3M Canada Company 1840 Oxford Street East, Post Office Box 5757 London, Ontario N6A 4T1 Medical Emergency Telephone: (519) 451-2500, Ext. 2222 Transportation Emergency Telephone (CANUTEC): (613) 996-6666 ======================================================================= Material Safety Data Sheet ======================================================================= Document id : 11-6696-6 Issue date : 2011/04/14 Version : 14.00 Supersedes date : 2011/03/04 Copyright, 1997, 3M Canada Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. Prepared by: Corporate Regulatory Services, 3M Canada Company Telephone: (800) 364-3577, Fax: (800) 603-7758, Web Site: www.3M.ca ----------------------------------------------------------------------- 1 Chemical Product and Company Identification ----------------------------------------------------------------------- Tradename: 3M(TM) SCOTCHCAL(TM) TRANSLUCENT GRAPHIC FILM FOR THERMOFORMING (INACTIVE) Product ID: 3M(TM) SCOTCHCAL(TM) TRANSLUCENT GRAPHIC FILM FOR Page 2 of 10   THERMOFORMING (INACTIVE) ----------------------------------------------------------------------- 75-0000-1649-5 75-0000-1650-3 75-0000-1651-1 75-0000-1652-9 75-0000-1653-7 75-0000-1654-5 75-0000-1655-2 75-0000-1656-0 75-0000-1658-6 75-0000-1659-4 75-0000-1660-2 75-3455-7750-8 75-3455-7753-2 75-3455-7754-0 75-3455-7755-7 75-3455-7756-5 75-3455-7758-1 75-3455-7759-9 75-3455-7760-7 75-3455-7761-5 75-3455-7762-3 75-3455-7763-1 75-3455-7764-9 75-3455-7765-6 75-3455-7766-4 75-3455-7767-2 75-3455-7768-0 75-3455-7769-8 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75-3467-2938-9 75-3467-2943-9 75-3467-2952-0 75-3467-2953-8 75-3467-2975-1 75-3467-2998-3 75-3467-2999-1 75-3467-3002-3 75-3467-3003-1 75-3467-3004-9 75-3467-3041-1 75-3467-3042-9 75-3467-3053-6 75-3467-3063-5 75-3467-3064-3 75-3467-3070-0 75-3467-3073-4 75-3467-3074-2 75-3467-3084-1 75-3467-3088-2 75-3467-3104-7 75-3467-3107-0 75-3467-3108-8 75-3467-3113-8 XR-1815-6759-9 75-3467-3496-7 75-3467-3497-5 75-3467-7356-9 75-3467-7357-7 75-3467-7358-5 75-3467-7359-3 75-3467-7360-1 75-3467-7361-9 75-3467-7362-7 75-3467-7363-5 75-3467-7364-3 75-3467-7365-0 75-3467-7366-8 75-3467-7900-4 75-3467-7901-2 75-3467-7902-0 75-3467-7903-8 75-3467-7912-9 75-3467-7913-7 75-3467-7914-5 75-3467-7915-2 75-3467-7963-2 75-3467-7964-0 75-3467-8674-4 DR-3630-0050-3 DR-3630-0151-9 DR-3630-0200-4 DR-3630-0250-9 DR-3630-0260-8 DR-3630-0330-9 DR-3630-0360-6 DR-3630-0430-7 DR-3630-0440-6 DR-3630-0510-6 DR-3630-0530-4 DR-3630-0570-0 DR-3630-0610-4 DR-3630-0730-0 DR-3630-0760-7 DR-3630-0840-7 DR-3630-0870-4 DR-3630-0970-2 DR-3630-1060-1 DR-3630-1080-9 DR-3630-1090-8 DR-3630-1150-0 DR-3630-1160-9 DR-3630-1180-7 DR-3630-1210-2 DR-3630-1250-8 DR-3630-1260-7 DR-3630-1270-6 DR-3630-1280-5 DR-3630-1290-4 DR-3630-1310-0 DR-3630-1330-8 DR-3630-1430-6 DR-3630-1670-7 DR-3630-3170-6 DR-9950-3153-8 DY-3632-3080-5 DY-3636-1190-5 DY-3636-8770-7 3M(TM) SCOTCHCAL(TM) TRANSLUCENT GRAPHIC FILM FOR Page 3 of 10   THERMOFORMING (INACTIVE) ----------------------------------------------------------------------- Intended Use of Product: FILM Division: COMMERCIAL GRAPHICS ----------------------------------------------------------------------- 2 Hazards Identification ----------------------------------------------------------------------- Critical Hazards: Burns may result from contact with hot or molten product. LEAD CHROMATE (7758-97-6) is a cancer hazard causing lung cancer based on human experience (NTP human carcinogen, IARC human carcinogen 1, ACGIH suspected human carcinogen A2). WARNING: Contains a chemical which can cause cancer (1333-86-4) (IARC possible human carcinogen 2B) See Sections 7 and 11 for further information. ----------------------------------------------------------------------- 3 Composition/Information on Ingredients ----------------------------------------------------------------------- Ingredient Name CAS Number Percentage ------------------------------------- ------------------ ------------- PVC FILM Trade Secret 70 - 90 ACRYLIC ADHESIVE Trade Secret 10 - 30 LEAD CHROMATE 7758-97-6 0.1 0.99 CARBON BLACK 1333-86-4 0.1 0.99 Ingredient Statements: Some colours in the film series contain lead chromate based pigments 7758-97-6; carbon black 1330-86-4 NOTE: PVC FILM has no CAS number. ACRYLIC ADHESIVE has no CAS number. Each percentage is expressed as the ratio of the weight of the ingredient to the weight of the controlled product. ----------------------------------------------------------------------- 4 First Aid Measures ----------------------------------------------------------------------- Instructions for Eye Contact: Immediately flush eyes with large amounts of water for at least 30 minutes. DO NOT ATTEMPT TO REMOVE MOLTEN MATERIAL. Get immediate medical attention. Instructions for Skin Contact: Immediately flush skin with large amounts of cold water for at least 15 minutes. DO NOT ATTEMPT TO REMOVE MOLTEN MATERIAL. Cover affected area with a clean dressing. Get immediate medical attention. 