3M Canada Company Post Office Box 5757 London, Ontario N6A 4T1 Medical Emergency Telephone: (519)451-2500, Ext. 2222 ======================================================================= Material Safety Data Sheet ======================================================================= Document id : 10-3802-5 Issue date : 2002/12/12 Version : 14.00 Supersedes date : 2001/07/08 Prepared by: Environmental Health and Safety Services Department, 3M Canada Company. Telephone: (519) 452-6102, Fax: (519) 452-6015. ----------------------------------------------------------------------- 1 Product Identification ----------------------------------------------------------------------- Tradename: FC-120 FLUORAD BRAND FLUOROCHEMICAL SURFACTANT (INACTIVE) Product ID: 98-0211-0191-4 98-0211-0395-1 98-0211-0895-0 98-0211-1077-4 98-0211-7218-8 ZF-0002-1024-3 Intended Use of Product: SURFACTANT Division: 3M SPECIALTY MATERIALS ----------------------------------------------------------------------- 2 Composition/Information on Ingredients ----------------------------------------------------------------------- Ingredient Name CAS Number Percentage ------------------------------------- ------------------ ------------- 2-BUTOXYETHANOL 111-76-2 37.5 WATER 7732-18-5 36.0 - 39.0 C10 AMMONIUM PERFLUOROALKYL SULFONATE 67906-42-7 21.0 - 24.0 C9 AMMONIUM PERFLUOROALKYL SULFONATE 17202-41-4 1.0 - 3.0 DIISOPROPYL ETHER 108-20-3 0.1 - 1.0 ----------------------------------------------------------------------- 3 Hazards Identification ----------------------------------------------------------------------- Critical Hazards: May be absorbed through the skin and produce effects similar to those caused by inhalation and/or ingestion. FC-120 FLUORAD BRAND FLUOROCHEMICAL SURFACTANT Page 2 of 9 (INACTIVE) ----------------------------------------------------------------------- See Sections 7 and 11 for further information. ----------------------------------------------------------------------- 4 First Aid Measures ----------------------------------------------------------------------- Instructions for Eye Contact: Immediately flush eyes with large amounts of water. Get immediate medical attention. Instructions for Skin Contact: Flush skin with large amounts of water. If irritation persists, get medical attention. Instructions for Inhalation: Remove person to fresh air. If not breathing, give artificial respiration. If breathing is difficult, get immediate medical attention. Instructions for Ingestion: If swallowed, call a physician immediately. Only induce vomiting at the instruction of a physician. Never give anything by mouth to an unconscious person. ----------------------------------------------------------------------- 5 Fire Fighting Measures ----------------------------------------------------------------------- Flash point: Approximately 48 C PMCC Lower Explosive Limit (%): Not available Upper Explosive Limit (%): Not available Autoignition temperature: Not available Suitable Extinguishing Media: Water; Carbon Dioxide; Dry chemical; Foam; Exposure Hazards during Fire: No data available. Combustion Products from Fire: Carbon monoxide and carbon dioxide; oxides of nitrogen; oxides of sulfur; hydrogen fluoride; Ammonia; Fire Fighting Procedures: Wear full protective clothing, including helmet, self-contained, positive pressure or pressure demand breathing apparatus, bunker coat and pants, bands around arms, waist and legs, face mask, and protective covering for exposed areas of the head. ----------------------------------------------------------------------- 6 Accidental Release Measures ----------------------------------------------------------------------- Personal Precautions: Refer to other sections of this MSDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. FC-120 FLUORAD BRAND FLUOROCHEMICAL SURFACTANT Page 3 of 9 (INACTIVE) ----------------------------------------------------------------------- Spill Response: Ventilate the area with fresh air. Remove all ignition sources such as flames, smoking materials, and electrical spark sources. Use only non-sparking tools. Contain spill. Evacuate unprotected and untrained personnel from hazard area. The spill should be cleaned up by qualified personnel. Cover with absorbent material. Collect as much of the spilled material as possible using non-sparking tools. Clean up residue with water. Place in an approved metal container. Seal the container. Methods for Disposal: Incinerate in a permitted hazardous waste incinerator. Combustion products will include HF. Facility must be capable of handling halogenated materials. ----------------------------------------------------------------------- 7 Handling and Storage ----------------------------------------------------------------------- Storage Requirements: Store away from areas where product may come into contact with food or pharmaceuticals. Store at room temperature. Keep container closed when not in use. Incompatible Materials: Not applicable. Ventilation: Keep container in well-ventilated area. Fire Prevention: Ground containers securely when transferring contents. Wear low static or properly grounded shoes. Explosion