3M Canada Company Post Office Box 5757 London, Ontario N6A 4T1 Medical Emergency Telephone: (519)451-2500, Ext. 2222 ======================================================================= Material Safety Data Sheet ======================================================================= Document id : 10-3807-4 Issue date : 2002/12/12 Version : 17.00 Supersedes date : 2000/04/03 Prepared by: Environmental Health and Safety Services Department, 3M Canada Company. Telephone: (519) 452-6102, Fax: (519) 452-6015. ----------------------------------------------------------------------- 1 Product Identification ----------------------------------------------------------------------- Tradename: FC-135 "FLUORAD" BRAND FLUOROCHEMICAL SURFACTANT (INACTIVE) Product ID: GF-1000-0050-4 98-0211-0558-4 98-0211-0559-2 98-0211-0898-4 98-0211-7220-4 Intended Use of Product: SURFACTANT Division: 3M SPECIALTY MATERIALS ----------------------------------------------------------------------- 2 Composition/Information on Ingredients ----------------------------------------------------------------------- Ingredient Name CAS Number Percentage ------------------------------------- ------------------ ------------- FLUOROALKYL QUATERNARY AMMONIUM 1652-63-7 40 - 44 IODIDE (C8) ISOPROPYL ALCOHOL 67-63-0 33 WATER 7732-18-5 17 FLUOROALKYL QUATERNARY AMMONIUM 68957-58-4 1 - 5 IODIDE (C6) FLUOROALKYL QUATERNARY AMMONIUM 67584-58-1 1 - 4 IODIDE (C7) FLUOROALKYL QUATERNARY AMMONIUM 67939-95-1 1 - 4 IODIDE (C4) FLUOROALKYL QUATERNARY AMMONIUM 68957-57-3 0.1 - 2 IODIDE (C5) RESIDUAL ORGANIC FLUOROCHEMICALS Mixture 0 - 1 FC-135 "FLUORAD" BRAND FLUOROCHEMICAL SURFACTANT Page 2 of 10 (INACTIVE) ----------------------------------------------------------------------- Ingredient Name CAS Number Percentage ------------------------------------- ------------------ ------------- METHYL IODIDE 74-88-4 0.1 ----------------------------------------------------------------------- 3 Hazards Identification ----------------------------------------------------------------------- Critical Hazards: Single overexposure, above recommended guidelines, may cause: Central Nervous System Depression: signs/symptoms can include headache, dizziness, drowsiness, incoordination, slowed reaction time, slurred speech, giddiness and unconsciousness. May be absorbed through the skin and produce effects similar to those caused by inhalation and/or ingestion. See Sections 7 and 11 for further information. ----------------------------------------------------------------------- 4 First Aid Measures ----------------------------------------------------------------------- Instructions for Eye Contact: Immediately flush eyes with large amounts of water. Get immediate medical attention. Instructions for Skin Contact: Flush skin with large amounts of water. If irritation persists, get medical attention. Instructions for Inhalation: If signs/symptoms occur, remove person to fresh air. If signs/symptoms continue, call a physician. Instructions for Ingestion: If swallowed, call a physician immediately. Only induce vomiting at the instruction of a physician. Never give anything by mouth to an unconscious person. ----------------------------------------------------------------------- 5 Fire Fighting Measures ----------------------------------------------------------------------- Flash point: 22 C PMCC ASTM D93 Lower Explosive Limit (%): Not Available. Upper Explosive Limit (%): Not Available. Autoignition temperature: Not Available. Suitable Extinguishing Media: Water; Carbon Dioxide; Dry chemical; Foam; Exposure Hazards during Fire: No data available. Combustion Products from Fire: Carbon monoxide and carbon dioxide; hydrogen fluoride; oxides of nitrogen; oxides of sulfur; Toxic vapours, gases or particulates; FC-135 "FLUORAD" BRAND FLUOROCHEMICAL SURFACTANT Page 3 of 10 (INACTIVE) ----------------------------------------------------------------------- Fire Fighting Procedures: Wear full protective clothing, including helmet, self-contained, positive pressure or pressure demand breathing apparatus, bunker coat and pants, bands around arms, waist and legs, face mask, and protective covering for exposed areas of the head. ----------------------------------------------------------------------- 6 Accidental Release Measures ----------------------------------------------------------------------- Personal Precautions: Refer to other sections of this MSDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. Spill Response: Ventilate the area with fresh