3M(TM) SCOTCHCAL(TM) TRANSLUCENT GRAPHIC FILM FOR Page 4 of 10   THERMOFORMING (INACTIVE) ----------------------------------------------------------------------- Instructions for Inhalation: Remove person to fresh air. If signs/symptoms develop, get medical attention. Instructions for Ingestion: No need for first aid is anticipated. ----------------------------------------------------------------------- 5 Fire Fighting Measures ----------------------------------------------------------------------- Flash point: Not applicable Lower Explosive Limit (%): Not applicable Upper Explosive Limit (%): Not applicable Autoignition temperature: Not Available Suitable Extinguishing Media: Ordinary combustible material. Use fire extinguishers with class A extinguishing agents (e.g., water, foam). Exposure Hazards during Fire: No data available. Combustion Products from Fire: Carbon monoxide - During Combustion; Carbon dioxide - During Combustion; Hydrogen Chloride - During Combustion; Unusual Fire and Explosion Hazards None known. Fire Fighting Procedures: Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatus (SCBA). NFPA: Health 1 NFPA: Fire 1 NFPA: Reactivity 0 NFPA: Unusual Reaction Hazard none National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. Special Instructions: Not applicable. 3M(TM) SCOTCHCAL(TM) TRANSLUCENT GRAPHIC FILM FOR Page 5 of 10   THERMOFORMING (INACTIVE) ----------------------------------------------------------------------- ----------------------------------------------------------------------- 6 Accidental Release Measures ----------------------------------------------------------------------- Personal Precautions: No data available. Environmental Procedures No data available. Methods for cleaning up No data available. Methods for Disposal: Not applicable. ----------------------------------------------------------------------- 7 Handling and Storage ----------------------------------------------------------------------- Storage Requirements: Store in a cool, dry place. Incompatible Materials: None known. Ventilation: No data available. Use Instructions: For industrial or professional use only. ----------------------------------------------------------------------- 8 Exposure Controls/Personal Protection ----------------------------------------------------------------------- Personal Protection ------------------- Eye Protection: Avoid eye contact with vapours, mists, or spray. Avoid eye contact with dust or airborne particles. The following should be worn alone or in combination, as appropriate, to prevent eye contact: Safety glasses with side shields Indirect vented goggles; Hand Protection: Avoid skin contact with hot material. Wear appropriate gloves, such as Nomex, when handling this material to prevent thermal burns. Skin Protection: Avoid skin contact. Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible materials. Respiratory Protection: Avoid breathing of vapours. Ingestion (Prevention): 3M(TM) SCOTCHCAL(TM) TRANSLUCENT GRAPHIC FILM FOR Page 6 of 10   THERMOFORMING (INACTIVE) ----------------------------------------------------------------------- Not an expected route of exposure. Recommended Ventilation: Use with appropriate local exhaust ventilation. Provide appropriate local exhaust for molten or extruded material. Use in a well-ventilated area. Provide appropriate local exhaust when product is heated. Provide ventilation adequate to control dust concentrations below recommended exposure limits and/or control dust. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below Occupational Exposure Limits and/or control dust, fume, or airborne particles. If ventilation is not adequate, use respiratory protection equipment. Ingredient Exposure Data ------------------------ PVC FILM (Trade Secret) LD50 (rat, oral) No data available. LC50 (rat, inhalation/4 hours) No data available. Exposure Limits No data available. ACRYLIC ADHESIVE (Trade Secret) Specific Ingredient Data No data available. LD50 (rat, oral) No data available. LC50 (rat, inhalation/4 hours) No data available. Exposure Limits No data available. LEAD CHROMATE (7758-97-6) LD50 (rat, oral) No data available. LC50 (rat, inhalation/4 hours) No data available. Exposure Limits ACGIH: TWA 0.05 mg/m3 as Pb; (Table A2) ACGIH: TWA 0.012 mg/m3 as Cr; (Table A2) CARBON BLACK (1333-86-4) LD50 (rat, oral) > 15400 mg/kg LD50 (dermal, rabbit) > 3 g/kg LC50 (rat, inhalation/4 hours)   6750 mg/m3 Exposure Limits ACGIH: TWA 3.5 mg/m3 (Table A4) CMRG: TWA 0.5 mg/m3 3M(TM) SCOTCHCAL(TM) TRANSLUCENT GRAPHIC FILM FOR Page 7 of 10   THERMOFORMING (INACTIVE) ----------------------------------------------------------------------- ----------------------------------------------------------------------- 9 Physical and Chemical Properties ----------------------------------------------------------------------- Physical form,Color,Odour: Solid; Adhesive coated film; various colours; Odour Threshold: No data available. pH: Not applicable Boiling point/boiling range: Not applicable Melting point/melting range: Not Available Vapour pressure: Not applicable Water Solubility: Nil Specific gravity: Not applicable Vapour density: Not applicable Volatile organic compounds: Not applicable Evaporation rate: Not applicable Viscosity: No