Prevention: Keep away from heat, sparks, open flame, pilot lights and other sources of ignition. Use Instructions: Keep container tightly closed. No smoking: Smoking while using this product can result in contamination of the tobacco and/or smoke and lead to the formation of the hazardous decomposition products mentioned in section 10 of this MSDS. ----------------------------------------------------------------------- 8 Exposure Controls/Personal Protection ----------------------------------------------------------------------- Personal Protection ------------------- Eye Protection: Avoid eye contact with vapours, mists, or spray. Indirect vented goggles FC-120 FLUORAD BRAND FLUOROCHEMICAL SURFACTANT Page 4 of 9 (INACTIVE) ----------------------------------------------------------------------- Hand Protection: Wear appropriate gloves when handling this material. The following glove material(s) are recommended: butyl rubber; Skin Protection: Avoid skin contact. Respiratory Protection: Avoid breathing of airborne material. Select one of the following approved respirators based on airborne concentration of contaminants and in accordance with regulations: half-mask organic vapour respirator with dust/mist prefilter; Ingestion (Prevention): Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Wash hands after handling and before eating. Recommended Ventilation: If exhaust ventilation is not adequate, use appropriate respiratory protection. Provide ventilation adequate to control vapour concentrations below recommended exposure limits and/or control spray or mist. Ingredient Exposure Data ------------------------ 2-BUTOXYETHANOL (111-76-2) LD50 (rat, oral):: 470 mg/kg LC50 (rat, inhalation/4 hours):: 450 ppm PIN (Product Identification Number):: 2369 Inventory Certifications:: AICS - Australian Inventory of Chemical Substances CICS - Chinese Inventory of Chemical Substances DSL - Domestic Substances List (Canada) 2039050 EINECS - European Inventory of Existing Commercial Chemical Substances KE-04134 KECI - Korean Existing Chemicals Inventory 2-407;7-97 MITI - Ministry of International Trade and Industry (JAPAN) PICCS - Philippines Inventory of Commercial Chemical Substances TSCA - Toxic Substances Control Act (USA) Exposure Limits: : ACGIH: TWA 20 ppm ACGIH: TWA 121 mg/m3 EU Hazard Symbols and Risk Phrases:: EU - Adaptation 28 (Xn,Xi; R:20 - 21-22-36-38) WATER (7732-18-5) LD50 (rat, oral):: > 90 ml/kg LC50 (rat, inhalation/4 hours):: No data available. FC-120 FLUORAD BRAND FLUOROCHEMICAL SURFACTANT Page 5 of 9 (INACTIVE) ----------------------------------------------------------------------- Exposure Limits:: No data available. C10 AMMONIUM PERFLUOROALKYL SULFONATE (67906-42-7) LD50 (rat, oral):: No data available. LC50 (rat, inhalation/4 hours):: No data available. Exposure Limits:: No data available. C9 AMMONIUM PERFLUOROALKYL SULFONATE (17202-41-4) Specific Ingredient Data: No data available. LD50 (rat, oral):: No data available. LC50 (rat, inhalation/4 hours):: No data available. Exposure Limits:: No data available. DIISOPROPYL ETHER (108-20-3) LD50 (rat, oral):: 8470 mg/kg LC50 (rat, inhalation/4 hours):: 162 g/m3 PIN (Product Identification Number):: 1159 Inventory Certifications:: DSL - Domestic Substances List (Canada) CICS - Chinese Inventory of Chemical Substances 2035606 EINECS - European Inventory of Existing Commercial Chemical Substances AICS - Australian Inventory of Chemical Substances TSCA - Toxic Substances Control Act (USA) PICCS - Philippines Inventory of Commercial Chemical Substances KE-27717 KECI - Korean Existing Chemicals Inventory 2-362 MITI - Ministry of International Trade and Industry (JAPAN) Exposure Limits:: ACGIH: TWA 250 ppm ACGIH: TWA 1050 mg/m3 ACGIH: STEL 310 ppm ACGIH: STEL 1300 mg/m3 EU Hazard Symbols and Risk Phrases:: EU - Adaptation 25 (F; R:11-19-66-67) EU Nota:: 6 ----------------------------------------------------------------------- 9 Physical and Chemical Properties ----------------------------------------------------------------------- Physical form,Color,Odour: Liquid; clear to pale amber solution; Odour Threshold: No data available. pH: 8.5 - 9.5 Boiling point/boiling range: Approximately 96 C Melting point/melting range: Not applicable Vapour pressure: Approximately 16 mmHg calculated @ 20 C FC-120 FLUORAD BRAND FLUOROCHEMICAL SURFACTANT Page 6 of 9 (INACTIVE) ----------------------------------------------------------------------- Water Solubility: Moderate Partition coefficient (K o/w): No data available. Specific gravity: 1.08 g/ml Vapour density: Approximately 1.08 Air=1 calculated @ 20 C Volatile organic compounds: 380 gms/liter SCAQMD Evaporation rate: < 1 BuOAc=1 Viscosity: Not available ----------------------------------------------------------------------- 10 Stability and Reactivity ----------------------------------------------------------------------- Conditions to Avoid: None known. Materials to Avoid: Not applicable. Hazardous Decomposition: Carbon monoxide and carbon dioxide; oxides of nitrogen; oxides of sulfur; hydrogen fluoride; Ammonia; Stability and Reactivity: Stable. Hazardous polymerization will not