3M Technologies Pte. Ltd. 1 Yishun Avenue 7 Singapore 768923 Phone: +65 6450 8888 Emergency Phone: +65 6849 3050 ======================================================================== Safety Data Sheet ======================================================================== Document id : 19-8850-0 Issue date : 06/07/2012 Version : 1.00 Supersedes date : --- 1 IDENTIFICATION ------------------------------------------------------------------------ Tradename 8001 Static Control Surface Mark Remover 3M Product ID 98-0798-5602-1 Intended Use of Product: Static Control Surface Mark Remover Contact Address: 3M Singapore Pte. Ltd. 1 Yishun Avenue 7 Singapore 768923 Phone: +65 6849 3050 www.3m.com.sg 2 HAZARDS IDENTIFICATION ------------------------------------------------------------------------ GHS Classification - Environmental Acute Aquatic Toxicity: Category 3. GHS Classification - Health Serious Eye Damage/Irritation: Category 1. Skin Corrosion/Irritation: Category 3. Specific Target Organ Toxicity (single exposure): Category 1. Specific Target Organ Toxicity (repeated exposure): Category 1. Signal Word DANGER! Symbols Corrosion | Health Hazard | Hazard Statements - Environmental H402 Harmful to aquatic life. Hazard Statements - Health Causes serious eye damage. H316 Causes mild skin irritation. Hazard Statements - Target Organ, Single Exposure, Category 1 H370 Causes damage to organs: blood or blood-forming organs | Hazard Statements - Target Organ, Prolonged or Repeated Exposure, Category 1 H372 Causes damage to organs through prolonged or repeated exposure: blood or blood-forming organs | Precautionary Statements - Prevention P260 Do not breathe dust/fume/gas/mist/vapours/spray. P280A Wear eye/face protection. Precautionary Statements - Response P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P332 + P313 If skin irritation occurs: Get medical advice/attention. P307 + P311 IF exposed: Call a POISON CENTER or doctor/physician. P310 Immediately call a POISON CENTER or doctor/physician. 3 COMPOSITION/INFORMATION ON INGREDIENTS ------------------------------------------------------------------------ Ingredient name CAS number % ------------------------------------- ------------------ ------------- WATER 7732-18-5 80 - 95 2-BUTOXYETHANOL 111-76-2 3 - 7 ETHANOLAMINE 141-43-5 1 - 5 ALCOHOLS, C6-12, ETHOXYLATED 68439-45-2 0.5 - 1.5 ALCOHOLS, C12-14-SECONDARY, 84133-50-6 0.5 - 1.5 ETHOXYLATED 4 FIRST-AID MEASURES ------------------------------------------------------------------------ Instructions for Eye Contact Immediately flush eyes with large amounts of water for at least 15 minutes. Get immediate medical attention. Instructions for Skin Contact Remove contaminated clothing and shoes. Wash affected area with soap and water. If signs/symptoms develop, get medical attention. Wash contaminated clothing and clean shoes before reuse. Instructions for Inhalation If signs/symptoms develop, remove person to fresh air. If signs/symptoms persist, get medical attention. Instructions for Ingestion Do not induce vomiting unless instructed to do so by medical personnel. Give victim two glasses of water. Never give anything by mouth to an unconscious person. Get medical attention. 5 FIRE-FIGHTING MEASURES ------------------------------------------------------------------------ Suitable Extinguishing Media Unsuitable Extinguishing Media Exposure Hazards during Fire Non-flammable: ordinary combustible material. Material will not burn. Combustion Products from Fire Not determined. Fire Fighting Procedures Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatus (SCBA). Special Instructions for Fire Fighting Contact with aluminum or zinc in a pressurised system may generate hydrogen gas which could create an explosion hazard. 6 ACCIDENTAL RELEASE MEASURES ------------------------------------------------------------------------ Personal Precautions Evacuate unprotected and untrained personnel from hazard area. The spill should be cleaned up by qualified personnel. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapours, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or vapours in the spill area to burn or explode. Remember, adding an absorbent material does not remove a toxic, corrosivity or flammability hazard. Cover, but do not seal for 48 hours. Environmental Procedures For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water. Collect the resulting residue containing solution. Place in a metal container approved for use in transportation by appropriate authorities. The container must be lined with polyethylene plastic or contain a plastic drum liner made of polyethylene. Dispose of collected material as soon as possible. Methods for Cleaning Up Refer to other sections of this MSDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. Contain spill. For large spills, if necessary, get assistance from professional spill clean up team. For small spills, carefully neutralise spill by adding appropriate dilute acid such as vinegar. Work slowly to avoid boiling or spattering. Continue to add neutralising agent until reaction stops. Let cool before collecting. Or use a commercially available caustic (alkaline or basic) spill clean-up kit. Follow kit directions exactly. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Collect as much of the spilled material as possible. Clean up residue with water. Methods for Disposal Since regulations vary, consult applicable regulations or authorities before disposal. 