data available. Percent Volatile: Not applicable ----------------------------------------------------------------------- 10 Stability and Reactivity ----------------------------------------------------------------------- Conditions to Avoid: None known. Materials to Avoid: None known. Hazardous Decomposition: Carbon monoxide - During Combustion; Carbon dioxide - During Combustion; Hydrogen Chloride - During Combustion; Stability and Reactivity: Stable. Hazardous polymerization will not occur. ----------------------------------------------------------------------- 11 Toxicological Information ----------------------------------------------------------------------- Effects from Eye Contact: During heating: Thermal Burns: Signs/symptoms may include severe pain, redness and swelling, and tissue destruction. Vapours from heated material can cause eye irritation. Signs/symptoms can include redness, swelling, pain, tearing, and blurred or hazy vision. Effects from Skin Contact: During heating: Thermal Burns: Signs/symptoms can include intense pain, redness and swelling, and tissue destruction. Effects from Inhalation: During heating: Vapours from heated material may cause irritation of the 3M(TM) SCOTCHCAL(TM) TRANSLUCENT GRAPHIC FILM FOR Page 8 of 10   THERMOFORMING (INACTIVE) ----------------------------------------------------------------------- respiratory system. Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Effects from Ingestion: No health effects are expected. Sensitization Information: No data available. Carcinogenicity: LEAD CHROMATE (7758-97-6) is a cancer hazard causing lung cancer based on human experience (NTP human carcinogen, IARC human carcinogen 1, ACGIH suspected human carcinogen A2). WARNING: Contains a chemical which can cause cancer (1333-86-4) (IARC possible human carcinogen 2B) Mutagenicity: No data available. Reproductive Effects: No data available. Component Based Information: No data available. Product Based Information: No data available. ----------------------------------------------------------------------- 12 Ecological Information ----------------------------------------------------------------------- Environmental Data: Ecotoxicity Data: Not determined. Ecofate Data: Not determined. Special statements for 2001/58/EC: A conservative assessment indicates this product presents a low environmental risk because use and disposal are unlikely to result in the significant release of components to the environment. ----------------------------------------------------------------------- 13 Disposal Considerations ----------------------------------------------------------------------- Product as Sold: Dispose of waste product in a permitted hazardous waste facility. Product Packaging: No data available. Special Instructions: Since regulations vary, consult applicable regulations or authorities before disposal. 3M(TM) SCOTCHCAL(TM) TRANSLUCENT GRAPHIC FILM FOR Page 9 of 10   THERMOFORMING (INACTIVE) ----------------------------------------------------------------------- ----------------------------------------------------------------------- 14 Transport Information ----------------------------------------------------------------------- Transportation of Dangerous Goods --------------------------------- TDG Classification: Non-Regulated Material Special Information:: Contact 3M for more information. These transportation classifications are provided as a customer service. As the shipper YOU remain responsible for complying with all applicable laws and regulations, including proper transportation classification and packaging. 3M's transportation classifications are based on product formulation, packaging, 3M policies and 3M's understanding of applicable current regulations. 3M does not guarantee the accuracy of this classification information. This information applies only to transportation classification and not the packaging, labeling, or marking requirements. The original 3M package is certified for Canadian ground shipment only. If you are shipping by air or ocean, the package may not meet applicable regulatory requirements. ----------------------------------------------------------------------- 15 Regulatory Information ----------------------------------------------------------------------- WHMIS Classification: Exempt (Manufactured Article) NOTE: This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR. ----------------------------------------------------------------------- 16 Other Information ----------------------------------------------------------------------- Reason for Reissue: The following Sections and topics have been updated or revised: Added product id(s) to the MSDS; Update Tradename (Obsolete product) The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, STATUTORY OR OTHERWISE, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OR CONDITION OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user 3M(TM) SCOTCHCAL(TM) TRANSLUCENT GRAPHIC FILM FOR Page 10 of 10   THERMOFORMING (INACTIVE) ----------------------------------------------------------------------- evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. ---End---