3M MALAYSIA SDN BHD ======================================================================== CHEMICAL SAFETY DATA SHEET ======================================================================== Document id : 16-6314-5 Issue date : 01/03/2007 Version : 1.00 Supersedes date : --- Document status : Issued This CSDS has been prepared by Toxicology Department 3M Malaysia Sdn. Bhd. ------------------------------------------------------------------------ SECTION 1: CHEMICAL PRODUCT AND COMPANY IDENTIFICATION ------------------------------------------------------------------------ Tradename 3M SUPER 33+ AND SUPER 88 AND 37 AND 15 VINYL ELECTRICAL TAPE-NO LEAD 3M Product ID: 80-6108-3383-4, 80-6112-6706-5, 80-6112-6707-3, 80-6114-2435-1, 80-6114-3008-5, 80-6114-3009-3 Intended Use of Product Electrical COMPANY IDENTIFICATION ---------------------- Manufacturer's name and address 3M 3M Center St. Paul, Minnesota 55144-1000 USA Importer's name and address 3M Malaysia Sdn. Bhd. Bangunan 3M No. 6, Persiaran Tropicana 47410 Petaling Jaya Selangor Telephone number 03-7806-2888 Emergency telephone number 1-651-7376501 ( 24 hours ) CONTACT POINT ------------- Designation Toxicology Coordinator Telephone number 03-7806-2888 ------------------------------------------------------------------------ SECTION 2: COMPOSITION/INFORMATION ON INGREDIENT ------------------------------------------------------------------------ Ingredient name CAS number Percentage ------------------------------------- ------------------ ------------- POLY(VINYL CHLORIDE) 9002-86-2 40 - 50 Polyester resin Trade Secret 15 - 25 phenolic-cured rubber adhesive Trade Secret 10 - 20 Tackifying resin Trade Secret 5 - 10 SYNTHETIC RUBBER Trade Secret 1 - 5 RESIN Trade Secret 1 - 5 Epoxidized Vegetable Oil 8013-07-8 1 - 3 DI-C8-10-BRANCHED ALKYL PHTHALATE, 68515-48-0 2 - 3 C9 RICH ANTIMONY TRIOXIDE 1309-64-4 1 - 3 CARBON BLACK 1333-86-4 1 - 3 P-TERT-BUTYLPHENOL-FORMALDEHYDE RESIN 25085-50-1 < 2 Stabilizer Trade Secret 1 - 2 ------------------------------------------------------------------------ SECTION 3: PHYSICAL AND CHEMICAL PROPERTIES ------------------------------------------------------------------------ Physical form,Color,Odor Solid Roll of Tape Black adhesive tape, slight odor. Water Solubility NIL Boiling point/boiling range N/A Melting point/melting range NOT DETERMINED Vapour pressure N/A Percent Volatile N/A Evaporation rate N/A Vapour density N/A Specific gravity = 1.22 g/ml Flash point N/A Autoflammability NOT DETERMINED Flammable Limits - LEL NOT DETERMINED Flammable Limits - UEL NOT DETERMINED Viscosity N/A ------------------------------------------------------------------------ SECTION 4: HAZARD IDENTIFICATION ------------------------------------------------------------------------ Risk Phrases None ------------------------------------------------------------------------ SECTION 5: FIRST AID MEASURES ------------------------------------------------------------------------ Instructions for Ingestion Do not induce vomiting. Get immediate medical attention. Give victim two glasses of water. Never give anything by mouth to an unconscious person. Instructions for Eye Contact Flush eyes with large amounts of water. If signs/symptoms persist, get medical attention. Instructions for Skin Contact Wash affected area with soap and water. If signs/symptoms develop, get medical attention. Instructions for Inhalation Remove person to fresh air. If signs/symptoms develop, get medical attention. ------------------------------------------------------------------------ SECTION 6: FIRE FIGHTING MEASURES ------------------------------------------------------------------------ Suitable Extinguishing Media Use fire extinguishers with class B extinguishing agents (e.g., dry chemical, carbon dioxide). Fire Fighting Procedures Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatus (SCBA). Special Instructions for Fire Fighting Not applicable. Contact with aluminum or zinc in a pressurized system may generate hydrogen gas which could create an explosion hazard. Exposure Hazards during Fire No unusual fire or explosion hazards are anticipated. ------------------------------------------------------------------------ SECTION 7: ACCIDENTAL RELEASE MEASURE ------------------------------------------------------------------------ Spill Response Not applicable. Methods for Disposal Not applicable. ------------------------------------------------------------------------ SECTION 8: HANDLING AND STORAGE ------------------------------------------------------------------------ Incompatible Materials Keep away from aluminum and zinc. Store away from oxidizing agents. Use Instructions This product is considered to be an article which does not release or otherwise result in exposure to a hazardous chemical under normal use conditions. Avoid contact with oxidizing agents. ------------------------------------------------------------------------ SECTION 9: EXP0SURE CONTROL AND PERSONAL PROTECTION ------------------------------------------------------------------------ DI-C8-10-BRANCHED ALKYL PHTHALATE, C9 RICH (68515-48-0) Exposure Limits 5 mg/m3 CMRG: TWA; PER 11/22/90 VENDOR MSDS. ANTIMONY TRIOXIDE (1309-64-4) Exposure Limits 0.5 mg/m3 0.5 mg/m3 ACGIH: TWA - specific form; as Sb - Category: ANTIMONY COMPOUNDS ACGIH: TWA - specific form; as Sb; CARBON BLACK (1333-86-4) Exposure Limits 3.5 mg/m3 0.5 mg/m3 ACGIH: TWA; Table A4 CMRG: TWA; DUPONT MSDS DATED 1/6/99 FOR 11-0018-9474-7. Recommended Ventilation Use with appropriate local exhaust ventilation. Not applicable. Provide appropriate local exhaust for cutting, grinding, sanding or machining. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below Occupational Exposure Limits and/or control dust, fume, or airborne particles. If ventilation is not adequate, use respiratory protection equipment. Eye Protection Not applicable. Avoid eye contact with vapors, mists, or spray. Hand Protection Not applicable. Skin Protection Gloves not normally required. Avoid prolonged or repeated skin contact. Respiratory Protection Avoid breathing of fumes. Avoid breathing of dust created by cutting, sanding, grinding or machining. Ingestion Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Not applicable. Keep out of the reach of children. ------------------------------------------------------------------------ SECTION 10: STABILITY AND REACTIVITY ------------------------------------------------------------------------ Materials to Avoid Strong Oxidizing Agents None known. Finely divided active metals Alkali and alkaline earth metals Reactions with metals in powder form occur from 370 C onwards. Hazardous Decomposition Carbon monoxide During Combustion Carbon dioxide During Combustion Hydrogen Chloride During Combustion Irritant Vapors or Gases During Combustion Oxides of Antimony During Combustion Oxides of Zinc During Combustion Hydrocarbons At Elevated Temperatures Under recommended usage conditions, hazardous decomposition products are not expected. Hazardous decomposition products may occur as a result of oxidation, heating, or reaction with another material. Stability and Reactivity Hazardous polymerization will not occur. Stable ------------------------------------------------------------------------ SECTION 11: TOXICOLOGICAL INFORMATION ------------------------------------------------------------------------ Effects from Eye Contact No health effects are expected. Effects from Skin Contact No health effects are expected. Effects from Inhalation No health effects are expected. If thermal decomposition occurs: Upper Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Effects from Ingestion Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, nausea, diarrhea and vomiting. Carcinogenicity Contains a chemical or chemicals which can cause cancer. Other Toxicological Information This product, when used under reasonable conditions and in accordance with the 3M directions for use, should not present a health hazard. However, use or processing of the product in a manner not in accordance with the product's directions for use may affect the performance of the product and may present potential health and safety hazards. ------------------------------------------------------------------------ SECTION 12: ECOLOGICAL INFORMATION ------------------------------------------------------------------------ Environmental Data No data available. Ecotoxicity Data Not applicable. Ecofate Data Not applicable. Special statements for 2001/58/EC A conservative assessment indicates this product presents a low environmental risk because use and disposal are unlikely to result in the significant release of components to the environment. Other Ecotoxicity Information The environmental properties of this product present a low environmental hazard. ------------------------------------------------------------------------ SECTION 13: DISPOSAL INFORMATION ------------------------------------------------------------------------ Product as Sold Not applicable. Potential for Recycling Reclaim if feasible. If product can't be reclaimed, dispose of waste product in a sanitary landfill. Alternatively, incinerate the waste product in an industrial, commercial, or municipal incinerator. ------------------------------------------------------------------------ SECTION 14: TRANSPORT INFORMATION ------------------------------------------------------------------------ UN Number IMO Class ICAO Class Special Instructions ** NOT HAZARDOUS FOR TRANSPORT FOR DOT, IMO OR IATA. ------------------------------------------------------------------------ SECTION 15: REGULATORY INFORMATION ------------------------------------------------------------------------ Symbols None Risk Phrases None Safety Phrases None Special Regulatory Information Contact 3M for more information. ------------------------------------------------------------------------ SECTION 16: OTHER INFORMATION ------------------------------------------------------------------------ Reason for Reissue Change in product name. The information on this data sheet represents our current data and best opinion as to the proper use in handling of this product under normal conditions. Any use of the product which is not in conformance with this data sheet or which involves using the product in combination with any other product or any other process is the responsibility of the user.