air. Remove all ignition sources such as flames, smoking materials, and electrical spark sources. Use only non-sparking tools. Contain spill. Evacuate unprotected and untrained personnel from hazard area. The spill should be cleaned up by qualified personnel. Cover with absorbent material. Cover spill area with a fire-extinguishing foam. An aqueous film forming foam (AFFF) is recommended. Collect as much of the spilled material as possible using non-sparking tools. Clean up residue with water. Place in an approved metal container. Seal the container. Methods for Disposal: Incinerate in a permitted hazardous waste incinerator. Combustion products will include HF. Facility must be capable of handling halogenated materials. ----------------------------------------------------------------------- 7 Handling and Storage ----------------------------------------------------------------------- Storage Requirements: Store away from areas where product may come into contact with food or pharmaceuticals. Keep container closed when not in use. Incompatible Materials: Store away from heat. Store out of direct sunlight. Ventilation: Keep container in well-ventilated area. Fire Prevention: Extremely flammable liquid and vapour. Ground containers securely when transferring contents. Wear low static or properly grounded shoes. No smoking while handling this material. Explosion Prevention: Keep away from heat, sparks, open flame, pilot lights and other sources of ignition. Prevent all sources of ignition. FC-135 "FLUORAD" BRAND FLUOROCHEMICAL SURFACTANT Page 4 of 10 (INACTIVE) ----------------------------------------------------------------------- Use Instructions: Keep container tightly closed. No smoking: Smoking while using this product can result in contamination of the tobacco and/or smoke and lead to the formation of the hazardous decomposition products mentioned in section 10 of this MSDS. ----------------------------------------------------------------------- 8 Exposure Controls/Personal Protection ----------------------------------------------------------------------- Personal Protection ------------------- Eye Protection: Avoid eye contact with vapours, mists, or spray. Indirect vented goggles Hand Protection: Wear appropriate gloves when handling this material. The following glove material(s) are recommended: butyl rubber; natural rubber; Skin Protection: Avoid skin contact. The following protective clothing material(s) are recommended: coveralls; Respiratory Protection: Avoid breathing of airborne material. Select one of the following approved respirators based on airborne concentration of contaminants and in accordance with regulations: half-mask organic vapour and acid gas respirator; full-face organic vapour and acid gas respirator; Ingestion (Prevention): Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Wash hands after handling and before eating. Recommended Ventilation: If exhaust ventilation is not adequate, use appropriate respiratory protection. Provide ventilation adequate to control vapour concentrations below recommended exposure limits and/or control spray or mist. Ingredient Exposure Data ------------------------ FLUOROALKYL QUATERNARY AMMONIUM IODIDE (C8) (1652-63-7) Specific Ingredient Data: No data available. LD50 (rat, oral):: No data available. LC50 (rat, inhalation/4 hours):: No data available. Exposure Limits:: No data available. FC-135 "FLUORAD" BRAND FLUOROCHEMICAL SURFACTANT Page 5 of 10 (INACTIVE) ----------------------------------------------------------------------- ISOPROPYL ALCOHOL (67-63-0) LD50 (rat, oral):: 4710 mg/kg LC50 (rat, inhalation/4 hours):: 17000 ppm PIN (Product Identification Number):: 1219 Inventory Certifications:: AICS - Australian Inventory of Chemical Substances TSCA - Toxic Substances Control Act (USA) DSL - Domestic Substances List (Canada) PICCS - Philippines Inventory of Commercial Chemical Substances KE-29363 KECI - Korean Existing Chemicals Inventory 2-207 MITI - Ministry of International Trade and Industry (JAPAN) CICS - Chinese Inventory of Chemical Substances 2006617 EINECS - European Inventory of Existing Commercial Chemical Substances Exposure Limits:: ACGIH: TWA 400 ppm ACGIH: TWA 983 mg/m3 ACGIH: STEL 500 ppm ACGIH: STEL 1230 mg/m3 EU Hazard Symbols and Risk Phrases:: EU - Adaptation 26 (F,Xi; R:11-36-67) EU Nota:: 6 WATER (7732-18-5) LD50 (rat, oral):: > 90 ml/kg LC50 (rat, inhalation/4 hours):: No data available. Exposure Limits:: No data available. FLUOROALKYL QUATERNARY AMMONIUM IODIDE (C6) (68957-58-4) Specific Ingredient Data: No data available. LD50 (rat, oral):: No data available. LC50 (rat, inhalation/4 hours):: No data available. Exposure Limits:: No data available. FLUOROALKYL QUATERNARY AMMONIUM IODIDE (C7) (67584-58-1) Specific Ingredient Data: No data available. LD50 (rat, oral):: No data available. LC50 (rat, inhalation/4 hours):: No data available. Exposure Limits:: No data available. FLUOROALKYL QUATERNARY AMMONIUM IODIDE (C4) (67939-95-1) Specific Ingredient Data: No data available. LD50 (rat, oral):: No data available. LC50 (rat, inhalation/4 hours):: No data available. Exposure Limits:: No data available. FC-135 "FLUORAD" BRAND FLUOROCHEMICAL SURFACTANT Page 6 of 10 (INACTIVE) ----------------------------------------------------------------------- FLUOROALKYL QUATERNARY AMMONIUM IODIDE (C5) (68957-57-3) Specific Ingredient Data: No data available. LD50 (rat, oral):: No data available. LC50 (rat, inhalation/4 hours):: No data available. Exposure Limits:: No data available. RESIDUAL ORGANIC FLUOROCHEMICALS (Mixture) Specific Ingredient Data: No data available. LD50 (rat, oral):: No data available. LC50 (rat, inhalation/4 hours):: No data available. Exposure Limits:: No data available. METHYL IODIDE (74-88-4) LD50 (rat, oral):: 76 mg/kg LC50 (rat, inhalation/4 hours):: 224 ppm PIN (Product Identification Number):: 2644 Inventory Certifications:: CICS - Chinese Inventory of Chemical Substances 2-42 MITI - Ministry of International Trade and Industry (JAPAN) TSCA - Toxic Substances Control Act (USA) 2008195 EINECS - European Inventory of Existing Commercial Chemical Substances PICCS - Philippines Inventory of Commercial Chemical Substances DSL - Domestic Substances List (Canada) AICS - Australian Inventory of Chemical Substances KE-21038 KECI - Korean Existing Chemicals Inventory Exposure Limits:: ACGIH: TWA 2 ppm (skin contact contributes to exposure) ACGIH: TWA 12 mg/m3 (skin contact contributes to exposure) EU Hazard Symbols and Risk Phrases:: EU - Adaptation 21 (Xn,T,Xi; R:21-23-25-37-38-40 Carc.Cat.3) ----------------------------------------------------------------------- 9 Physical and Chemical Properties ----------------------------------------------------------------------- Physical form,Color,Odour: Liquid; dark amber; isopropyl alcohol odour; Odour Threshold: No data available. pH: 3 - 5 Boiling point/boiling range: 82 C (Initial) Melting point/melting range: Not applicable Vapour pressure: Approximately 24 mmHg at 20 C Water Solubility: Complete Partition coefficient (K o/w): No data available. FC-135 "FLUORAD" BRAND FLUOROCHEMICAL SURFACTANT Page 7 of 10 (INACTIVE) ----------------------------------------------------------------------- Specific gravity: Approximately 1.2 Water=1 Vapour density: Approximately 1.2 Air=1 at 20 C Volatile organic compounds: 396 gms/liter SCAQ443 Evaporation rate: < 1.0 BuOAc=1 Viscosity: Not Available. ----------------------------------------------------------------------- 10 Stability and Reactivity ----------------------------------------------------------------------- Conditions to Avoid: None known. Materials to Avoid: Not applicable. Hazardous Decomposition: Carbon monoxide and carbon dioxide; hydrogen fluoride; oxides of nitrogen; oxides of sulfur; Toxic vapours, gases or particulates; Stability and Reactivity: Stable. Hazardous polymerization will not occur. ----------------------------------------------------------------------- 11 Toxicological Information ----------------------------------------------------------------------- Effects from Eye Contact: Mild Eye Irritation: Signs/symptoms may include redness, pain, and tearing. Effects from Skin Contact: Mild Skin Irritation: Signs/symptoms can include localized redness, swelling, and itching. May be absorbed through the skin and produce effects similar to those caused by inhalation and/or ingestion. Effects from Inhalation: Single overexposure, above recommended guidelines, may cause: Central Nervous System Depression: signs/symptoms can include headache, dizziness, drowsiness, incoordination, slowed reaction time, slurred speech, giddiness and unconsciousness. Upper Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Effects from Ingestion: Animal studies conducted on organic fluorochemicals which are present in this product indicate effects including liver disturbances, weight loss, loss of appetite, lethargy, and neurological, pancreatic, adrenal and hematologic effects. There are no known human health effects from anticipated