7 HANDLING AND STORAGE ------------------------------------------------------------------------ Use Instructions Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Avoid breathing of vapours, mists or spray. Avoid skin contact. Storage Requirements Store away from areas where product may come into contact with food or pharmaceuticals. Store under normal warehouse conditions. Incompatible Materials Keep away from aluminum and zinc. 8 EXPOSURE CONTROLS/PERSONAL PROTECTION ------------------------------------------------------------------------ 2-BUTOXYETHANOL (111-76-2) ACGIH - TWA: 20 ppm ACGIH: TWA ETHANOLAMINE (141-43-5) ACGIH - STEL: 6 ppm ACGIH: STEL ACGIH - TWA: 3 ppm ACGIH: TWA Recommended Ventilation Use in an enclosed process area is recommended. Use in a well-ventilated area. Eye Protection Avoid eye contact with vapours, mists, or spray. The following should be worn alone or in combination, as appropriate, to prevent eye contact: Safety glasses with side shields Indirect Vented Goggles Hand Protection The following glove material(s) are recommended: butyl rubber neoprene nitrile rubber Skin Protection Avoid skin contact. Respiratory Protection Avoid breathing of vapours, mists or spray. Under normal use conditions, airborne exposures are not expected to be significant enough to require respiratory protection. Ingestion Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Keep out of the reach of children. 9 PHYSICAL AND CHEMICAL PROPERTIES ------------------------------------------------------------------------ - Appearance and Odour: Liquid. Clear, colourless; mild solvent odour - Odour Threshold: Not determined. - pH: 12.5 - 13.5 - Boiling point/boiling range: CA 100.0 C - Flash point: N/A - Autoflammability: N/A - Flammable Limits - LEL: N/A - Flammable Limits - UEL: N/A - Vapour pressure: < 27 psia CONDITIONS: @ 55.0 C - Water Solubility: - Partition coefficient (K o/w): Not determined - Specific gravity: 0.997 CA 1 Water=1 - Relative Density: Not determined. - Volatile organic compounds: 5 - 10 % CARB - Evaporation rate: CA 1 - Viscosity: < 100 centipoise - Percent Volatile: 64 - 100 % by wt 10 STABILITY AND REACTIVITY ------------------------------------------------------------------------ Stability and Reactivity Hazardous polymerisation will not occur. Stable. Conditions to Avoid None known. Materials to Avoid None known. Hazardous Decomposition Carbon monoxide - During Combustion Carbon dioxide - During Combustion Oxides of Nitrogen - During Combustion 11 TOXICOLOGICAL INFORMATION ------------------------------------------------------------------------ Effects from Eye Contact Corrosive (Eye Burns): Signs/symptoms may include cloudy appearance of the cornea, chemical burns, severe pain, tearing, ulcerations, significantly impaired vision or complete loss of vision. Effects from Skin Contact Moderate Skin Irritation: Signs/symptoms may include localised redness, swelling, itching, and dryness. May be absorbed through skin and cause target organ effects. Effects from Inhalation Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. May be absorbed following inhalation and cause target organ effects. Effects from Ingestion Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhoea. May be absorbed following ingestion and cause target organ effects. Other Effects and Information Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness. Blood Effects: Signs/symptoms may include generalised weakness and fatigue, skin pallor, changes in blood clotting time, internal bleeding, and/or hemoglobinemia. Prolonged or repeated exposure may cause: Liver Effects: Signs/symptoms may include loss of appetite, weight loss, fatigue, weakness, abdominal tenderness and jaundice. Kidney/Bladder Effects: Signs/symptoms may include changes in urine production, abdominal or lower back pain, increased protein in urine, increased blood urea nitrogen (BUN), blood in urine, and painful urination. Numerical Measures of Toxicity Not determined. 12 ECOLOGICAL INFORMATION ------------------------------------------------------------------------ Environmental Data Not determined. Mobility in Soil and Water Not determined. Persistence/Biodegradability Not determined. Bioaccumulation Potential Not determined. Ecotoxicity Data Not determined. Ecological Fate Data Not determined. 13 DISPOSAL CONSIDERATIONS ------------------------------------------------------------------------ Product as Sold Dispose of waste product in a permitted hazardous waste facility. Product in Use Not determined. Product after Use Not determined. Product Packaging Not determined. Potential for Recycling Not determined. 14 TRANSPORT INFORMATION ------------------------------------------------------------------------ UN NUMBER: - UN number: Not restricted for transportation. SG ROAD/SEA FREIGHT (IMO) CLASSIFICATION: Substance Identification Number: ADR/RID CLASSIFICATION: ICAO/IATA CLASSIFICATION: 15 REGULATORY INFORMATION ------------------------------------------------------------------------ WSH (General Provision) Regulations This product is subject to SDS, 2006 labelling, PEL and other requirements in the Act/Regulations. 16 OTHER INFORMATION ------------------------------------------------------------------------ Reason for Reissue Updated MSDS to reflect changes to original ND document. (# 19-7627-3)