3M MALAYSIA SDN BHD ======================================================================== CHEMICAL SAFETY DATA SHEET ======================================================================== Document id : 16-6046-3 Issue date : 29/06/2012 Version : 1.00 Supersedes date : --- Document status : Issued This CSDS has been prepared by Toxicology Department 3M Malaysia Sdn. Bhd. ------------------------------------------------------------------------ SECTION 1: CHEMICAL PRODUCT AND COMPANY IDENTIFICATION ------------------------------------------------------------------------ Tradename 3M(TM) Super Foam Fast Spray Adhesive 74, Clear 3M Product ID: 62-4950-4935-5, 62-4950-4936-3, 62-4950-4950-4, 62-4950-4955-3 Intended Use of Product aerosol foam adhesive COMPANY IDENTIFICATION ---------------------- Manufacturer's name and address 3M 3M Center St. Paul, Minnesota 55144-1000 USA Importer's name and address 3M Malaysia Sdn. Bhd. Bangunan 3M No. 6, Persiaran Tropicana 47410 Petaling Jaya Selangor Telephone number 03-7806-2888 Emergency telephone number 1-651-7376501 ( 24 hours ) CONTACT POINT ------------- Designation Toxicology Coordinator Telephone number 03-7806-2888 ------------------------------------------------------------------------ SECTION 2: COMPOSITION/INFORMATION ON INGREDIENT ------------------------------------------------------------------------ Ingredient name CAS number Percentage ------------------------------------- ------------------ ------------- N.J.T.S. Reg No. 04499600-6501P Trade Secret 15 - 25 DIMETHYL ETHER 115-10-6 15 - 25 Exposure Limits: 1880 mg/m3 AIHA: TWA 1000 ppm AIHA: TWA 1000 ppm CMRG: TWA ACETONE 67-64-1 15 - 25 Exposure Limits: 2380 mg/m3 ACGIH: STEL; Table A4; Comments: Added A4 per 2003 ACGIH updates LAM 750 ppm ACGIH: STEL; Table A4; Comments: Added A4 per 2003 ACGIH updates LAM 1780 mg/m3 ACGIH: TWA; Table A4; Comments: Added A4 per 2003 ACGIH updates LAM 500 ppm ACGIH: TWA; Table A4; Comments: Added A4 per 2003 ACGIH updates LAM PENTANE 109-66-0 5 - 15 Exposure Limits: 600 ppm ACGIH: TWA 600 ppm ACGIH: TWA; Category: Pentane PETROLEUM NAPHTHA 64742-48-9 < 5 Exposure Limits: 100 ppm 3M: TWA CYCLOHEXANE 110-82-7 < 5 Exposure Limits: 100 ppm ACGIH: TWA; Comments: Changed limit values per May 2002 RDC database. Change on 7/22/02 does not require reissue. CYCLOPENTANE 287-92-3 < 1 Exposure Limits: 1720 mg/m3 ACGIH: TWA 600 ppm ACGIH: TWA 2-BENZOTRIAZOLYL-4-METHYLPHENOL 2440-22-4 < 0.2 ------------------------------------------------------------------------ SECTION 3: PHYSICAL AND CHEMICAL PROPERTIES ------------------------------------------------------------------------ Physical form,Color,Odor Gas clear, sweet fruity odor liquid in aerosol Water Solubility NIL Boiling point/boiling range No data available. Melting point/melting range NOT DETERMINED Vapour pressure No data available. Percent Volatile CA. 79 % by wt Evaporation rate 1.9 Ether=1 Vapour density = 2.97 Air=1 Specific gravity 0.718 Water=1 Flash point -45.56 C TCC Autoflammability NOT DETERMINED Flammable Limits - LEL NOT DETERMINED Flammable Limits - UEL NOT DETERMINED Viscosity N/A ------------------------------------------------------------------------ SECTION 4: HAZARD IDENTIFICATION ------------------------------------------------------------------------ Risk Phrases Extremely flammable. Risk of serious damage to eyes. Repeated exposure may cause skin dryness or cracking. Vapours may cause drowsiness and dizziness. Toxic to aquatic organisms. May cause long-term adverse effects in the aquatic environment. ------------------------------------------------------------------------ SECTION 5: FIRST AID MEASURES ------------------------------------------------------------------------ Instructions for Ingestion Do not induce vomiting unless instructed to do so by medical personnel. Give victim two glasses of water. Never give anything by mouth to an unconscious person. Get medical attention. Instructions for Eye Contact Immediately flush eyes with large amounts of water for at least 15 minutes. Get immediate medical attention. Instructions for Skin Contact Remove contaminated clothing and shoes. Wash affected area with soap and water. If signs/symptoms develop, get medical attention. Wash contaminated clothing and clean shoes before reuse. Instructions for Inhalation If signs/symptoms develop, remove person to fresh air. If signs/symptoms persist, get medical attention. Special Instructions for First Aid Exposure may increase myocardial irritability. Do not administer sympathomimetic drugs unless absolutely necessary. ------------------------------------------------------------------------ SECTION 6: FIRE FIGHTING MEASURES ------------------------------------------------------------------------ Suitable Extinguishing Media Use fire extinguishers with class B extinguishing agents (e.g., dry chemical, carbon dioxide). Fire Fighting Procedures Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatus (SCBA). Special Instructions for Fire Fighting Aerosol container contains flammable material under pressure. Exposure Hazards during Fire Closed containers exposed to heat from fire may build pressure and explode. Vapors may travel long distances along the ground or floor to an ignition source and flash back. ------------------------------------------------------------------------ SECTION 7: ACCIDENTAL RELEASE MEASURE ------------------------------------------------------------------------ Spill Response Not applicable. Methods for Disposal Not applicable. ------------------------------------------------------------------------ SECTION 8: HANDLING AND STORAGE ------------------------------------------------------------------------ Incompatible Materials Store away from acids. Store away from heat. Store out of direct sunlight. Fire Prevention No smoking while handling this material. Extremely flammable liquid and vapor. Explosion Prevention Keep away from heat, sparks, open flame, pilot lights and other sources of ignition. Use Instructions Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Avoid eye contact with vapors, mists, or spray. Vapors may ignite explosively. May cause flash fire. Prevent build-up of vapors - open all windows and doors. Maintain vapor concentrations below recommended exposure limits. Use only with cross-ventilation. Without adequate ventilation, vapors may settle in low-lying areas. Keep away from heat, sparks, and open flame. Do not smoke or ignite matches, lighters, etc. ------------------------------------------------------------------------ SECTION 9: EXP0SURE CONTROL AND PERSONAL PROTECTION ------------------------------------------------------------------------ DIMETHYL ETHER (115-10-6) Exposure Limits 1880 mg/m3 AIHA: TWA 1000 ppm AIHA: TWA 1000 ppm CMRG: TWA ACETONE (67-64-1) Exposure Limits 2380 mg/m3 ACGIH: STEL; Table A4; Comments: Added A4 per 2003 ACGIH updates LAM 750 ppm ACGIH: STEL; Table A4; Comments: Added A4 per 2003 ACGIH updates LAM 1780 mg/m3 ACGIH: TWA; Table A4; Comments: Added A4 per 2003 ACGIH updates LAM 500 ppm ACGIH: TWA; Table A4; Comments: Added A4 per 2003 ACGIH updates LAM PENTANE (109-66-0) Exposure Limits 600 ppm ACGIH: TWA 600 ppm ACGIH: TWA; Category: Pentane PETROLEUM NAPHTHA (64742-48-9) Exposure Limits 100 ppm 3M: TWA CYCLOHEXANE (110-82-7) Exposure Limits 100 ppm ACGIH: TWA; Comments: Changed limit values per May 2002 RDC database. Change on 7/22/02 does not require reissue. CYCLOPENTANE (287-92-3) Exposure Limits 1720 mg/m3 ACGIH: TWA 600 ppm ACGIH: TWA Recommended Ventilation Use with appropriate local exhaust ventilation. Use with functioning spray booth or local exhaust. Do not use in a confined area or areas with little or no air movement. Do not remain in area where available oxygen may be reduced. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below Occupational Exposure Limits and/or control mist, vapor, or spray. If ventilation is not adequate, use respiratory protection equipment. Eye Protection Avoid eye contact with vapors, mists, or spray. The following should be worn alone or in combination, as appropriate, to prevent eye contact: Safety glasses with side shields Hand Protection Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible materials. Skin Protection Avoid skin contact. Respiratory Protection Select one of the following approved respirators based on airborne concentration of contaminants and in accordance with regulations: Half facepiece or full facepiece air-purifying respirator suitable for organic vapors Ingestion Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Keep out of the reach of children. ------------------------------------------------------------------------ SECTION 10: STABILITY AND REACTIVITY ------------------------------------------------------------------------ Conditions to Avoid Heat Materials to Avoid Strong Oxidizing Agents Hazardous Decomposition Hydrocarbons During Combustion Carbon monoxide During Combustion Carbon dioxide During Combustion Oxides of Nitrogen During Combustion Stability and Reactivity Hazardous polymerization will not occur. Stable This material may be reactive with certain agents under certain conditions - see the remaining headings in this section ------------------------------------------------------------------------ SECTION 11: TOXICOLOGICAL INFORMATION ------------------------------------------------------------------------ Effects from Eye Contact Corrosive (Eye Burns): Signs/symptoms may include cloudy appearance of the cornea, chemical burns, severe pain, tearing, ulcerations, significantly impaired vision or complete loss of vision. Effects from Skin Contact Moderate Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness. Effects from Inhalation Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Intentional concentration and inhalation may be harmful or fatal. May be absorbed following inhalation and cause target organ effects. Prolonged or repeated exposure may cause: Respiratory Effects: Signs/symptoms may include cough, shortness of breath, chest tightness, wheezing, increased heart rate, bluish colored skin (cyanosis), sputum production, changes in lung function tests, and/or respiratory failure. Single exposure, above recommended guidelines, may cause: Cardiac Sensitization: Signs/symptoms may include irregular heartbeat (arrhythmia), faintness, chest pain, and may be fatal. Effects from Ingestion Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. May be absorbed following ingestion and cause target organ effects. Other Toxicological Information Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness. ------------------------------------------------------------------------ SECTION 12: ECOLOGICAL INFORMATION ------------------------------------------------------------------------ Environmental Data No data available. Ecotoxicity Data Not determined. Ecofate Data Not determined. ------------------------------------------------------------------------ SECTION 13: DISPOSAL INFORMATION ------------------------------------------------------------------------ Product as Sold Incinerate in a permitted hazardous waste incinerator. As a disposal alternative, dispose of waste product in a permitted hazardous waste facility. The facility should be equipped to handle gaseous waste. ------------------------------------------------------------------------ SECTION 14: TRANSPORT INFORMATION ------------------------------------------------------------------------ UN Number UN1950, AEROSOLS, FLAMMABLE, 2.1 IMO Class UN1950, AEROSOLS, 2.1, LIMITED QUANTITY ICAO Class UN1950, AEROSOLS, FLAMMABLE, 2.1 Special Instructions Transportation classifications are provided as a customer service. As for shipping, YOU remain responsible for complying with all applicable laws and regulations, including proper transportation classification and packaging. 3M's transportation classifications are based on product formulation, packaging, 3M policies and 3M's understanding of applicable current regulations. 3M does not guarantee the accuracy of this classification information. This information applies only to transportation classification and not the packaging, labeling or marking requirements. The above information is only for reference. If you are shipping by air or ocean, YOU are advised to check & meet applicable regulatory requirements. ------------------------------------------------------------------------ SECTION 15: REGULATORY INFORMATION ------------------------------------------------------------------------ Symbols F+ Extremely Flammable Xi Irritant N Dangerous to environment Risk Phrases Extremely flammable. Risk of serious damage to eyes. Repeated exposure may cause skin dryness or cracking. Vapours may cause drowsiness and dizziness. Toxic to aquatic organisms. May cause long-term adverse effects in the aquatic environment. Safety Phrases Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50 degrees C. Do not pierce or burn, even after use. Do not spray on a naked flame or any incandescent material. Keep away from sources of ignition - No Smoking. Keep out of the reach of children. Do not breathe vapor or spray. Use only in well ventilated areas. Wear eye protection. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Avoid release to the environment. Refer to special instructions/safety data sheets. Special Regulatory Information Contact 3M for more information. ------------------------------------------------------------------------ SECTION 16: OTHER INFORMATION ------------------------------------------------------------------------ The information on this data sheet represents our current data and best opinion as to the proper use in handling of this product under normal conditions. Any use of the product which is not in conformance with this data sheet or which involves using the product in combination with any other product or any other process is the responsibility of the user.