exposure to these organic fluorochemicals when used as intended and instructed. Sensitization Information: No data available. FC-135 "FLUORAD" BRAND FLUOROCHEMICAL SURFACTANT Page 8 of 10 (INACTIVE) ----------------------------------------------------------------------- Carcinogenicity: No data available. Mutagenicity: No data available. Reproductive Effects: No data available. Component Based Information: No data available. Product Based Information: No data available. Other Effects & Information: A Material Toxicity Summary Sheet (MTSS) has been developed for this product. Please contact the address listed on the first page of this MSDS to obtain a copy of the MTSS for this product. This product contains one or more organic fluorochemicals that have the potential to be absorbed and remain in the body for long periods of time, either as the parent molecule or as metabolites, and may accumulate with repeated exposures. There are no known human health effects from anticipated exposure to these organic fluorochemicals when used as intended and instructed. The presence of organic fluorochemicals in the blood of the general population and subpopulations, such as workers, has been published dating back to the 1970's. 3M's epidemiological study of its own workers indicates no adverse effects. ----------------------------------------------------------------------- 12 Ecological Information ----------------------------------------------------------------------- Environmental Data: Persistence/Biodegradability: This product contains one or more organic fluorochemicals that have the potential to resist degradation and persist in the environment Ecotoxicity Data: No data available. Ecofate Data: Other Effects and Information: BIODEGRADATION DATA: Chemical Oxygen Demand (COD): 1.3 g/g 5 Day Biochemical Oxygen Demand (BOD-5): 0.5 g/g AQUATIC TOXICITY: Fathead minnow (Pimephales promelas): 96-Hr. LC50, 60 mg/l NOTE: Composite COD, BOD, and aquatic toxicity values were calculated from the component data of: ----------------------------------------------------------------------- 13 Disposal Considerations ----------------------------------------------------------------------- FC-135 "FLUORAD" BRAND FLUOROCHEMICAL SURFACTANT Page 9 of 10 (INACTIVE) ----------------------------------------------------------------------- Product as Sold: No data available. Product Packaging: No data available. Special Instructions: Since regulations vary, consult applicable regulations or authorities before disposal. ----------------------------------------------------------------------- 14 Transportation Information ----------------------------------------------------------------------- Transportation of Dangerous Goods --------------------------------- TDG Classification: Regulated Material. Proper Shipping Name: Isopropanol Solution Class/Division: 3.2 UN Number: UN 1219 Packing Group: II ----------------------------------------------------------------------- 15 Regulatory Information ----------------------------------------------------------------------- WHMIS Classification: B2 NOTE: This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR. Product Certifications: The product on this MSDS, or all its components, is included on the following countries' chemical inventories, as noted: AICS - Australian Inventory of Chemical Substances DSL - Domestic Substances List (Canada) EINECS - European Inventory of Existing Commercial Chemical Substances MITI - Ministry of International Trade and Industry (JAPAN) TSCA - Toxic Substances Control Act (USA) PICCS - Philippines Inventory of Commercial Chemical Substances CICS - Chinese Inventory of Chemical Substances KECI - Korean Existing Chemicals Inventory ----------------------------------------------------------------------- 16 Other Information ----------------------------------------------------------------------- FC-135 "FLUORAD" BRAND FLUOROCHEMICAL SURFACTANT Page 10 of 10 (INACTIVE) ----------------------------------------------------------------------- Reason for Reissue: The following Sections and topics have been updated or revised: Update Tradename (Obsolete product) Copyright, 1997, Minnesota Mining and Manufacturing Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: 1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and 2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, STATUTORY OR OTHERWISE, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OR CONDITION OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. ---End---