------------------------------------------ Product as Sold Cure (harden, set, or react) the product according to product instructions. Dispose of completely cured (or polymerized) wastes in a sanitary landfill. As a disposal alternative, incinerate uncured product in an industrial or commercial incinerator. ------------------------------------------------------------------------ SECTION 14: TRANSPORT INFORMATION ------------------------------------------------------------------------ UN Number IMO Class ICAO Class Special Instructions ** NON RESTRICTED ITEM. ------------------------------------------------------------------------ SECTION 15: REGULATORY INFORMATION ------------------------------------------------------------------------ Symbols None Risk Phrases None Safety Phrases None Special Regulatory Information Contact 3M for more information. ------------------------------------------------------------------------ SECTION 16: OTHER INFORMATION ------------------------------------------------------------------------ Reason for Reissue Change in MSDS ingredient disclosure. The information on this data sheet represents our current data and best opinion as to the proper use in handling of this product under normal conditions. Any use of the product which is not in conformance with this data sheet or which involves using the product in combination with any other product or any other process is the responsibility of the user.