3M Canada Company 1840 Oxford Street East, Post Office Box 5757 London, Ontario N6A 4T1 Medical Emergency Telephone: (519) 451-2500, Ext. 2222 Transportation Emergency Telephone (CANUTEC): (613) 996-6666 ======================================================================= Material Safety Data Sheet ======================================================================= Document id : 22-7596-4 Issue date : 2012/01/11 Version : 6.00 Supersedes date : 2008/05/29 Copyright, 1997, 3M Canada Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. Prepared by: Corporate Regulatory Services, 3M Canada Company Telephone: (800) 364-3577, Fax: (800) 603-7758, Web Site: www.3M.ca ----------------------------------------------------------------------- 1 Chemical Product and Company Identification ----------------------------------------------------------------------- Tradename: Scotch-Weld(TM) Engineering Grade Instant Adhesive PR1500-2 & PR1500A-40 (INACTIVE) Product ID: 62-6137-0250-5 CS-0406-7270-4 62-6137-0355-2 62-6138-4050-3 Intended Use of Product: ADHESIVE Division: AD - Industrial Adhesives and Tapes Division ----------------------------------------------------------------------- 2 Hazards Identification ----------------------------------------------------------------------- Critical Hazards: Combustible liquid and vapour. Severe Eye Irritation: Signs/symptoms may include significant redness, swelling, pain, tearing, cloudy appearance of the cornea, and impaired vision. Bonds eyelids rapidly. Moderate Skin Irritation: Signs/symptoms can include localized redness, swelling, itching, and dryness. Bonds skin rapidly. Prolonged or repeated exposure may cause: Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching. See Sections 7 and 11 for further information. Scotch-Weld(TM) Engineering Grade Instant Page 2 of 10   Adhesive PR1500-2 & PR1500A-40 (INACTIVE) ----------------------------------------------------------------------- ----------------------------------------------------------------------- 3 Composition/Information on Ingredients ----------------------------------------------------------------------- Ingredient Name CAS Number Percentage ------------------------------------- ------------------ ------------- ETHYL CYANOACRYLATE 7085-85-0 85 - 95 ACRYLIC POLYMER: NJTS No. Trade Secret 10 15 56705700001-5863P HYDROQUINONE 123-31-9 0.1 0.25 NOTE: ACRYLIC POLYMER is a Trade Secret material which is not controlled according to WHMIS criteria. Each percentage is expressed as the ratio of the weight of the ingredient to the weight of the controlled product. ----------------------------------------------------------------------- 4 First Aid Measures ----------------------------------------------------------------------- Instructions for Eye Contact: Immediately flush eyes with large amounts of water for at least 30 minutes. Get immediate medical attention. DO NOT PEEL EYELIDS APART. Instructions for Skin Contact: FOR SKIN BONDS: Quickly soak in warm water and avoid use of excessive force to free bonded area. If unable to free bonded area, or if lips or mouth are bonded, get medical attention. If irritation persists, get medical attention. Instructions for Inhalation: Remove person to fresh air. If signs/symptoms develop, get medical attention. Instructions for Ingestion: Do not induce vomiting unless instructed to do so by medical personnel. Give victim two glasses of water. Never give anything by mouth to an unconscious person. Get medical attention. ----------------------------------------------------------------------- 5 Fire Fighting Measures ----------------------------------------------------------------------- Flash point: >= 79.4 C CC Lower Explosive Limit (%): Not Available Upper Explosive Limit (%): Not Available Autoignition temperature: Not Available Suitable Extinguishing Media: Use fire extinguishers with class B extinguishing agents (e.g., dry chemical, carbon dioxide). Scotch-Weld(TM) Engineering Grade Instant Page 3 of 10   Adhesive PR1500-2 & PR1500A-40 (INACTIVE) ----------------------------------------------------------------------- Exposure Hazards during Fire: Closed containers exposed to heat from fire may build pressure and explode. Vapours may travel long distances along the ground or floor to an ignition source and flash back. Combustion Products from Fire: Carbon monoxide - During Combustion; Carbon dioxide - During Combustion; Oxides of Nitrogen - During Combustion; Unusual Fire and Explosion Hazards Combustible liquid and vapour. Fire Fighting Procedures: Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and prevent explosive rupture. Water may be used to blanket the fire. Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatus (SCBA). NFPA: Health 2 NFPA: Fire 2 NFPA: Reactivity 1 NFPA: Unusual Reaction Hazard none National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. ----------------------------------------------------------------------- 6 Accidental Release Measures ----------------------------------------------------------------------- Personal Precautions: Observe precautions from other sections. Call 3M- HELPS line (1-800-364-3577) for more information on handling and managing the spill. Environmental Procedures No data available. Methods for cleaning up No data available. Spill Response: Evacuate unprotected and untrained personnel from hazard area. The spill should be cleaned up by qualified personnel. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn or explode. Contain spill. For Scotch-Weld(TM) Engineering Grade Instant Page 4 of 10   Adhesive PR1500-2 & PR1500A-40 (INACTIVE) ----------------------------------------------------------------------- larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Collect as much of the spilled material as possible using non-sparking tools. Clean up residue with an appropriate solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow safety precautions on the solvent label and MSDS. Place in a closed container approved for transportation by appropriate authorities. Dispose of collected material as soon as possible. ----------------------------------------------------------------------- 7 Handling and Storage ----------------------------------------------------------------------- Storage Requirements: Keep container closed when not in use. Incompatible Materials: Store away from heat; Store out of direct sunlight. Store away from oxidizing agents. Alcohols; Strong bases; Water; Material polymerizes rapidly by contact with water, alcohol, amines and alkalis. Ventilation: Keep container in well-ventilated area. Fire Prevention: Combustible liquid and vapour. Explosion Prevention: Keep away from heat, sparks, open flame, pilot lights and other sources of ignition. Use Instructions: Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Keep container tightly closed. Avoid breathing of vapours, mists or spray. Avoid skin contact. Avoid breathing of vapours created during the cure cycle. Avoid eye contact with vapours, mists, or spray. Avoid breathing of dust created by cutting, sanding, grinding or machining. For industrial or professional use only. Avoid contact with oxidizing agents. Scotch-Weld(TM) Engineering Grade Instant Page 5 of 10   Adhesive PR1500-2 & PR1500A-40 (INACTIVE) ----------------------------------------------------------------------- ----------------------------------------------------------------------- 8 Exposure Controls/Personal Protection ----------------------------------------------------------------------- Personal Protection ------------------- Eye Protection: Avoid eye contact with vapours, mists, or spray. The following should be worn alone or in combination, as appropriate, to prevent eye contact: Safety glasses with side shields Indirect vented goggles; Hand Protection: Wear appropriate gloves when handling this material. The following glove material(s) are recommended: nitrile rubber; polyethylene; fluoroelastomer (Viton); DO NOT wear cotton gloves. Skin Protection: Avoid skin contact. Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible materials. The following protective clothing material(s) are recommended: Apron - Polyethylene/ethylene vinyl alcohol Respiratory Protection: Avoid breathing of vapours, mists or spray. Avoid breathing of vapours created during the cure cycle. Avoid breathing of dust created by cutting, sanding, grinding or machining. Select one of the following approved respirators based on airborne concentration of contaminants and in accordance with regulations: Half facepiece or fullface air-purifying respirator with organic vapor cartridges and P95 particulate prefilters Half facepiece or fullface air-purifying respirator with organic vapour cartridges and N95 particulate prefilters; Half facepiece or fullface air-purifying respirator with organic vapour cartridges and P100 particulate prefilters; Ingestion (Prevention): Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Keep out of the reach of children. Recommended Ventilation: Provide appropriate local exhaust for cutting, grinding, sanding or machining. Curing enclosures must be exhausted to outdoors or to a suitable emission control device. Scotch-Weld(TM) Engineering Grade Instant Page 6 of 10   Adhesive PR1500-2 & PR1500A-40 (INACTIVE) ----------------------------------------------------------------------- Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below Occupational Exposure Limits. If ventilation is not adequate, use respiratory protection equipment. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below Occupational Exposure Limits and/or control mist, vapour, or spray. If ventilation is not adequate, use respiratory protection equipment. Ingredient Exposure Data ------------------------ ETHYL CYANOACRYLATE (7085-85-0) Specific Ingredient Data No data available. LD50 (rat, oral) > 5 ml/kg LC50 (rat, inhalation/4 hours) No data available. Exposure Limits ACGIH-TWA: 0.2 ppm ACGIH: TWA ACRYLIC POLYMER: NJTS No. 56705700001-5863P (Trade Secret) LD50 (rat, oral) No data available. LC50 (rat, inhalation/4 hours) No data available. Exposure Limits No data available. HYDROQUINONE (123-31-9) LD50 (rat, oral) 320 mg/kg LC50 (rat, inhalation/4 hours) No data available. Exposure Limits CMRG: STEL 2 mg/m3 ACGIH: TWA 4 mg/m3 (Table A3) ----------------------------------------------------------------------- 9 Physical and Chemical Properties ----------------------------------------------------------------------- Physical form,Color,Odour: Liquid; thin; Clear; Colourless; sharp, irritating odour; Odour Threshold: No data available. pH: Not applicable Boiling point/boiling range: >= 55.0 C @ 2 mmHg Melting point/melting range: Not applicable Vapour pressure: <= 0.5 mmHg @ 23.9 C Water Solubility: Nil Specific gravity: 0.9 - 1.1 Water=1 Vapour density: Not Available Volatile organic compounds: Not Available Evaporation rate: Negligible Viscosity: 1275 2000 centipoise at 23 C Percent Volatile: No data available. Scotch-Weld(TM) Engineering Grade Instant Page 7 of 10   Adhesive PR1500-2 & PR1500A-40 (INACTIVE) ----------------------------------------------------------------------- ----------------------------------------------------------------------- 10 Stability and Reactivity ----------------------------------------------------------------------- Conditions to Avoid: Heat; Store out of direct sunlight. Materials to Avoid: Alcohols; Strong oxidizing agents; Strong bases; Water; Material polymerizes rapidly by contact with water, alcohol, amines and alkalis. Hazardous Decomposition: Carbon monoxide - During Combustion; Carbon dioxide - During Combustion; Oxides of Nitrogen - During Combustion; Stability and Reactivity: Stable. Hazardous polymerization may occur. May occur in large quantities only. ----------------------------------------------------------------------- 11 Toxicological Information ----------------------------------------------------------------------- Effects from Eye Contact: Bonds eyelids rapidly. Severe Eye Irritation: Signs/symptoms may include significant redness, swelling, pain, tearing, cloudy appearance of the cornea, and impaired vision. Vapours released during curing may cause eye irritation. Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision. Dust created by cutting, grinding, sanding, or machining can cause eye irritation: Signs/symptoms can include redness, swelling, pain, tearing, and blurred or hazy vision. Effects from Skin Contact: Bonds skin rapidly. Moderate Skin Irritation: Signs/symptoms can include localized redness, swelling, itching, and dryness. Prolonged or repeated exposure may cause: Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching. Effects from Inhalation: Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Dust from cutting, grinding, sanding or machining may cause irritation of the respiratory system. Signs/symptoms may include Scotch-Weld(TM) Engineering Grade Instant Page 8 of 10   Adhesive PR1500-2 & PR1500A-40 (INACTIVE) ----------------------------------------------------------------------- cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Effects from Ingestion: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. Sensitization Information: Prolonged or repeated exposure may cause: Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching. Carcinogenicity: No data available. Mutagenicity: No data available. Reproductive Effects: No data available. Component Based Information: No data available. Product Based Information: No data available. ----------------------------------------------------------------------- 12 Ecological Information ----------------------------------------------------------------------- Environmental Data: Ecotoxicity Data: Not determined. Ecofate Data: Not determined. ----------------------------------------------------------------------- 13 Disposal Considerations ----------------------------------------------------------------------- Product as Sold: Cure (harden, set, or react) the product according to product instructions. Dispose of completely cured (or polymerized) wastes in a sanitary landfill. Incinerate in an industrial or commercial facility. As a disposal alternative, dispose of waste product in a facility permitted to accept chemical waste. Product Packaging: No data available. Special Instructions: Since regulations vary, consult applicable regulations or authorities before disposal. Scotch-Weld(TM) Engineering Grade Instant Page 9 of 10   Adhesive PR1500-2 & PR1500A-40 (INACTIVE) ----------------------------------------------------------------------- ----------------------------------------------------------------------- 14 Transport Information ----------------------------------------------------------------------- Transportation of Dangerous Goods --------------------------------- TDG Classification: Non-Regulated Material Special Instructions: Not regulated per U.S. DOT, IATA or IMO. Special Information:: Contact 3M for more information. These transportation classifications are provided as a customer service. As the shipper YOU remain responsible for complying with all applicable laws and regulations, including proper transportation classification and packaging. 3M's transportation classifications are based on product formulation, packaging, 3M policies and 3M's understanding of applicable current regulations. 3M does not guarantee the accuracy of this classification information. This information applies only to transportation classification and not the packaging, labeling, or marking requirements. The original 3M package is certified for Canadian ground shipment only. If you are shipping by air or ocean, the package may not meet applicable regulatory requirements. ----------------------------------------------------------------------- 15 Regulatory Information ----------------------------------------------------------------------- WHMIS Classification: B3, D2B NOTE: This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR. Product Certifications: The product on this MSDS, or all its components, is included on the following countries' chemical inventories, as noted: EINECS - European Inventory of Existing Commercial Chemical Substances TSCA - Toxic Substances Control Act (USA) The components of this product are in compliance with the chemical notification requirements of CEPA. Scotch-Weld(TM) Engineering Grade Instant Page 10 of 10   Adhesive PR1500-2 & PR1500A-40 (INACTIVE) ----------------------------------------------------------------------- ----------------------------------------------------------------------- 16 Other Information ----------------------------------------------------------------------- Reason for Reissue: The following Sections and topics have been updated or revised: Update Tradename (Obsolete product) The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, STATUTORY OR OTHERWISE, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OR CONDITION OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. ---End---