occur. ----------------------------------------------------------------------- 11 Toxicological Information ----------------------------------------------------------------------- Effects from Eye Contact: Mild Eye Irritation: Signs/symptoms may include redness, pain, and tearing. Effects from Skin Contact: Mild Skin Irritation: Signs/symptoms can include localized redness, swelling, and itching. May be absorbed through the skin and produce effects similar to those caused by inhalation and/or ingestion. Effects from Inhalation: Single overexposure, above recommended guidelines, may cause: Upper Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Effects from Ingestion: Ingestion may cause: Chemical (Aspiration) Pneumonitis: Signs/symptoms can include coughing, gasping, choking, burning of the mouth, difficulty breathing, bluish colored skin (cyanosis), and possibly death. Sensitization Information: No data available. Carcinogenicity: No data available. FC-120 FLUORAD BRAND FLUOROCHEMICAL SURFACTANT Page 7 of 9 (INACTIVE) ----------------------------------------------------------------------- Mutagenicity: No data available. Reproductive Effects: No data available. Component Based Information: No data available. Product Based Information: No data available. Other Effects & Information: A Material Toxicity Summary Sheet (MTSS) has been developed for this product. Please contact the address listed on the first page of this MSDS to obtain a copy of the MTSS for this product. ----------------------------------------------------------------------- 12 Ecological Information ----------------------------------------------------------------------- Environmental Data: Persistence/Biodegradability: The components labeled 'perfluorinated' are completely fluorinated. Perfluoroalkyl compounds resist degradation in most natural environments. Ecotoxicity Data: Testing indicates this product is toxic to aquatic organisms (1 mg/L < Lowest LC50, EC50, or IC50 < or = 10 mg/L). Testing indicates this product has insignificant toxicity to wastewater treatment system organisms (sludge respiration IC50 > 1000 mg/L). Ecofate Data: Other Effects and Information: BIODEGRADATION: Chemical Oxygen Demand (COD): 1.0 g/g 5 Day Biochemical Oxygen Demand (BOD-5): 0.07 g/g 20-Day Biochemical Demand (BOD20): 0.72 g/g AQUATIC TOXICITY: Fathead minnow (Pimephales promelas): 96 hour LC50, 4.8 mg/l (Water flea (Daphnia magna)): 48 hour EC50, 44 mg/l Microtox (Photobacterium phosphoreum) 30-min EC50: 330 mg/l Activated Sludge Respiration Inhibition Test (OECD Method 209): 30 minute EC50, and 30 hour EC50: > 1000 mg/l Handling this product according to recommendations is important because its properties present a moderate environmental hazard. Take precautions to prevent direct release of this product to the environment. FC-120 FLUORAD BRAND FLUOROCHEMICAL SURFACTANT Page 8 of 9 (INACTIVE) ----------------------------------------------------------------------- ----------------------------------------------------------------------- 13 Disposal Considerations ----------------------------------------------------------------------- Product as Sold: No data available. Product Packaging: No data available. Special Instructions: Since regulations vary, consult applicable regulations or authorities before disposal. ----------------------------------------------------------------------- 14 Transportation Information ----------------------------------------------------------------------- Transportation of Dangerous Goods --------------------------------- TDG Classification: Non-Regulated Material ----------------------------------------------------------------------- 15 Regulatory Information ----------------------------------------------------------------------- WHMIS Classification: B3, D1A NOTE: This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR. Product Certifications: The product on this MSDS, or all its components, is included on the following countries' chemical inventories, as noted: AICS - Australian Inventory of Chemical Substances DSL - Domestic Substances List (Canada) EINECS - European Inventory of Existing Commercial Chemical Substances TSCA - Toxic Substances Control Act (USA) KECI - Korean Existing Chemicals Inventory CICS - Chinese Inventory of Chemical Substances PICCS - Philippines Inventory of Commercial Chemical Substances ----------------------------------------------------------------------- 16 Other Information ----------------------------------------------------------------------- Reason for Reissue: The following Sections and topics have been updated or revised: Update Tradename (Obsolete product) FC-120 FLUORAD BRAND FLUOROCHEMICAL SURFACTANT Page 9 of 9 (INACTIVE) ----------------------------------------------------------------------- Copyright, 1997, Minnesota Mining and Manufacturing Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: 1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and 2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, STATUTORY OR OTHERWISE, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OR CONDITION OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. ---End---